Abstract
The presence of natural organic matter such as humic acid in water creates various problems in water purification. Humic acid can react with chlorine in the disinfection step and lead to the production of trihalomethanes and haloacetic acids that these compounds have carcinogenic and mutagenic properties; therefore, they must be removed before arriving to the disinfection stage. The purpose of this research was adsorption of humic acid from simulated wastewater by synthesized FeNi3/SiO2/TiO2 magnetic nanocomposites. FeNi3/SiO2/TiO2 magnetic nanocomposites were synthesized by sol-gel procedure and its characteristics were determined by TEM, VSM, BET, FESEM, and XRD techniques. Then, the effects of such pH (3–11), FeNi3/SiO2/TiO2 dosage (0.005–0.1 g/L), contact time (0–200 min), and initial concentration (2–15 mg/L) were studied on humic acid adsorption using FeNi3/SiO2/TiO2. The results of adsorption experiments revealed that the highest percentage of humic acid removal (94.4%) was achieved at pH 3, initial concentration of 5 ppm, FeNi3/SiO2/TiO2 dose of 0.1 g/L, and contact time of 90 min. The analyses of experimental isotherm data showed that the humic acid adsorption was described by Langmuir model and also the kinetic studies represented that the process of adsorption of humic acid on FeNi3/SiO2/TiO2 was followed by the pseudo-second kinetic. According to the results, it can be concluded that FeNi3/SiO2/TiO2 magnetic nanocomposites have a high ability to absorb humic acid from simulated wastewater.
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References
Ang W, Mohammad AW et al (2015) Hybrid chitosan/FeCl3 coagulation–membrane processes: performance evaluation and membrane fouling study in removing natural organic matter. Sep Purif Technol 152:23–31
Bazrafshan E, Balarak D et al (2016) Fluoride removal from aqueous solutions by cupricoxide nanoparticles. Fluoride 49(3):233
Bazrafshan E, Sobhanikia M et al (2017) Chromium biosorption from aqueous environments by mucilaginous seeds of Cydonia oblonga: kinetic and thermodynamic studies. Global Nest J 19(2):269–277
Dehghani MH, Faraji M, Mohammadi A, Kamani H (2017) Optimization of fluoride adsorption onto natural and modified pumice using response surface methodology: isotherm, kinetic and thermodynamic studies. Korean J Chem Eng 34(2):454–462
Derakhshani E, Naghizadeh A (2018) Optimization of humic acid removal by adsorption onto bentonite and montmorillonite nanoparticles. J Mol Liq 259:76–81
Dong C, Chen W, Liu C (2014a) Preparation of novel magnetic chitosan nanoparticle and its application for removal of humic acid from aqueous solution. Appl Surf Sci 292:1067–1076
Dong C, Chen W, Liu C, Liu Y, Liu H (2014b) Synthesis of magnetic chitosan nanoparticle and its adsorption property for humic acid from aqueous solution. Colloids Surf A Physicochem Eng Asp 446:179–189
Esmaeili H, Ebrahimi A et al (2012) Kinetic and isotherm studies of humic acid adsorption onto iron oxide magnetic nanoparticles in aqueous solutions. Int J Environ Health Eng 1(1):33
Giasuddin AB, Kanel SR et al (2007) Adsorption of humic acid onto nanoscale zerovalent iron and its effect on arsenic removal. Environ Sci Technol 41(6):2022–2027
Hamid N, Ismail A et al (2011) Morphological and separation performance study of polysulfone/titanium dioxide (PSF/TiO2) ultrafiltration membranes for humic acid removal. Desalination 273(1):85–92
Jayalath S, Wu H, Larsen SC, Grassian VH (2018) Surface adsorption of Suwannee River humic acid on TiO2 nanoparticles: a study of pH and particle size. Langmuir 34(9):3136–3145
Khodadadi M, Ehrampoush M et al (2018a) FeNi3@ SiO2 magnetic nanocomposite as a highly efficient Fenton-like catalyst for humic acid adsorption and degradation in neutral environments. Desalin Water Treat 118:258–267
Khodadadi M, Ehrampoush M et al (2018b) Synthesis and characterizations of FeNi3@ SiO2@ TiO2 nanocomposite and its application in photo-catalytic degradation of tetracycline in simulated wastewater. J Mol Liq 255:224–232
Khodadadi M, Al-Musawi TJ, Kamranifar M et al (2019) A comparative study of using barberry stem powder and ash as adsorbents for adsorption of humic acid. Environ Sci Pollut Res 26:26159
Korotta-Gamage SM, Sathasivan A (2017) A review: potential and challenges of biologically activated carbon to remove natural organic matter in drinking water purification process. Chemosphere 167:120–138
Lee P, Sun D et al (2007) Adsorption and photodegradation of humic acids by nano-structured TiO2 for water treatment. J Adv Oxid Technol 10(1):72–78
Lin K-YA, Chang H-A (2015) Efficient adsorptive removal of humic acid from water using zeolitic imidazole framework-8 (ZIF-8). Water Air Soil Pollut 226(2):10
Liu J, Huang H, Huang R, Zhang J, Hao S, Shen Y, Chen H (2016) Mechanisms of CPB modified zeolite on mercury adsorption in simulated wastewater. Water Environ Res 88(6):490–499
Lu Z, Zhao X, Zhu Z, Yan Y, Shi W, Dong H, Ma Z, Gao N, Wang Y, Huang H (2015) Enhanced recyclability, stability, and selectivity of CdS/C@ Fe3O4 nanoreactors for orientation photodegradation of ciprofloxacin. Chem Eur J 21(51):18528–18533
Mahvi AH, Mohammadi M et al (2016) Sodium dodecyl sulfate modifed-zeolite as a promising adsorbent for the removal of natural organic matter from aqueous environments. Health Scope 5(1):11–18
Matilainen A, Sillanpää M (2010) Removal of natural organic matter from drinking water by advanced oxidation processes. Chemosphere 80(4):351–365
Naghizadeh A, Ghafouri M (2017) Synthesis and performance evaluation of chitosan prepared from Persian Gulf shrimp shell in removal of reactive blue 29 dye from aqueous solution (isotherm, thermodynamic and kinetic study). Iran J Chem Chem Eng (IJCCE) 36(3):25–36
Naghizadeh A, Ghafouri M, Jafari A (2017) Investigation of equilibrium, kinetics and thermodynamics of extracted chitin from shrimp shell in reactive blue 29 (RB-29) removal from aqueous solutions. Desalin Water Treat 70:355–363
Nasseh N, Taghavi L, Barikbin B, Nasseri MA (2018) Synthesis and characterizations of a novel FeNi3/SiO2/CuS magnetic nanocomposite for photocatalytic degradation of tetracycline in simulated wastewater. J Clean Prod 179:42–54
Panahi AH, Ashrafi SD, Kamani H, Khodadadi M, Lima EC, Mostafapour FK, Mahvi AH (2019) Removal of cephalexin from artificial wastewater by mesoporous silica materials using Box-Behnken response surface methodology. Desalin Water Treat 159:169–180
Paul B, Parashar V et al (2015) Graphene in the Fe 3 O 4 nano-composite switching the negative influence of humic acid coating into an enhancing effect in the removal of arsenic from water. Environ Sci 1(1):77–83
Qin J-J, Oo MH et al (2006) Impact of coagulation pH on enhanced removal of natural organic matter in treatment of reservoir water. Sep Purif Technol 49(3):295–298
Rao P, Lo IM et al (2011) Removal of natural organic matter by cationic hydrogel with magnetic properties. J Environ Manag 92(7):1690–1695
Shekari H, Sayadi M et al (2017) Synthesis of nickel ferrite/titanium oxide magnetic nanocomposite and its use to remove hexavalent chromium from aqueous solutions. Surf Interf 8:199–205
Shen J, Schäfer AI (2015) Factors affecting fluoride and natural organic matter (NOM) removal from natural waters in Tanzania by nanofiltration/reverse osmosis. Sci Total Environ 527:520–529
Song W, Shao D, Lu SS, Wang XK (2014) Simultaneous removal of uranium and humic acid by cyclodextrin modified graphene oxide nanosheets. SCIENCE CHINA Chem 57(9):1291–1299
Tang Y, Liang S, Yu S, Gao N, Zhang J, Guo H, Wang Y (2012) Enhanced adsorption of humic acid on amine functionalized magnetic mesoporous composite microspheres. Colloids Surf A Physicochem Eng Asp 406:61–67
Wang X, Wu Z, Wang Y, Wang W, Wang X, Bu Y, Zhao J (2013) Adsorption–photodegradation of humic acid in water by using ZnO coupled TiO2/bamboo charcoal under visible light irradiation. J Hazard Mater 262:16–24
Wang J, Tian H, Ji Y (2015) Adsorption behavior and mechanism of humic acid on aminated magnetic nanoadsorbent. Sep Sci Technol 50(9):1285–1293
Yang S, Hu J, Chen C, Shao D, Wang X (2011) Mutual effects of Pb (II) and humic acid adsorption on multiwalled carbon nanotubes/polyacrylamide composites from aqueous solutions. Environ Sci Technol 45(8):3621–3627
Zazouli MA, Kalankesh LR (2017) Removal of precursors and disinfection by-products (DBPs) by membrane filtration from water; a review. J Environ Health Sci Eng 15(1):25
Zhang X, Minear RA (2006) Formation, adsorption and separation of high molecular weight disinfection byproducts resulting from chlorination of aquatic humic substances. Water Res 40(2):221–230
Zularisam A, Ismail A et al (2006) Behaviours of natural organic matter in membrane filtration for surface water treatment—a review. Desalination 194(1–3):211–231
Zulfikar M, Suri F et al (2016) Fe3O4 nano-particles prepared by co-precipitation method using local sands as a raw material and their application for humic acid removal. Int J Environ Stud 73(1):79–94
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The authors appreciate the Vice President for Research and Technology of Birjand University of Medical Sciences for funding this study.
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Akbari, F., Khodadadi, M., Hossein Panahi, A. et al. Synthesis and characteristics of a novel FeNi3/SiO2/TiO2 magnetic nanocomposites and its application in adsorption of humic acid from simulated wastewater: study of isotherms and kinetics. Environ Sci Pollut Res 26, 32385–32396 (2019). https://doi.org/10.1007/s11356-019-06371-9
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DOI: https://doi.org/10.1007/s11356-019-06371-9