Abstract
The application of a hybrid Cu(tpa).GO (Cu(tpa) copper terephthalate metal organic framework, GO graphene oxide) composite as a new adsorbent for the removal of toxic metal ions was reported. New hybrid nanocomposite with excellent dispersibility and stability was successfully fabricated by the simple and effective ultrasonication method. The synthesized composite was characterized by scanning electron microscopy (SEM), UV-Vis and Fourier-transform infrared (FT-IR) techniques. The characterization results concluded that the binding mechanism of the Cu(tpa) and GO was related to both π−π packing and hydrogen bonding. For scrutinizing the sorption activity, the prepared adsorbents were assessed for the removal of Mn2+, Cu2+, Zn2+, Cd2+, Pb2+ and Fe3+ metal ions from aqueous synthetic solution and also acid mine drainage (AMD) wastewater. The sorption experiments demonstrated that the removal efficiency was significantly improved by modified hybrid Cu(tpa).GO composite, owing to the significant number of active binding sites and unique structure formed based on π-conjugated networks. Also, it was shown that the adsorption reaction was mainly attributed to the chemical interactions between metal ions and the surface functional groups. Moreover, kinetic and adsorption studies clarified that the adsorption process onto the Cu(tpa).GO follows a pseudo-second-order kinetics and fits the Langmuir and Freundlich adsorption models. Holistically, the results of this research represent that applying Cu(tpa).GO can be remarked as an effective adsorbent with high possibility at conventional water treatment.
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References
Abedin Khan N, Hasan Z, Hwa Jhung S (2013) Adsorptive removal of hazardous materials using metal-organic frameworks (MOFs): a review. J Hazard Mater 244-245:444–456
Akhbarizadeh R, Shayestefar MR, Darezereshki E (2014) Competitive removal of metals from wastewater by maghemite nanoparticles: a comparison between simulated wastewater and AMD. Mine Water Environ 33:89–96
Barrie JD, Hallberg KB (2005) Acid mine drainage remediation options: a review. Sci Total Environ 338:3–14
Fu F, Wang Q (2011) Removal of heavy metal ions from wastewaters: a review. J Environ Manag 92:407–418
Giraldo L, Erto A, Moreno-Piraján JC (2013) Magnetite nanoparticles for removal of heavy metals from aqueous solutions: synthesis and characterization. Adsorption 19:465–474
Gomes HI, Jones A, Rogerson M, Greenway GM, Fernandez Lisbona D, Burke IT, Mayes WM (2017) Removal and recovery of vanadium from alkaline steel slag leachates with anion exchange resins. J Environ Manag 187:384–392
Guo X, Zhang S, Xq S (2008) Adsorption of metal ions on lignin. J Hazard Mater 151:134–142
Hasan Z, Jeon J, Jhung SH (2012) Adsorptive removal of naproxen and clofibric acid from water using metal-organic frameworks. J Hazard Mater 209-210:151–157
Huang CY, Song M, Gu ZY, Wang HF, Yan XP (2011) Probing the adsorption characteristic of metal-organic framework MIL-101 for volatile organic compounds by quartz crystal microbalance. Environ Sci Technol 45:4490–4496
Kalin M, Fyson A, Wheeler WN (2006) The chemistry of conventional and alternative treatment systems for the neutralization of acid mine drainage. Sci Total Environ 366:395–408
Klimkova S, Cernik M, Lacinova L, Filip J, Jancik D, Zboril R (2011) Zero-valent iron nanoparticles in treatment of acid mine water from in situ uranium leaching. Chemosphere 82:1178–1184
Kobya M, Demirbas E, Senturk E, Ince M (2005) Adsorption of heavy metal ions from aqueous solutions by activated carbon prepared from apricot stone. Bioresour Technol 96:1518–1521
Mayer KU, Benner SG, Blowes DW (2006) Process-based reactive transport modeling of a permeable reactive barrier for the treatment of mine drainage. J Contam Hydrol 85:195–211
Mohaghegh N, Tasviri M, Rahimi E, Gholami MR (2015) A novel p–n junction Ag3PO4/BiPO4 based stabilized Pickering emulsions for highly efficient photocatalysis. RSC Adv 5:12944–12955
Motsi T, Rowson NA, Simmons MJH (2009) Adsorption of heavy metals from acid mine drainage by natural zeolite. Int J Miner Process 92:42–48
Petit C, Bandosz TJ (2010) Enhanced adsorption of ammonia on metal-organic framework/graphite oxide composites: analysis of surface interactions. Adv Funct Mater 20:111–118
Pradeep T, Anshup (2009) Noble metal nanoparticles for water purification: a critical review. Thin Solid Films 517:6441–6478
Rahimi E, Mohaghegh N (2016) Removal of toxic metal ions from Sungun acid rock drainage using mordenite zeolite, graphene nanosheets, and a novel metal–organic framework. Mine Water Environ 35:18–28
Ríos CA, Williams CD, Roberts CL (2008) Removal of heavy metals from acid mine drainage (AMD) using coal fly ash, natural clinker and synthetic zeolites. J Hazard Mater 156:23–35
Ruparelia JP, Duttagupta SP, Chatterjee AK, Mukherji S (2008) Potential of carbon nanomaterials for removal of heavy metals from water. Desalination 232:145–156
Shin EJ, Lauve A, Carey M, Bukovsky E, Ranville JF, Evans RJ, Herring AM (2008) The development of bio-carbon adsorbents from Lodgepole Pine to remediate acid mine drainage in the Rocky Mountains. Biomass Bioenergy 32:267–276
Simate GS, Ndlovu S (2014) Acid mine drainage: challenges and opportunities. J Chem Eng Environ 2:1785–1803
Wang J, Zheng S, Shao Y, Liu J, Xu Z, Zhu D (2010) Amino-functionalized Fe3O4@SiO2 core–shell magnetic nanomaterial as a novel adsorbent for aqueous heavy metals removal. J Colloid Interface Sci 349:293–299
Wang X, Wang Q, Wang Q, Gao F, Yang Y, Guo H (2014) Highly dispersible and stable copper terephthalate metal−organic framework−graphene oxide nanocomposite for an electrochemical sensing application. ACS Appl Mater Interfaces 6:11573–11580
Yang STY, Chang L, Wang HF, Liu GB, Chen S, Wang YW, Liu YF, Cao AN (2010) Folding/aggregation of graphene oxide and its application in Cu2+ removal. J Colloid Interface Sci 351:122–127
Zhang M (2011) Adsorption study of Pb(II), Cu(II) and Zn(II) from simulated acid mine drainage using dairy manure compost. Chem Eng J 172:361–368
Zhang Y, Jiao Z, Hu Y, Lv S, Fan H, Zeng Y, Hu J, Wang M (2016) Removal of tetracycline and oxytetracycline from water by magnetic Fe3O4@graphene. Environ Sci Pollut Res:1–9
Zhao G, Ren X, Gao X, Tan X, Li J, Chen C, Huang Y, Wang X (2011) Removal of Pb(II) ions from aqueous solutions on few-layered graphene oxide nanosheets. Dalton Trans 40:10945–10952
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Rahimi, E., Mohaghegh, N. New hybrid nanocomposite of copper terephthalate MOF-graphene oxide: synthesis, characterization and application as adsorbents for toxic metal ion removal from Sungun acid mine drainage. Environ Sci Pollut Res 24, 22353–22360 (2017). https://doi.org/10.1007/s11356-017-9823-6
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DOI: https://doi.org/10.1007/s11356-017-9823-6