Abstract
Considering combinatorial optimality of functional group analysis, speciation, solution chemistry complexity, Pd(II) adsorption–desorption characteristics, this article addresses the competence and efficacy of anion exchange resins namely Amberlite IRA958, Dowex Marathon MSA, Lewatit TP214, and Amberlyst A21 commercial resins. Based on preliminary batch adsorption experiments conducted in the range of 2−10 pH, 0.2−2 g L−1 adsorbent dosage, and 5−1080-min contact time, the optimal adsorption process parameters refer to 4 pH, 1.6, and 1.4 g L−1 adsorbent dosage, and 840- and 720-min contact time for Amberlite IRA958 and Dowex Marathon MSA resins, respectively. Among alternate models, the best-fit models refer to the Freundlich isotherm and pseudo-second-order kinetic models to represent Pd(II) adsorption data obtained for both Dowex Marathon MSA and Amberlite IRA958 resins. Based on the Langmuir isotherm, the maximum monolayer adsorption capacity was evaluated to be 185.16 and 166.67 mg g−1 for Dowex Marathon MSA and Amberlite IRA958 resins, respectively. For model electroless plating solutions as adsorbate system possessing desired solution chemistry complexity and resin cost, nitrogen- and oxygen-containing Amberlyst A21 resin is concluded to be optimal resin. This is not in agreement with the generalized rule of thumb that considers sulfur–nitrogen functional group containing commercial resins to be effective than resins with nitrogen–oxygen functional groups. Due to functional group interactions with the noble metal, no other by-products or exchanged chemicals have been produced in due course of Pd(II) adsorption process, which can be also regarded as an added advantage of the process.
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References
Aharoni C, Ungarish M (1977) Kinetics of activated chemisorption. Part 2—theoretical models. J. Chem. Soc. 73:456–464
Cieszynska A, Wiśniewski M (2012) Extractive recovery of palladium(II) from hydrochloric acid solutions with Cyphos®IL 104. Hydrometallurgy 113–114:79–85
Hubicki Z, Wolowicz A (2009) Adsorption of palladium(II) from chloride solutions on Amberlyst A 29 and Amberlyst A 21 resins. Hydrometallurgy 96:159–165
Hubicki Z, Leszczynska M, Lodyga B, Lodyga A (2007) Recovery of palladium(II) from chloride and chloride–nitrate solutions using ion-exchange resins with S-donor atoms. Desalination 207:80–86
Hubicki Z, Wawrzkiewicz M, Wolowicz A (2008) Application of ion exchange methods in recovery of Pd(II) Ions – a review. Chem. Anal. (Warsaw) 53:759–784
Jalilian N, Ebrahimzadeh H, Asgharinezhad AA, Molaei K (2017) Extraction and determination of trace amounts of gold(III), palladium(II), platinum(II) and silver(I) with the aid of a magnetic nanosorbent made from Fe3O4-decorated and silica-coated graphene oxide modified with a polypyrrole-polythiophene copolymer. Microchimica Acta 184:2191–2200
Jarvis KE, Parry SJ, Piper JM (2001) Temporal and spatial studies of autocatalyst-derived platinum, rhodium, and palladium and selected vehicle-derived trace elements in the environment. Environ. Sci. Technol. 35:1031–1036
Kielhorn J, Melber C, Keller D, Mangelsdorf I (2002) Palladium: a review of exposure and effects to human health. Int J Hyg Environ Health 205:417–432
Labosova L, Stofkova M, Kracunovska J (2006) The study of possibilities of selective recovery of palladium (II) from chlorides solutions by ion exchange resin Lewatit TP-214. Acta Metall Slovaca 12:235–241
Langmuir I (1918) The adsorption gases on plane surface of glass, mica and platinum. J. Am. Chem. Soc. 40:1361–1403
Liu Y (2009) Is the free energy change of adsorption correctly calculated? J. Chem. Eng. Data 54:1981–1985
Nagireddi S, Golder AK, Uppaluri R (2017a) Investigation on Pd (II) removal and recovery characteristics of chitosan from electroless plating solutions. J. Water Process Eng. 19:8–17
Nagireddi S, Katiyar V, Uppaluri R (2017b) Pd(II) adsorption characteristics of glutaraldehyde cross-linked chitosan copolymer resin. Int. J. Biol. Macromol. 94:72–84
Nagireddi S, Golder AK, Uppaluri R (2018) Role of protonation and functional groups in Pd(II) recovery and reuse characteristics of commercial anion exchange resin-synthetic electroless plating solution systems. J. Water Process Eng. 22:227–238
Nikoloski AN, Ang K-L, Li D (2015) Recovery of platinum, palladium and rhodium from acidic chloride leach solution using ion exchange resins. Hydrometallurgy 152:20–32
Niu H, Volesky B (2003) Characteristics of anionic metal species biosorption with waste crab shells. Hydrometallurgy 71:209–215
Organization WH (2002) Environmental health criteria 226-palladium. In: World Health Organization. International Programme on Chemical Safety, Geneva
Rajesh Y (2015) Adsorption characteristics of activated carbon adsorbents for the recovery of Pd (II) from synthetic electroless plating solutions. Indian Institute of Technology Guwahati, Guwahati, p 247
Sharififard H, Soleimani M, Ashtiani FZ (2012) Evaluation of activated carbon and bio-polymer modified activated carbon performance for palladium and platinum removal. Journal of the Taiwan Institute of Chemical Engineers 43:696–703
Tahmasebi E, Yamini Y (2014) Polythiophene-coated Fe3O4 nanoparticles as a selective adsorbent for magnetic solid-phase extraction of silver(I), gold(III), copper(II) and palladium(II). Microchimica Acta 181:543–551
Traeger J, Konig J, Stadtke A, Holdt H-J (2012) Development of a solvent extraction system with 1,2-bis(2-methoxyethylthio)benzene for the selective separation of palladium(II) from secondary raw materials. Hydrometallurgy 127–128:30–38
Wolowicz A, Hubicki Z (2011a) Comparison of strongly basic anion exchange resins applicability for the removal of palladium(II) ions from acidic solutions. Chemical Engineering Journal 171:206–215
Wolowicz A, Hubicki Z (2011b) Comparison of strongly basic anion exchange resins applicability for the removal of palladium(II) ions from acidic solutions. Chemical Engineering Journal 171:206–215
Wolowicz A, Hubicki Z (2012) The use of the chelating resin of a new generation Lewatit MonoPlus TP-220 with the bis-picolylamine functional groups in the removal of selected metal ions from acidic solutions. Chem. Eng. J. 197:493–508
Wołowicz A, Hubicki Z (2012) Ion exchange recovery of palladium(II) from acidic solutions using monodisperse Lewatit SR-7. Ind. Eng. Chem. Res. 51:16688–16696
Wolowicz A, Hubicki Z (2014) Adsorption characteristics of noble metals on the strongly basic anion exchanger Purolite A-400TL. J Mater Sci 49:6191–6202
Zhou L, Liu J, Liu Z (2009) Adsorption of platinum(IV) and palladium(II) from aqueous solution by thiourea-modified chitosan microspheres. Journal of Hazardous Materials 172:439–446
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The infrastructural facilities provided by Centre for the Environment, Chemical Engineering Department, and Central Instruments Facility at the Indian Institute of Technology Guwahati are duly appreciated by the authors.
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The authors would like to thank the monetary support of CSIR (Council for Science and Industrial Research, New Delhi, India) for an extramural grant (22(0672/14/EMR-II) is as well appreciated and thankfully acknowledged to support the research findings of this work.
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Highlights
• Dowex Marathon MSA anion exchange resin provided excellent Pd(II) removal and recovery characteristics from synthetic electroless plating solutions.
• Optimal batch adsorption process parameters for the Dowex resin are 4 pH, 720-min contact time, and 1.4 g L−1 adsorbent dosage.
• Resin performed excellently despite having the inhibitory role of Na2EDTA and NH4OH species.
• Speciation analysis is in agreement with the hypothesis associated with optimal pH.
• Acid-base theory based on the classification of commercial resins (S > N > O) proven to be wrong.
• Combinatorial optimality of process parameters, resin performance, and resin cost the best guideline for the screening of alternate resins.
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Nagireddi, S., Golder, A.K. & Uppaluri, R. Combinatorial optimality of functional groups, process parameters, and Pd(II) adsorption–desorption characteristics for commercial anion exchange resins-synthetic electroless plating systems. Environ Sci Pollut Res 27, 24614–24626 (2020). https://doi.org/10.1007/s11356-019-05941-1
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DOI: https://doi.org/10.1007/s11356-019-05941-1