Abstract
In an effort for efficient solar energy harvesting, carbon-doped zinc oxide (C-ZnO) nanoparticles with intriguing properties were synthesized by sonicated sol–gel technique with the aid of activated charcoal. Compared to pure ZnO, the incorporation of carbon has drastically promoted the photocatalytic activity of C-ZnO towards the degradation of phenanthrene under illumination of both UV and sunlight. The characterization of the as-synthesized nanoparticles by scanning electron microscope (SEM), UV–vis spectra, Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), and energy-dispersive X-ray spectroscopy (EDS) confirmed the carbon doping of C-ZnO. The highest degradation rate of phenanthrene was obtained at pH 7 and C-ZnO loading of 0.5 g L−1. Finally, the kinetic studies of the photocatalytic degradation of phenanthrene by using C-ZnO were well-fitted with the Langmuir–Hinshelwood model and followed the pseudo-first-order rate expression.
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Most data generated or analyzed during this study are included in this published article and its supplementary information file. Anyway, further datasets used and/or analyzed during the current study are available from the corresponding author on reasonable request.
References
Ahmed S, Rasul MG, Martens WN, Brown R, Hashib MA (2010) Heterogeneous photocatalytic degradation of phenols in wastewater: a review on current status and developments. Desalination 261:3–18. https://doi.org/10.1016/j.desal.2010.04.062
Bozetine H, Wang Q, Barras A, Li M, Hadjersi T, Szunerits S, Boukherroub R (2016) Green chemistry approach for the synthesis of ZnO–carbon dots nanocomposites with good photocatalytic properties under visible light. J Colloid Interface Sci 465:286–294. https://doi.org/10.1016/j.jcis.2015.12.001
Chandrabose G, Dey A, Gaur SS, Pitchaimuthu S, Jagadeesan H, Braithwaite NSJ, Selvaraj V, Kumar V, Krishnamurthy S (2021) Removal and degradation of mixed dye pollutants by integrated adsorption-photocatalysis technique using 2-D MoS2/TiO2 nanocomposite. Chemosphere 279:130467. https://doi.org/10.1016/j.chemosphere.2021.130467
Chang H, Sun Z, Ho KYF, Tao X, Yan F, Kwok WM, Zheng Z (2011) A highly sensitive ultraviolet sensor based on a facile in situ solution-grown ZnO nanorod/graphene heterostructure. Nanoscale 3:258–264. https://doi.org/10.1039/C0NR00588F
Chen J, Peijnenburg WJGM, Quan X, Chen S, Martens D, Schramm KW, Kettrup A (2001) Is it possible to develop a QSPR model for direct photolysis half-lives of PAHs under irradiation of sunlight? Environ Pollut 114:137–143. https://doi.org/10.1016/S0269-7491(00)00195-0
Chen WJ, Wu JK, Lin JC, Lo ST, Lin HD, Hang DR, Shih MF, Liang CT, Chang YH (2013) Room-temperature violet luminescence and ultraviolet photodetection of Sb-doped ZnO/Al-doped ZnO homojunction array. Nanoscale Res Lett 8:1–6. https://doi.org/10.1186/1556-276X-8-313
Chen H, Wen M, Huang Z, Wu Q, Liu J, Tu T (2015) Construction of Cu@ ZnO nanobrushes based on Cu nanowires and their high-performance selective degradation of polycyclic aromatic hydrocarbons. J Mater Chem A 3:600–607. https://doi.org/10.1039/C4TA05204H
Cheng HM, Hsieh WF (2010) High-efficiency metal-free organic-dye-sensitized solar cells with hierarchical ZnO photoelectrode. Energy Environ Sci 3:442–447. https://doi.org/10.1039/B915725E
Dagdeviren C, Hwang SW, Su Y, Kim S, Cheng H, Gur O, Haney H, Omenetto FG, Huang Y, Rogers JA (2013) Transient, biocompatible electronics and energy harvesters based on ZnO. small 9:3398–3404. https://doi.org/10.1002/smll.201300146
Ding D, Lan W, Yang Z, Zhao X, Chen Y, Wang J, Zhang X, Zhang Y, Su Q, Xie E (2016) A simple method for preparing ZnO foam/carbon quantum dots nanocomposite and their photocatalytic applications. Mater Sci Semicond Process 47:25–31. https://doi.org/10.1016/j.mssp.2016.02.004
Djurišić AB, Ng AMC, Chen XY (2010) ZnO nanostructures for optoelectronics: material properties and device applications. Prog Quantum Electron 34:191–259. https://doi.org/10.1016/j.pquantelec.2010.04.001
Ge X, Tian F, Wu Z, Yan Y, Cravotto G, Wu Z (2015) Adsorption of naphthalene from aqueous solution on coal-based activated carbon modified by microwave induction: microwave power effects. Chem Eng Process 91:67–77. https://doi.org/10.1016/j.cep.2015.03.019
Gomis-Berenguer A, Velasco LF, Velo-Gala I, Ania CO (2017) Photochemistry of nanoporous carbons: perspectives in energy conversion and environmental remediation. J Colloid Interface Sci 490:879–901. https://doi.org/10.1016/j.jcis.2016.11.046
Guoa X, Duana J, Wanga W, Zhang Z (2020) Modified graphitic carbon nitride as the photocatalyst for wastewater treatment under visible light irradiation. Fuel 280:118544. https://doi.org/10.1016/j.fuel.2020.118544
Han C, Yang MQ, Weng B, Xu YJ (2014) Improving the photocatalytic activity and anti-photocorrosion of semiconductor ZnO by coupling with versatile carbon. Phys Chem Chem Phys 16:16891–16903. https://doi.org/10.1039/C4CP02189D
Hassan SS, El Azab WI, Ali HR, Mansour MS (2015) Green synthesis and characterization of ZnO nanoparticles for photocatalytic degradation of anthracene. Adv Nat Sci: Nanosci. Nanotechnol 6:045012. https://doi.org/10.1088/2043-6262/6/4/045012
Hong RY, Li JH, Chen LL, Liu DQ, Li HZ, Zheng Y, Ding JJPT (2009) Synthesis, surface modification and photocatalytic property of ZnO nanoparticles. Powder Technol 189:426–432. https://doi.org/10.1016/j.powtec.2008.07.004
Huang J, Yin Z, Zheng Q (2011) Applications of ZnO in organic and hybrid solar cells. Energy & Environmental Science 4:3861–3877. https://doi.org/10.1039/c1ee01873f
International Agency for Research on Cancer (1987) IARC monographs on the evaluation of carcinogenic risks to humans, supplement 7. Overall evaluations of carcinogenicity: An updating of IARC monographs volumes 1 to 42. Lyon, France
Ijaz M, Zafar M, Islam A, Afsheen S, Iqbal T (2020) A review on antibacterial properties of biologically synthesized zinc oxide nanostructures. J Inorg Organomet Polym 30:2815–2826. https://doi.org/10.1007/s10904-020-01603-9
Islam SE, Hang DR, Chen CH, Chou MM, Liang CT, Sharma KH (2021) Rational design of hetero-dimensional C-ZnO/MoS2 nanocomposite anchored on 3D mesoporous carbon framework towards synergistically enhanced stability and efficient visible-light-driven photocatalytic activity. Chemosphere 266:129148. https://doi.org/10.1016/j.chemosphere.2020.129148
Jain R, Shrivastava M (2008) Photocatalytic removal of hazardous dye cyanosine from industrial waste using titanium dioxide. J Hazard Mater 152:216–220. https://doi.org/10.1016/j.jhazmat.2007.06.119
Janus M, Inagak M, Tryba B, Toyoda M, Morawski AW (2006) Carbon-modified TiO2 photocatalyst by ethanol carbonization. Appl Catal B 63:272–276. https://doi.org/10.1016/j.apcatb.2005.10.005
Jian S, Tian Z, Hu J, Zhang K, Zhang L, Duan G, Yang W, Jiang S (2021) Enhanced visible light photocatalytic efficiency of La-doped ZnO nanofibers via electrospinning-calcination technology. Advanced Powder Materials, in Press. https://doi.org/10.1016/j.apmate.2021.09.004
Kaur Y, Bhatia Y, Chaudhary S, Chaudhary GR (2017) Comparative performance of bare and functionalize ZnO nanoadsorbents for pesticide removal from aqueous solution. J Mol Liq 234:94–103. https://doi.org/10.1016/j.molliq.2017.03.069
Kavitha R, Devi LG (2014) Synergistic effect between carbon dopant in titania lattice and surface carbonaceous species for enhancing the visible light photocatalysis. J Environ Chem Eng 2:857–867. https://doi.org/10.1016/j.jece.2014.02.016
Khan SU, Al-Shahry M, Ingler WB (2002) Efficient photochemical water splitting by a chemically modified n-TiO2. science 297:2243–2245. https://doi.org/10.1126/science.1075035
Kornmüller A, Cuno M, Wiesmann U (1997) Selective ozonation of polycyclic aromatic hydrocarbons in oil/water-emulsions. Water Sci Technol 35:57–64. https://doi.org/10.1016/S0273-1223(97)00009-7
Kotsis K, Staemmler V (2006) Ab initio calculations of the O1s XPS spectra of ZnO and Zn oxo compounds. Phys Chem Chem Phys 8:1490–1498. https://doi.org/10.1039/B515699H
Kubelka P (1948) New contributions to the optics of intensely light-scattering materials. Part i, Josa 38:448–457. https://doi.org/10.1364/JOSA.38.000448
Lam SM, Sin JC, Abdullah AZ, Mohamed AR (2012) Degradation of wastewaters containing organic dyes photocatalysed by zinc oxide: a review. Desalin Water Treat 41:131–169. https://doi.org/10.1080/19443994.2012.664698
Lavand AB, Malghe YS (2018) Synthesis, characterization and visible light photocatalytic activity of carbon and iron modified ZnO. J King Saud Univ-Sci 30:65–74. https://doi.org/10.1016/j.jksus.2016.08.009
Lei XF, Xue XX, Yang H, Chen C, Li X, Niu MC, Gao XY, Yang YT (2015) Effect of calcination temperature on the structure and visible-light photocatalytic activities of (N, S and C) co-doped TiO2 nano-materials. Appl Surf Sci 332:172–180. https://doi.org/10.1016/j.apsusc.2015.01.110
Lettmann C, Hildenbrand K, Kisch H, Macyk W, Maier WF (2001) Visible light photodegradation of 4-chlorophenol with a coke-containing titanium dioxide photocatalyst. Appl Catal B 32:215–227. https://doi.org/10.1016/S0926-3373(01)00141-2
Li F, Sun S, Jiang Y, Xia M, Sun M, Xue B (2008) Photodegradation of an azo dye using immobilized nanoparticles of TiO2 supported by natural porous mineral. J Hazard Mater 152:1037–1044. https://doi.org/10.1016/j.jhazmat.2007.07.114
Lin J, Yu JC (1998) An investigation on photocatalytic activities of mixed TiO2 -rare earth oxides for the oxidation of acetone in air. J Photochem Photobiol, A 116:63–67. https://doi.org/10.1016/S1010-6030(98)00289-5
Lin T, Yu L, Sun M, Cheng G, Lan B, Fu Z (2016) Mesoporous α-MnO2 microspheres with high specific surface area: controlled synthesis and catalytic activities. Chem Eng J 286:114–121. https://doi.org/10.1016/j.cej.2015.09.024
Ling CM, Mohamed AR, Bhatia SV (2004) Performance of photocatalytic reactors using immobilized TiO2 film for the degradation of phenol and methylene blue dye present in water stream. Chemosphere 57:547–554. https://doi.org/10.1016/j.chemosphere.2004.07.011
Lu J, Dai Y, Guo M, Yu L, Lai K, Huang B (2012) Chemical and optical properties of carbon-doped TiO2: a density-functional study. Appl Phys Lett 100:102114. https://doi.org/10.1063/1.3693525
Ma S, Xue J, Zhou Y, Zhang Z, Wu X (2014) A facile route for the preparation of ZnO/C composites with high photocatalytic activity and adsorption capacity. CrystEngComm 16:4478–4484. https://doi.org/10.1039/C4CE00110A
Ma B, Lv X, He Y, Xu J (2016) Assessing adsorption of polycyclic aromatic hydrocarbons on Rhizopus oryzae cell wall components with water–methanol cosolvent model. Ecotoxicol Environ Saf 125:55–60. https://doi.org/10.1016/j.ecoenv.2015.11.032
Maensiri S, Laokul P, Promarak V (2006) Synthesis and optical properties of nanocrystalline ZnO powders by a simple method using zinc acetate dihydrate and poly (vinyl pyrrolidone). J Cryst Growth 289:102–106. https://doi.org/10.1016/j.jcrysgro.2005.10.145
Manekkathodi A, Lu MY, Wang CW, Chen LJ (2010) Direct growth of aligned zinc oxide nanorods on paper substrates for low-cost flexible electronics. Adv Mater 22:4059–4063. https://doi.org/10.1002/adma.201001289
Merabet S, Bouzaza A, Wolbert D (2009) Photocatalytic degradation of indole in a circulating upflow reactor by UV/TiO2 process—influence of some operating parameters. J Hazard Mater 166:1244–1249. https://doi.org/10.1016/j.jhazmat.2008.12.047
Mishra DK, Mohapatra J, Sharma MK, Chattarjee R, Singh SK, Varma S, Behera SN, Nayak SK, Entel P (2013) Carbon doped ZnO: synthesis, characterization and interpretation. J Magn Magn Mater 329:146–152. https://doi.org/10.1016/j.jmmm.2012.09.058
Nikazar M, Gholivand K, Mahanpoor K (2008) Photocatalytic degradation of azo dye Acid Red 114 in water with TiO2 supported on clinoptilolite as a catalyst. Desalination 219:293–300. https://doi.org/10.1016/j.desal.2007.02.035
Oppenländer T (2003) Photochemical purification of water and air: advanced oxidation processes (AOPs): principles, reaction mechanisms, reactor concepts, Weinheim: Wiley-vch Verlag Gmbh & Co. 8 239–277
Parida KM, Dash SS, Das DP (2006) Physico-chemical characterization and photocatalytic activity of zinc oxide prepared by various methods. J Colloid Interface Sci 298:787–793. https://doi.org/10.1016/j.jcis.2005.12.053
Petukhov AV (1997) Effect of molecular mobility on kinetics of an electrochemical Langmuir-Hinshelwood reaction. Chem Phys Lett 277:539–544. https://doi.org/10.1016/S0009-2614(97)00916-0
Pongpiachan S (2013) Vertical distribution and potential risk of particulate polycyclic aromatic hydrocarbons in high buildings of Bangkok Thailand. Asian Pac J Cancer Prev 14:1865–1877. https://doi.org/10.7314/APJCP.2013.14.3.1865
Rani M, Shanker U (2018) Removal of chlorpyrifos, thiamethoxam, and tebuconazole from water using green synthesized metal hexacyanoferrate nanoparticles. Environ Sci Pollut Res 25:10878–10893. https://doi.org/10.1007/s11356-018-1346-2
Ren C, Yang B, Wu M, Xu J, Fu Z, Guo T, Zhao Y, Zhu C (2010) Synthesis of Ag/ZnO nanorods array with enhanced photocatalytic performance. J hazard mater 182:123–129. https://doi.org/10.1016/j.jhazmat.2010.05.141
Sannino F, Pirozzi D, Vitiello G, D’errico G, Aronne A, Fanelli E, Pernice P (2014) Oxidative degradation of phenanthrene in the absence of light irradiation by hybrid ZrO2-acetylacetonate gel-derived catalyst. Appl. Catal. B 156:101–107. https://doi.org/10.1016/j.apcatb.2014.03.006
Shaban YA, Fallata HM (2019) Sunlight-induced photocatalytic degradation of acetaminophen over efficient carbon doped TiO2 (CTiO2) nanoparticles. Res Chem Intermed 45:2529–2547. https://doi.org/10.1007/s11164-019-03750-2
Shaban YA, Orif MI (2019) Purification of seawater by C-Cu-TiO2 ceramic based membrane. Desalin Water Treat 162:60–69. https://doi.org/10.5004/dwt.2019.24360
Shaban YA, El Sayed MA, El Maradny AA, Al Farawati RK, Al Zobidi MI (2013) Photocatalytic degradation of phenol in natural seawater using visible light active carbon modified (CM)-n-TiO2 nanoparticles under UV light and natural sunlight illuminations. Chemosphere 91:307–313. https://doi.org/10.1016/j.chemosphere.2012.11.035
Shaban YA, El Maradny AA, Al Farawati RK (2016) Photocatalytic reduction of nitrate in seawater using C/TiO2 nanoparticles. J Photochem Photobiol, A 328:114–121. https://doi.org/10.1016/j.jphotochem.2016.05.018
Sliem MA, Salim AY, Mohamed GG (2019) Photocatalytic degradation of anthracene in aqueous dispersion of metal oxides nanoparticles: effect of different parameters. J Photochem Photobiol, A 371:327–335. https://doi.org/10.1016/j.jphotochem.2018.11.028
Tang WZ, Huang CP (1995) Photocatalyzed oxidation pathways of 2, 4-dichlorophenol by CdS in basic and acidic aqueous solutions. Water Res 29:745–756. https://doi.org/10.1016/0043-1354(94)00151-V
Tauc J, Grigorovici R, Vancu A (1966) Optical properties and electronic structure of amorphous germanium. Phys. Status Solidi B 15:627–637. https://doi.org/10.1002/pssb.19660150224
Tian J, Zhang Q, Uchaker E, Gao R, Qu X, Zhang S, Cao G (2013) Architectured ZnO photoelectrode for high efficiency quantum dot sensitized solar cells. Energy Environ Sci 6:3542–3547. https://doi.org/10.1039/C3EE41056K
US EPA (2006). National emission standards for hazardous air pollutants, miscellaneous organic chemical manufacturing, United States Environmental Protection Agency, 40316–40342.
Veeralingam S, Yadav P, Badhulika S (2020) An Fe-doped ZnO/BiVO4 heterostructure-based large area, flexible, high-performance broadband photodetector with an ultrahigh quantum yield. Nanoscale 12(16):9152–9161. https://doi.org/10.1039/c9nr10776b
Venkatachalam N, Palanichamy M, Arabindoo B, Murugesan V (2007) Enhanced photocatalytic degradation of 4-chlorophenol by Zr4+ doped nano TiO2. J Mol Catal a: Chem 266:158–165. https://doi.org/10.1016/j.molcata.2006.10.051
Vinayagam M, Ramachandran S, Ramya V, Sivasamy A (2018) Photocatalytic degradation of orange G dye using ZnO/biomass activated carbon nanocomposite. J Environ Chem Eng 6:3726–3734. https://doi.org/10.1016/j.jece.2017.06.005
Wang R, Ren D, Xia S, Zhang Y, Zhao J (2009) Photocatalytic degradation of Bisphenol A (BPA) using immobilized TiO2 and UV illumination in a horizontal circulating bed photocatalytic reactor (HCBPR). J Hazard Mater 169:926–932. https://doi.org/10.1016/j.jhazmat.2009.04.036
Xu C, Killmeyer R, Gray ML, Khan SU (2006) Photocatalytic effect of carbon-modified n-TiO2 nanoparticles under visible light illumination. Appl Catal B 64:312–317. https://doi.org/10.1016/j.apcatb.2005.11.008
Zeng YU, Hong PA, Wavrek DA (2000) Chemical–biological treatment of pyrene. Water Res 34:1157–1172. https://doi.org/10.1016/S0043-1354(99)00270-5
Zhan WW, Kuang Q, Zhou JZ, Kong XJ, Xie ZX, Zheng LS (2013) Semiconductor@ metal–organic framework core–shell heterostructures: a case of ZnO@ ZIF-8 nanorods with selective photoelectrochemical response. J Am Chem Soc 135:1926–1933. https://doi.org/10.1021/ja311085e
Zhang L, Cheng H, Zong R, Zhu Y (2009) Photocorrosion suppression of ZnO nanoparticles via hybridization with graphite-like carbon and enhanced photocatalytic activity. J Phys Chem C 113:2368–2374. https://doi.org/10.1021/jp807778r
Zhang G, Zhang YC, Nadagouda M, Han C, O’Shea K, El-Sheikh SM, Ismail AA, Dionysiou DD (2014) Visible light-sensitized S, N and C co-doped polymorphic TiO2 for photocatalytic destruction of microcystin-LR. Appl Catal B 144:614–621. https://doi.org/10.1016/j.apcatb.2013.07.058
Zhang P, Yang X, Zhao Z, Li B, Gui J, Liu D, Qiu J (2017) One-step synthesis of flowerlike C/Fe2O3 nanosheet assembly with superior adsorption capacity and visible light photocatalytic performance for dye removal. Carbon 116:59–67. https://doi.org/10.1016/j.carbon.2017.01.087
Zhu YP, Li M, Liu YL, Ren TZ, Yuan ZY (2014) Carbon-doped ZnO hybridized homogeneously with graphitic carbon nitride nanocomposites for photocatalysis. J Phys Chem C 118:10963–10971. https://doi.org/10.1021/jp502677h
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The authors acknowledge Mr. Mosa Alzobidi and Dr. Yasar N.K. for their appreciable help in the experimental analysis.
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Yasser A. Shaban contributed to the study conceptualization, supervision, visualization, project administration, writing–original draft preparation, and reviewing and editing the manuscript. Material preparation, analysis, and data collection were performed by Nojoud A. Alharbi. All authors read and approved the final manuscript.
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Shaban, Y., Alharbi, N.A. Sunlight-mediated photocatalytic removal of phenanthrene from wastewater using carbon-doped zinc oxide (C-ZnO) nanoparticles. Environ Sci Pollut Res 29, 47818–47831 (2022). https://doi.org/10.1007/s11356-022-19214-x
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DOI: https://doi.org/10.1007/s11356-022-19214-x