Abstract
The environmental problem caused by mining companies is known and has been studied by several authors. In this work, a sustainable solution was sought for iron-based waste collected from a mining company. This waste was purified and synthesized as a promising catalyst for degradation of polluting compounds, using methylene blue as a test. The sol–gel synthesis route was efficient for the removal of unwanted residues and for the formation of the α-Fe2O3 product. The material after sol–gel reached about 95.6% of degradation of the methylene blue solution (20 mg L−1), this response that can be attributed to a more porous and less compacted morphology and the presence of a more organized phase. This work assigns a sustainable purpose for iron waste, accumulated in mining companies, and shows that these materials can be as efficient for environmental remediation, as those contained in the literature.
Highlights
-
Purification and sol–gel synthesis of mining waste.
-
Use of mining waste as catalysts for advanced oxidative processes.
-
A sustainable purpose for the environmental problem caused by mining companies.
Similar content being viewed by others
Data availability
Data supporting the results of this study will be made available by the corresponding author, [ECS], upon reasonable request.
References
Akerdi, A. G., & Bahrami, S. H. (2019). Journal of Environmental Chemical Engineering Application of heterogeneous nano-semiconductors for photocatalytic advanced oxidation of organic compounds: A review. Journal of Environmental Chemical Engineering, 7, 103283.
Arellano, C. A. P., & Martínez, S. S. (2010). Effects of ph on the degradation of aqueous ferricyanide by photolysis and photocatalysis under solar radiation. Solar Energy Materials and Solar Cells, 94, 327–332.
Bouziani, A., Park, J., & Ozturk, A. (2020). Synthesis of α-Fe2O3/TiO2 heterogeneous composites by the sol-gel process and their photocatalytic activity. Journal of Photochemistry And Photobiology A: Chemistry, 400, 1–23.
Brasil, Agência Nacional., & de Mineração. (2020). Anuário Mineral Brasileiro: Principais substâncias metálicas. Agência Nacional de Mineração, 30, 1–60.
da Silva, E. C., de Moraes, M. O. S., Brito, W. R., Passos, R. R., Brambilla, R. F., da Costa, L. P., & Pocrifka, L. A. (2020). Synthesis of ZnO Nanoparticles by the Sol-Gel Protein Route: A Viable and Efficient Method for Photocatalytic Degradation of Methylene Blue and Ibuprofen. Journal of the Brazilian Chemical Society., 31, 1648–1653.
Demirci, S., Yurddaskal, M., Dikici, T., & Sarđoğlu, C. (2018). Fabrication and characterization of novel iodine doped hollow and mesoporous hematite (Fe2O3) particles derived from sol-gel method and their photocatalytic performances. J. of Hazardous Materials, 345, 27–37.
Deng, J., Liu, J., Dai, H., & Wang, W. (2018). Preparation of α-Fe2O3 nanowires through electrospinning and their Ag3PO4 heterojunction composites with enhanced visible light photocatalytic activity. Ferroelectrics, 528, 58–65.
Domacena, A. G., Aquino, C. E., & Balela, M. L. (2020). Photo-fenton degradation of methyl orange using hematite (α-Fe2O3) of various morphologies. Mater Today Proc., 22, 248–254.
dos Vergilio, C. S., Lacerda, D., de Oliveira, B. C. V., Sartori, E., Campos, G. M., de Pereira, A. L. S., de Aguiar, D. B., da Souza, T. S., de Almeida, M. G., Thompson, F., & Reende, C. E. (2020). Metal concentrations and biological effects from one of the largest mining disasters in the world (Brumadinho, Minas Gerais, Brazil). Scientific Reports, 10, 5936.
Freitas, V. A., Breder, S. M., Silvas, F. C., Rouse, P. R., & Oliveira, L. C. (2019). Use of iron ore tailing from tailing dam as catalyst in a fenton-like process for methylene blue oxidation in continuous flow mode. Chemosphere, 219, 328–334.
Iacob, M., Cazacu, M., Turta, C., Doroftei, F., Botko, M., Čižmár, E., Zeleňáková, A., & Feher, A. (2015). Amorphous iron-chromium oxide nanoparticles with long-term stability. Materials Research Bulletin, 65, 23–34.
Ilmetov, R. (2018). Photocatalytic activity of hematite nanoparticles prepared by sol-gel method. Mater Today Proc, 6, 11–14.
Kusior, A., Michalec, K., Jelen, P., & Radecka, M. (2019). Shaped Fe2O3 nanoparticles – synthesis and enhanced photocatalytic degradation towards RhB. Applied Surface Science, 476, 342–352.
Lebron, Y. A. R., Moreira, V. R., Drumond, G. P., Silva, M. M., Bernardes, R. O., Santos, L. V. D. S., Jacob, R., Viana, M. M., & Vasconcelos, C. K. B. D. (2020). Graphene oxide for efficient treatment of real contaminated water by mining tailings: metal adsorption studies to paraopeba river and risk assessment. Chemical Engineering Journal Advances, 2, 100017.
Macêdo, A. K. S., dos Santos, K. P. E., Brighenti, L. S., Windmöller, C. C., Barbosa, F. A. R., de Ribeiro, R. I. M. A., dos Santos, H. B., & Thomé, R. G. (2020). Histological and molecular changes in gill and liver of fish (Astyanax lacustris Lütken, 1875) exposed to water from the Doce basin after the rupture of a mining tailings dam in Mariana, MG, Brazil. Science of The Total Environment, 735, 139505.
Machala, L., Zboril, R., & Gedanken, A. (2007). Amorphous iron(III) oxide-A review. The Journal of Physical Chemistry B, 111, 4003–4018.
Neves, A. C. D. O., Barbieri, A. F., Pacheco, A. A., Resende, F., & d. M., Braga, R. F., Azevedo, A. A., & Fernandes, W. G. (2016). The human dimension in the espinhaço mountains: land conversion and ecosystem services. Ecology and Conservation of Mountaintop Grasslands in Brazil, 7, 501–530.
Sharma, S., Dutta, V., Singh, P., Raizada, P., Rahmani-Sani, A., Hosseini- Bandegharaei, A., & Thakur, V. K. (2019). Carbon quantum dot supported semiconductor photocatalysts for efficient degradation of organic pollutants in water: A review. Journal of Cleaner Production, 228, 755–769.
Silva, E. N., Brasileiro, L. O., Madeira, V. S., Farias, B. A., Ramalho, M. A., Elena Rodríguez-Aguado, E., & Rodríguez-Castellón, E. (2020). Reusable CuFe2O4-Fe2O3 catalyst synthesis and application for the heterogeneous photo-Fenton degradation of methylene blue in visible light. Journal of Environmental Chemical Engineering, 8, 1–44.
Singh, P., Sharma, K., Hasija, V., Sharma, V., Sharma, S., Raizada, P., Singh, M., Saini, A. K., Hosseini-Bandegharaei, A., & Thakur, V. K. (2019). Systematic review on applicability of magnetic iron oxides–integrated photocatalysts for degradation of organic pollutants in water. Mater Today Chemistry, 14, 100186.
Vohra, M. S., Al-Suwaiyan, M. S., Essa, M. H., Chowdhury, M. M. I., Rahman, M. M., & Labaran, B. A. (2016). Application of Solar Photocatalysis and Solar Photo- Fenton Processes for the Removal of Some Critical Charged Pollutants: Mineralization trends and formation of reaction intermediates. Arabian Journal for Science and Engineering, 41, 3877–3887.
Wang, C., & Huang, Z. (2016). Controlled synthesis of α-Fe2O3 nanostructures for efficient photocatalysis. Materials Letters, 164, 194–197.
Wang, W., Zhao, W., Zhang, H., Dou, X., & Shi, H. (2020). 2D/2D step-scheme α- Fe2O3/Bi2WO6 photocatalyst with efficient charge transfer for enhanced photo- Fenton catalytic activity. Chinese J Catal., 42, 97–106.
Wetchakun, K., Wetchakun, N., & Sakulsermsuk, S. (2019). An overview of solar/visible light-driven heterogeneous photocatalysis for water purification: TiO2- and ZnO- based photocatalysts used in suspension photoreactors. Journal of Industrial and Engineering Chemistry, 71, 19–49.
Wu, Z. J., Wang, L. C., Gao, Z. F., Liu, W. M., & Wu, X. R. (2016). Recycling blast furnace dust into metals (Al, Zn and Ti)-doped hematite with enhanced photocatalytic activity. Journal of Environmental Chemical Engineering, 4, 341–345.
Acknowledgements
WAL thanks to CNPq and FAPEAM for financial support and to the Laboratório Temático de Microscopia Óptica e Eletronica (LTMOE), from Instituto Nacional de Pesquisas do Amazonas (INPA) for the micrograph images.
Author information
Authors and Affiliations
Contributions
Wenderson A. S. Lira helped in writing—original draft, data curation, formal analysis, conceptualization, methodology and validation.
Emilly C Silva contributed to writing—original draft, data curation, formal analysis, supervision and visualization.
Leandro A. Pocrifka and Amanda C. Oliveira were involved in writing—review & editing.
Raimundo R. Passos reviewed the study.
Adriano C. Rabelo helped in project administration.
Corresponding author
Ethics declarations
Conflict of Interest
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Lira, W.A.S., Silva, E.C., Pocrifka, L.A. et al. Waste from an Amazon Mining Company Applied as a Catalyst in Photocatalysis Reactions for Environmental Remediation. Water Air Soil Pollut 233, 255 (2022). https://doi.org/10.1007/s11270-022-05733-3
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11270-022-05733-3