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Reduction of disinfection by-product precursors in reservoir water by coagulation and ultrafiltration

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Abstract

In this study, reservoir water intended for drinking water supply was treated by (i) ultrafiltration (UF) (ii) coagulation (CW) (iii) coagulation combined with ultrafiltration (CW-UF). To probe the influences of three treatment processes on disinfection byproduct (DBP) precursors in source water, the changes of dissolved organic matter (DOM) amounts and physicochemical properties, and disinfection byproduct (DBP) formation characteristics during chlorine disinfection were investigated. Both carbonaceous DBP (C-DBP) and nitrogenous DBP (N-DBP) formation and speciation were analyzed. The influence of chlorine dose, contact time on DBP formation and speciation were also studied to optimize the disinfection conditions to minimize the DBP formation. Compared with UF and CW alone, CW-UF improved the dissolved organic carbon (DOC) removal from about 20 % to 59 %. The three-dimensional excitation and emission matrix (3DEEM) fluorescence spectroscopy analysis showed that CW-UF had high removal efficiency in microbial products (Region IV), fulvic acid-like (Region III) and humic acid-like (Region V). The total C-DBP was determined by the formation of trihalomethanes and trichloromethane was the most abundant species (40 %). The most abundant N-DBP species was dichloroacetonitrile (32.5 %), followed by trichloroactetonitrile. CW-UF effectively reduced the risk of DBPs in drinking water supply by reducing 30.8 % and 16.9 % DBPs formation potential compared with UF and CW alone. Increasing contact time improved the yields of both C-DBPs and N-DBPs. Chlorine dosage had slight influence on DBP yield in this study.

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References

  • Amy GL, Tan L, Davis MK (1991) The effects of ozonation and activated carbon adsorption on trihalomethane speciation. Water Res 25:191–202

    Article  CAS  Google Scholar 

  • Association APH, (APHA) (2005) Standard methods for the examination of water and wastewater. American Public Health,. WE Federation, Washington DC

    Google Scholar 

  • Ates N, Yilmaz L, Kitis M, Yetis U (2009) Removal of disinfection by-product precursors by UF and NF membranes in low-SUVA waters. J Membr Sci 328:104–112

    Article  CAS  Google Scholar 

  • Chen Y, Dong BZ, Gao NY, Fan JC (2007) Effect of coagulation pretreatment on fouling of an ultrafiltration membrane. Desalination 204:181–188

    Article  CAS  Google Scholar 

  • Chu W, Gao N, Deng Y, Templeton MR, Yin D (2011) Impacts of drinking water pretreatments on the formation of nitrogenous disinfection by-products. Bioresour Technol 102:11161–11166

    Article  CAS  Google Scholar 

  • Chu W, Gao N, Krasner SW, Templeton MR, Yin D (2012) Formation of halogenated C-, N-DBPs from chlor(am)ination and UV irradiation of tyrosine in drinking water. Environ Pollut 161:8–14

    Article  CAS  Google Scholar 

  • David A, Reckhow ALM, Platt TL, MacNeill AL, McClellan JN (2001) Formation and degradation of dichloroacetonitrile in drinking waters. J Water Supply ResTechnol-Aqua 50:1–13

    Google Scholar 

  • de la Rubia A, Rodriguez M, Leon VM, Prats D (2008) Removal of natural organic matter and THM formation potential by ultra- and nanofiltration of surface water. Water Res 42:714–722

    Article  Google Scholar 

  • Dianchen Gang TEC, Shankha K, Banerji (2003) Relationship of chlorine decay and THMs formation to NOM size. J Hazard Mater A96:1–12

    Article  Google Scholar 

  • Drews (2010) Membrane fouling in membrane bioreactors–characterisation,contradictions, cause and cures. JMembrSci 363:1–28

    CAS  Google Scholar 

  • Fiksdal L, Leiknes T (2006) The effect of coagulation with MF/UF membrane filtration for the removal of virus in drinking water. J Membr Sci 279:364–371

    Article  CAS  Google Scholar 

  • Holbrook RD, Breidenich, J., DeRose, P.C., (2005): Impact of reclaimed water on select organic matter properties of a receiving StreamsFluorescence and Perylene sorption behavior. Environ Sci Technol 39, 6453–6460

  • Iriartevelasco U, Alvarezuriarte J, Gonzalezvelasco J (2007) Enhanced coagulation under changing alkalinity-hardness conditions and its implications on trihalomethane precursors removal and relationship with UV absorbance. Sep Purif Technol 55:368–380

    Article  CAS  Google Scholar 

  • Kabsch-Korbutowicz M (2005) Application of ultrafiltration integrated with coagulation for improved NOM removal. Desalination 174:13–22

    Article  CAS  Google Scholar 

  • Kabsch-Korbutowicz M (2006) Impact of pre-coagulation on ultrafiltration process performance. Desalination 194:232–238

    Article  CAS  Google Scholar 

  • Li R, Gao B, Ma D, Rong H, Sun S, Wang F, Yue Q, Wang Y (2015) Effects of chlorination operating conditions on trihalomethane formation potential in polyaluminum chloride-polymer coagulated effluent. J Hazard Mater 285:103–108

    Article  CAS  Google Scholar 

  • Ma D, Gao B, Xia C, Wang Y, Yue Q, Li Q (2014a) Effects of sludge retention times on reactivity of effluent dissolved organic matter for trihalomethane formation in hybrid powdered activated carbon membrane bioreactors. Bioresour Technol 166:381–388

    Article  CAS  Google Scholar 

  • Ma D, Peng B, Zhang Y, Gao B, Wang Y, Yue Q, Li Q (2014b) Influences of dissolved organic matter characteristics on trihalomethanes formation during chlorine disinfection of membrane bioreactor effluents. Bioresour Technol 165:81–87

    Article  CAS  Google Scholar 

  • Ma D, Meng Y, Xia C, Gao B, Wang Y (2015) Fractionation, characterization and C-, N-disinfection byproduct formation of soluble microbial products in MBR processes. Bioresour Technol 198:380–387

    Article  CAS  Google Scholar 

  • Mao R, Wang Y, Zhao Y, Gao B, Dong M (2013) Impact of various coagulation technologies on membrane fouling in coagulation/ultrafiltration process. Chem Eng J 225:387–393

    Article  CAS  Google Scholar 

  • McBean E, Zhu Z, Zeng W (2008) Systems analysis models for disinfection by-product formation in chlorinated drinking water in Ontario. Civ Eng Environ Syst 25:127–138

    Article  Google Scholar 

  • Mehmet Kitis TK, Andrew Wigton, James E. Kilduff (2002): Probing reactivity of dissolved organic matter for disinfection by-product formation using XAD-8 resin adsorption and ultrafiltration fractionation. Water Res 36, 3834–3848

  • Rathbun RE (1996) Bromine incorporation factors for trihalomethane formation for the Mississippi, Missouri, and Ohio rivers. Sci Total Environ 192:111–118

    Article  CAS  Google Scholar 

  • Reckhow DA, Singer PC (1985) Mechanisms of organic halide formation during fulvic acid chlorination and implications with respect to preozonation. Water Chlorination: Chemistry, Environmental Impact and Health Effects 5:1229–1257

    Google Scholar 

  • Richardson SD, Plewa MJ, Wagner ED, Schoeny R, Demarini DM (2007) Occurrence, genotoxicity, and carcinogenicity of regulated and emerging disinfection by-products in drinking water: a review and roadmap for research. Mutat Res 636:178–242

    Article  CAS  Google Scholar 

  • Judd SJ, Hillis P (2001) Optimisation of combined coagulation and microfiltration for water treatment. Wat Res 35:2895–2904

    Article  CAS  Google Scholar 

  • Sioutopoulos DC, Karabelas AJ (2012) Correlation of organic fouling resistances in RO and UF membrane filtration under constant flux and constant pressure. J Membr Sci 407-408:34–46

    Article  CAS  Google Scholar 

  • Sun S, Yang Z, Huang X, Bu F, Ma D, Dong H, Gao B, Yue Q, Wang Y, Li Q (2015) Coagulation performance and membrane fouling of polyferric chloride/epichlorohydrin–dimethylamine in coagulation/ultrafiltration combined process. Desalination 357:163–170

    Article  CAS  Google Scholar 

  • Touffet A, Baron J, Welte B, Joyeux M, Teychene B, Gallard H (2015) Impact of pretreatment conditions and chemical ageing on ultrafiltration membrane performances. Diagnostic of a coagulation/adsorption/filtration process. J Membr Sci 489:284–291

    Article  CAS  Google Scholar 

  • Uyak V, Yavuz S, Toroz I, Ozaydin S, Genceli EA (2007) Disinfection by-products precursors removal by enhanced coagulation and PAC adsorption. Desalination 216:334–344

    Article  CAS  Google Scholar 

  • Wang Y, Mao R, Wang Q, Yang Z, Gao B, Zhao Y (2012) Fulvic acid removal performance and control of disinfection by-product formation potential in coagulation–ultrafiltration process. Desalination 302:55–64

    Article  CAS  Google Scholar 

  • Wang YL, Feng J, Dentel SK, Lu J, Shi BY, Wang DS (2011) Effect of polyferric chloride (PFC) doses and pH on the fractal characteristics of PFC–HA flocs. Colloids Surf A Physicochem Eng Asp 379:51–61

    Article  CAS  Google Scholar 

  • Wen Chen PW, Jerry A. Leenheer and Ksrl Booksh (2003): Fluorescence Excitation-Emission Matrix Regional Integration to Quantify Spectra for Dissolved. Organic Matter.

  • Westerhoff P, Mash H (2002) Dissolved organic nitrogen in drinking water supplies: a review. Journal of Water Supply: Research and Technology - AQUA 51:415–448

    CAS  Google Scholar 

  • Yang X, Shang C, Westerhoff P (2007) Factors affecting formation of haloacetonitriles, haloketones, chloropicrin and cyanogen halides during chloramination. Water Res 41:1193–1200

    Article  CAS  Google Scholar 

  • Yao M, Nan J, Chen T, Zhan D, Li Q, Wang Z, Li H (2015) Influence of flocs breakage process on membrane fouling in coagulation/ultrafiltration process—effect of additional coagulant of poly-aluminum chloride and polyacrylamide. J Membr Sci 491:63–72

    Article  CAS  Google Scholar 

  • Zhao ZY, Gu JD, Fan XJ, Li HB (2006) Molecular size distribution of dissolved organic matter in water of the Pearl River and trihalomethane formation characteristics with chlorine and chlorine dioxide treatments. J Hazard Mater 134:60–66

    Article  CAS  Google Scholar 

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Acknowledgments

This work was supported by tai Shan scholar foundation. The kind suggestions from the anonymous reviewers are highly appreciated.

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Authors and Affiliations

  1. Shandong Key Laboratory of Water Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Shandong University, No. 27 Shanda South Road, Jinan, 250100, Shandong, People’s Republic of China

    Feng Wang, Baoyu Gao, Defang Ma, Qinyan Yue, Ruihua Li & Qianwen Wang

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  1. Feng Wang
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  2. Baoyu Gao
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  3. Defang Ma
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  4. Qinyan Yue
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  5. Ruihua Li
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  6. Qianwen Wang
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Correspondence to Baoyu Gao.

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Responsible editor: Philippe Garrigues

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Wang, F., Gao, B., Ma, D. et al. Reduction of disinfection by-product precursors in reservoir water by coagulation and ultrafiltration. Environ Sci Pollut Res 23, 22914–22923 (2016). https://doi.org/10.1007/s11356-016-7496-1

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  • DOI: https://doi.org/10.1007/s11356-016-7496-1

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