Abstract
The accumulation of total Pb, Cd, Cu, and Zn in soils (0–5 cm) and windowsill dust fractions (45–125, 10–45, and < 10 μm), and soil pollution indices (PI), were investigated in a long-term (~ 70 years) Pb smelter area and in the nearby urban city of Jiyuan, China. Principal component analysis (PCA) was utilized to identify metal contamination sources. Results showed that mean soil Pb, Cd, Cu, and Zn concentrations in the smelter area were 803, 13.8, 118, and 323 mg kg−1, while those of the urban area were 270, 7.95, 51.6, and 244 mg kg−1, respectively. Lead and Cd had greater soil PI than Cu and Zn. Lead concentrations in the 45–125, 10–45, and < 10-μm urban dust fractions ranged from 197.1 to 1953 (mean 1020), 202–3962 (2407), and 51.1–1258 (310.7) mg kg−1, while Cd concentrations ranged from 11.1 to 111 (49.2), 10.4–159 (64.3) and 21.5–131 (60.0) mg kg−1, respectively. Excessive Zn concentrations (5000–22,000 mg kg−1) in some urban dust samples were found at two sampling sites, while Zn concentrations were < 2600 mg kg−1 in all other samples. Based on PCA results, metal accumulation near the Pb smelter was dominated by smelting activities. The PCA results further suggested that mass vehicular transportation modes may be an important source of metals such as Cu and Zn in the urban area. Certain samples in both sub-areas had unsafe potential non-carcinogenic risks of Pb for children. These findings suggest that reducing environmentally relevant metal concentrations in this, and similar areas, will likely require a multi-faceted approach.
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References
Al-Shidi HK, Sulaiman H, Al-Reasi HA et al (2021) Human and ecological risk assessment of heavy metals in different particle sizes of road dust in Muscat, Oman. Environ Sci Pollut Res 28:33980–33993. https://doi.org/10.1007/s11356-020-09319-6
Amato F, Querol X, Johansson C et al (2010) A review on the effectiveness of street sweeping, washing and dust suppressants as urban PM control methods. Sci Total Environ 408:3070–3084. https://doi.org/10.1016/j.scitotenv.2010.04.025
Bureau of Statistics of Jiyuan City (2018) Statistical bulletin of economy and social development of Jiyuan City in 2017. http://www.jiyuan.gov.cn/depzwgk/sfzhggwyh/zhglxx/tjgb/202005/t20200528_675055.html accessed May 20, 2021
Chen M, Pi L, Luo Y et al (2016) Grain size distribution and health risk assessment of metals in outdoor dust in Chengdu, Southwestern China. Arch Environ Contam Toxicol 70:534–543. https://doi.org/10.1007/s00244-016-0266-8
Cheng Y-X, Zhao Z-S, Wang Y-Z, et al. (2014) Soil heavy metals pollution in the farmland near a lead smelter in Henan Province. Chin J Soil Sci 45:1505–1510 https://doi.org/10.19336/j.cnki.trtb.2014.06.034
de Andrade Lima LRP, Bernardez LA (2017) Characterization of the soil contamination around the former primary lead smelter at Santo Amaro, Bahia, Brazil. Environ Earth Sci 76:470. https://doi.org/10.1007/s12665-017-6791-6
Dietrich M, Krekeler MPS, Kousehlar M et al (2021) Quantification of Pb pollution sources in complex urban environments through a multi-source isotope mixing model based on Pb isotopes in lichens and road sediment. Environ Pollut 288:117815. https://doi.org/10.1016/j.envpol.2021.117815
Douay F, Pruvot C, Roussel H et al (2008) Contamination of urban soils in an area of north-ern France polluted by dust emissions of two smelters. Water Air Soil Pollut 188:247–260. https://doi.org/10.1007/s11270-007-9541-7
Duzgoren-Aydin NS, Weiss AL (2008) Use and abuse of Pb-isotope fingerprinting technique and GIS mapping data to assess lead in environmental studies. Environ Geochem Health 30:577–588. https://doi.org/10.1007/s10653-008-9179-4
Ettler V (2016) Soil contamination near non-ferrous metal smelters: a review. Appl Geochem 64:56–74. https://doi.org/10.1016/j.apgeochem.2015.09.020
Feng W, Zhang Y, Huang L et al (2022) Source apportionment of environmentally persistent free radicals (EPFRs) and heavy metals in size fractions of urban arterial road dust. Process Saf Environ Prot 157:352–361. https://doi.org/10.1016/j.psep.2021.11.039
Heidari M, Darijani T, Alipour V (2021) Heavy metal pollution of road dust in a city and its highly polluted suburb; quantitative source apportionment and source-specific ecological and health risk assessment. Chemosphere 273:129656. https://doi.org/10.1016/j.chemosphere.2021.129656
Henan Jiyuan Ecological Environmental Testing Center (2019) Annual bulletin of environmental quality of Jiyuan of 2018. http://hbj.jiyuan.gov.cn/hjjcz/hjzl/hjzlgb/201906/t20190605_555377.html accessed May 30, 2021
Hou S, Zheng N, Tang L et al (2019) Pollution characteristics, sources, and health risk assessment of human exposure to Cu, Zn, Cd and Pb pollution in urban street dust across China between 2009 and 2018. Environ Int 128:430–437. https://doi.org/10.1016/j.envint.2019.04.046
Hwang H-M, Fiala MJ, Park D et al (2016) Review of pollutants in urban road dust and stormwater runoff: part 1. Heavy metals released from vehicles. Int J Urban Sci 20:334–360. https://doi.org/10.1080/12265934.2016.1193041
Jeong H, Ryu J-S, Ra K (2022) Characteristics of potentially toxic elements and multi-isotope signatures (Cu, Zn, Pb) in non-exhaust traffic emission sources. Environ Pollut 292:118339. https://doi.org/10.1016/j.envpol.2021.118339
Laidlaw M, Zahran S, Mielke HW et al (2012) Re-suspension of lead contaminated urban soil as a dominant source of atmospheric lead in Birmingham, Chicago, Detroit and Pittsburgh, USA. Atmos Environ 49:302–310. https://doi.org/10.1016/j.atmosenv.2011.11.030
Lanzerstorfer C (2017) Variations in the composition of house dust by particle size. J Environ Sci Health A 52(8):770–777. https://doi.org/10.1080/10934529.2017.1303316
Lee PK, Kang MJ, Yu S et al (2020) Assessment of trace metal pollution in roof dusts and soils near a large Zn smelter. Sci Total Environ 713:136536. https://doi.org/10.1016/j.scitotenv.2020.136536
Li G, Sun G-X, Ren Y et al (2018a) Urban soil and human health: a review. Eur J Soil Sci 69:196–215. https://doi.org/10.1111/ejss.12518
Li Q, Zhao X, Li H, et al. (2016) Pollution and potential ecological risk assessment of heavy metals in agricultural soils of gas-type pollution. J Zhengzhou Univ (Medical Sciences) 51:718–722 https://doi.org/10.13705/j.issn.1671-6825.2016.06.008
Li S, Bi X, Li Z et al (2021) Heavy metal(loid)s contamination in ground dust and associated health risks at a former indigenous zinc smelting area. Int J Environ Res Public Health 18:893. https://doi.org/10.3390/ijerph18030893
Li X, Li Z, Lin C et al (2018b) Health risks of heavy metal exposure through vegetable consumption near a large-scale Pb/Zn smelter in central China. Ecotoxicol Environ Saf 161:99–110. https://doi.org/10.1016/j.ecoenv.2018.05.080
Li YL, Chen WP, Yang Y, et al. (2020a) Heavy metal pollution characteristics and comprehensive risk evaluation of farmland across the eastern plain of Jiyuan city. Acta Sci Circumst 40:2229–2236https://doi.org/10.13671/j.hjkxxb.2020a.0020
Li Y-L, Lu Y-F, Chen W-P, et al. (2020b) Spatial-temporal variation and source change of heavy metals in the cropland soil in the industrial city. Environ Sci 41:1432–1439 https://doi.org/10.13227/j.hjkx.201907254
Li Z, Feng X, Li G et al (2011) Mercury and other metal and metalloid soil contamination near a Pb/Zn smelter in east Hunan province, China. Appl Geochem 26:160–166. https://doi.org/10.1016/j.apgeochem.2010.11.014
Liddle B (2017) Urbanization and inequality/poverty. Urban Sci 1:35. https://doi.org/10.3390/urbansci1040035
Lisiewicz M, Heimburger R, Golimowski J (2000) Granulometry and the content of toxic and potentially toxic elements in vacuum-cleaner collected, indoor dusts of the city of Warsaw. Sci Total Environ 263:69–78. https://doi.org/10.1016/S0048-9697(00)00667-7
Liu E, Yan T, Birch G et al (2014) Pollution and health risk of potentially toxic metals in urban road dust in Nanjing, a mega-city of China. Sci Total Environ 476–477:522–531. https://doi.org/10.1016/j.scitotenv.2014.01.055
Ljung K, Siah WS, Devine B et al (2011) Extracting dust from soil: improved efficiency of a previously published process. Sci Total Environ 410:269–270. https://doi.org/10.1016/j.scitotenv.2011.07.061
Meza-Figueroa D, De la O-Villanueva M, De la Parra ML (2007) Heavy metal distribution in dust from elementary schools in Hermosillo, Sonora, Mexico. Atmos Environ 41:276-288https://doi.org/10.1016/j.atmosenv.2006.08.034
Ministry of Ecology and Environment of China, State Administration for Market Regulation of China 2018 Soil environmental quality risk control standard for soil contamination of development land (GB36600–2018).
Odewande A, Abimbola A (2008) Contamination indices and heavy metal concentrations in urban soil of Ibadan metropolis, southwestern Nigeria. Environ Geochem Health 30:243–254. https://doi.org/10.1007/s10653-007-9112-2
Ordóñez A, Loredo J, De Miguel E et al (2003) Distribution of heavy metals in the street dusts and soils of an industrial city in northern Spain. Arch Environ Contam Toxicol 44:160–170. https://doi.org/10.1007/s00244-002-2005-6
Rahman MS, Khan MDH, Jolly YN et al (2019) Assessing risk to human health for heavy metal contamination through street dust in the Southeast Asian Megacity: Dhaka, Bangladesh. Sci Total Environ 660:1610–1622. https://doi.org/10.1016/j.scitotenv.2018.12.425
Rasmussen PE, Beauchemin S, Nugent M et al (2008) Influence of matrix composition on the bioaccessibility of copper, zinc, and nickel in urban residential dust and soil. Hum Ecol Risk Assess 14:351–371. https://doi.org/10.1080/10807030801934960
Roy S, Gupta SK, Prakash J et al (2019) Ecological and human health risk assessment of heavy metal contamination in road dust in the National Capital Territory (NCT) of Delhi, India. Environ Sci Pollut Res 26:30413–30425. https://doi.org/10.1007/s11356-019-06216-5
Stafilov T, Šajn R, Pančevski Z et al (2010) Heavy metal contamination of topsoils around a lead and zinc smelter in the Republic of Macedonia. J Hazard Mater 175:896–914. https://doi.org/10.1016/j.jhazmat.2009.10.094
Tang Z, Chai M, Cheng J et al (2017) Contamination and health risks of heavy metals in street dust from a coal-mining city in eastern China. Ecotoxicol Environ Saf 138:83–91. https://doi.org/10.1016/j.ecoenv.2016.11.003
US EPA (2007) EPA Method 3051 A, Microwave assisted acid digestion of sediments, sludges, soils and oils. Revision 11, Feb 2007, Washington DC, 1–30
Van Pelt RS, Shekhter EG, Barnes MAW et al (2020) Spatial and temporal patterns of heavy metal deposition resulting from a smelter in El Paso, Texas. J Geochem Explor 210:106414. https://doi.org/10.1016/j.gexplo.2019.106414
Wade AM, Ritcher DD, Craft CB et al (2021) Urban-soil pedogenesis drives contrasting legacies of lead from paint and gasoline in city soil. Environ Sci Technol 55:7981–7989. https://doi.org/10.1021/acs.est.1c00546
Wang HZ, Cai LM, Wang QS et al (2021) A comprehensive exploration of risk assessment and source quantification of potentially toxic elements in road dust: a case study from a large Cu smelter in central China. Catena 196:104930. https://doi.org/10.1016/j.catena.2020.104930
Waterlot C, Bidar G, Pelfrene A et al (2013) Contamination, fractionation and availability of metals in urban soils in the vicinity of former lead and zinc smelters, France. Pedosphere 23:143–159. https://doi.org/10.1016/S1002-0160(13)60002-8
Wijaya AR, Ouchi AK, Tanaka K et al (2012) Metal contents and Pb isotopes in road-side dust and sediment of Japan. J Geochem Explor 118:68–76. https://doi.org/10.1016/j.gexplo.2012.04.009
Wiseman CLS, Levesque C, Rasmussen PE (2021) Characterizing the sources, concentrations and resuspension potential of metals and metalloids in the thoracic fraction of urban road dust. Sci Total Environ 786:147467. https://doi.org/10.1016/j.scitotenv.2021.147467
Witt EC III, Wronkiewicz DJ, Shi H (2013) Preliminary assessment of an economical fugitive road dust sampler for the collection of bulk samples for geochemical analysis. J Environ Qual 42:21–29. https://doi.org/10.2134/jeq2012.0158
Wu F, Kong S, Yan Q et al (2020) Sub-type source profiles of fine particles for fugitive dust and accumulative health risks of heavy metals: a case study in a fast-developing city of China. Environ Sci Pollut Res 27:16554–16573. https://doi.org/10.1007/s11356-020-08136-1
Xing W, Yang H, Ippolito JA et al (2020a) Atmospheric deposition of As, Cd, Cu, Pb and Zn near an operating and an abandoned lead smelter. J Environ Qual 49:1667–1678. https://doi.org/10.1002/jeq2.20151
Xing W, Yang H, Ippolito JA et al (2020b) Lead source and bioaccessibility in windowsill dusts within a Pb smelting-affected area. Environ Pollut 266:115110. https://doi.org/10.1016/j.envpol.2020.115110
Xing W, Zhao Q, Scheckel KG et al (2019) Inhalation bioaccessibility of Cd, Cu, Pb and Zn and speciation of Pb in particulate matter fractions from areas with different pollution characteristics in Henan Province, China. Ecotoxicol Environ Saf 175:192–200. https://doi.org/10.1016/j.ecoenv.2019.03.062
Xu D-M, Fu R-B, Liu H-Q et al (2021) Current knowledge from heavy metal pollution in Chinese smelter contaminated soils, health risk implications and associated remediation progress in recent decades: a critical review. J Clean Prod 286:124989. https://doi.org/10.1016/j.jclepro.2020.124989
Yang D, Ye C, Wang X et al (2018) Global distribution and evolvement of urbanization and PM2.5 (1998–2015). Atmos Environ 182:171–178. https://doi.org/10.1016/j.atmosenv.2018.03.053
Zhang Y, Hou D, O’Connor D et al (2019) Lead contamination in Chinese surface soils: source identification, spatial-temporal distribution and associated health risks. Crit Rev Environ Sci Technol 49:1386–1423. https://doi.org/10.1080/10643389.2019.1571354
Zhao X, Yao D, Cheng Y (2017) Function analysis on the total and available contents of toxic metal in soils of a lead smelting area. Environ Monit China 33:68–74 https://doi.org/10.19316/j.issn.1002-6002.2017.01.11
Zheng N, Hou S, Wang S et al (2020) Health risk assessment of heavy metals in street dust around a zinc smelting plant in China based on bioavailability and bioaccessibility. Ecotoxicol Environ Saf 197:110617. https://doi.org/10.1016/j.ecoenv.2020.110617
Zheng N, Liu J, Wang Q et al (2010) Health risk assessment of heavy metal exposure to street dust in the zinc smelting district, Northeast of China. Sci Total Environ 408:726–733. https://doi.org/10.1016/j.scitotenv.2009.10.075
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This work was supported by The National Key Research and Development Programs of China from Ministry of Science and Technology of China (grant number: 2018YFD0800304, received by Weiqin Xing) and National Natural Science Foundation of China from National Natural Science Foundation of China (grant number: 41471253, received by Liping Li).
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The study conception and design were performed by Weiqin Xing and Liping Li. Material preparation, data collection, and analysis were performed by Jie Luo, Ruilong Lu, and Zhongyu Hao. The first draft of the manuscript was written by Jie Luo and James A. Ippolito and Liping Li; all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.
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Xing, W., Luo, J., Ippolito, J.A. et al. Metal contamination in soils and windowsill dusts: implication of multiple sources on dust metal accumulation within a city affected by Pb smelting. Environ Sci Pollut Res 29, 68447–68459 (2022). https://doi.org/10.1007/s11356-022-20696-y
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DOI: https://doi.org/10.1007/s11356-022-20696-y