Abstract
The short chain ILs [BMIM] Oleate and [BMIM] Phosphate were explored as lubricant additives in both polar and non-polar base oils through using the multifunctional surfactants Triton-x-100 and PIBSA respectively. The formulations were stable and showed significant reductions in friction and wear compared with the base oil alone, the [BMIM] Phosphate Triton-x-100 in the Group V base oil showed a 63% reduction in wear scar diameter similar to [BMIM] Phosphate PIBSA in the Group III base oil, and a 44% reduction in coefficient of friction which was superior to all others IL additive blends which showed evidence of tribo-chemical reactions on the steel surface.
Similar content being viewed by others
References
Bart, J.C.J., Gucciardi, E., Cavallaro, S.: Biolubricants, pp. 824–846. Woodhead Publishing, Sawston (2013)
Bridges, N.J., Rogers, R.D., Visser, A.E., American Chemical Society: Ionic Liquids: Science and Applications. Oxford University Press, Oxford (2013)
Wasserscheid, P., Welton, T.: Ionic Liquids in Synthesis. Wiley, New York (2008)
Kumari, M., Maurya, J.K., Tasleem, M., Singh, P., Patel, R.: Probing HSA-ionic liquid interactions by spectroscopic and molecular docking methods. J. Photochem. Photobiol. B Biol. 138, 27–35 (2014)
Pal, A., Punia, R.: Interaction study of mixed micellar system of isoquinoline based surface active ionic liquids and cationic surfactant in aqueous medium. Colloid Polym. Sci. 297, 1011–1024 (2019)
Parmar, A., Aswal, V., Bahadur, P.: Interaction between the ionic liquids 1-alkyl-3-methylimidazolium tetrafluoroborate and Pluronic® P103 in aqueous solution: a DLS, SANS and NMR study. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 97, 137–143 (2012)
Sutto, T.E.: Hydrophobic and hydrophilic interactions of ionic liquids and polymers in solid polymer gel electrolytes. J. Electrochem. Soc. 154, P101–P107 (2007)
Thakkar, K., Bharatiya, B., Shah, D.O., Ray, D., Aswal, V.K., Bahadur, P.: Interaction of ionic liquid type cationic surfactants with triton X-100 nonionic micelles. Colloids Surf. A 484, 547–557 (2015)
Qu, J., Bansal, D.G., Yu, B., Howe, J.Y., Luo, H., Dai, S., Li, H., Blau, P.J., Bunting, B.G., Mordukhovich, G.: Antiwear performance and mechanism of an oil-miscible ionic liquid as a lubricant additive. ACS Appl. Mater. Interfaces. 4, 997–1002 (2012)
Xiao, H.: Ionic liquid lubricants: basics and applications. Tribol. Trans. 60, 20–30 (2017)
Srour, H., Rouault, H., Santini, C.C., Chauvin, Y.: A silver and water free metathesis reaction: a route to ionic liquids. Green Chem. 15, 1341–1347 (2013)
Kasrai, M., Cutler, J., Gore, K., Canning, G., Bancroft, G., Tan, K.: The chemistry of antiwear films generated by the combination of ZDDP and MoDTC examined by X-ray absorption spectroscopy. Tribol. Trans. 41, 69–77 (1998)
Morina, A., Neville, A., Priest, M., Green, J.: ZDDP and MoDTC interactions in boundary lubrication—The effect of temperature and ZDDP/MoDTC ratio. Tribol. Int. 39, 1545–1557 (2006)
Morina, A., Neville, A., Priest, M., Green, J.: ZDDP and MoDTC interactions and their effect on tribological performance—Tribofilm characteristics and its evolution. Tribol. Lett. 24, 243–256 (2006)
Somers, A., Howlett, P., MacFarlane, D., Forsyth, M.: A review of ionic liquid lubricants. Lubricants 1, 3 (2013)
Zhou, Y., Qu, J.: Ionic liquids as lubricant additives: a review. ACS Appl. Mater. Interfaces. 9, 3209–3222 (2017)
Qu, J., Bansal, D.G., Yu, B., Howe, J.Y., Luo, H., Dai, S., Li, H., Blau, P.J., Bunting, B.G., Mordukhovich, G., Smolenski, D.J.: Antiwear performance and mechanism of an oil-miscible ionic liquid as a lubricant additive. ACS Appl. Mater. Interfaces. 4, 997–1002 (2012)
Somers, A.E., Khemchandani, B., Howlett, P.C., Sun, J., MacFarlane, D.R., Forsyth, M.: Ionic liquids as antiwear additives in base oils: influence of structure on miscibility and antiwear performance for steel on aluminum. ACS Appl. Mater. Interfaces. 5, 11544–11553 (2013)
Sun, Y.-X., Wang, Y.-Y., Shen, B.-B., Zhang, B.-X., Hu, X.-M.: Synthesis and investigation of physico-chemical properties of dicationic ionic liquids. R. Soc. Open Sci. 5, 181230 (2018)
Liu, W., Ye, C., Gong, Q., Wang, H., Wang, P.: Tribological performance of room-temperature ionic liquids as lubricant. Tribol. Lett. 13, 81–85 (2002)
Wang, H., Lu, Q., Ye, C., Liu, W., Cui, Z.: Friction and wear behaviors of ionic liquid of alkylimidazolium hexafluorophosphates as lubricants for steel/steel contact. Wear 256, 44–48 (2004)
Lu, Q., Wang, H., Ye, C., Liu, W., Xue, Q.: Room temperature ionic liquid 1-ethyl-3-hexylimidazolium-bis(trifluoromethylsulfonyl)-imide as lubricant for steel–steel contact. Tribol. Int. 37, 547–552 (2004)
Zhang, L., Feng, D., Xu, B.: Tribological characteristics of alkylimidazolium diethyl phosphates ionic liquids as lubricants for steel–steel contact. Tribol. Lett. 34, 95–101 (2009)
Jiménez, A., Bermúdez, M., Iglesias, P., Carrión, F., Martínez-Nicolás, G.: 1-N-alkyl -3-methylimidazolium ionic liquids as neat lubricants and lubricant additives in steel–aluminium contacts. Wear 260, 766–782 (2006)
Amorim, P.M., Ferraria, A.M., Colaço, R., Branco, L.C., Saramago, B.: Imidazolium-based ionic liquids used as additives in the nanolubrication of silicon surfaces. Beilstein J. Nanotechnol. 8, 1961–1971 (2017)
Cai, M., Liang, Y., Yao, M., Xia, Y., Zhou, F., Liu, W.: Imidazolium ionic liquids as antiwear and antioxidant additive in Poly(ethylene glycol) for steel/steel contacts. ACS Appl. Mater. Interfaces 2, 870–876 (2010)
Kirchner, B.: Ionic Liquids, pp. 213–262. Springer, Berlin (2008)
García, A., González, R., Battez, A.H., Viesca, J., Monge, R., Fernández-González, A., Hadfield, M.: Ionic liquids as a neat lubricant applied to steel–steel contacts. Tribol. Int. 72, 42–50 (2014)
Pandey, P., Somers, A.E., Hait, S.K., Forsyth, M., Ramakumar, S.S.V.: A novel approach to improve the oil miscibility and incorporate multifunctionality in ionic liquids as lubricant additives. Phys. Chem. Chem. Phys. 23, 3429 (2021)
Pandey, P., Somers, A.E., Hait, S.K., Forsyth, M., Ramakumar, S.S.V.: Study of phosphonium based ionic liquid/dispersant additive interactions using spectroscopic technique for lubricant applications. J. Mol. Liq. (2021). https://doi.org/10.1016/j.molliq.2021.116665
Batıgöç, Ç., Akbaş, H., Boz, M.: Thermodynamics of non-ionic surfactant Triton X-100-cationic surfactants mixtures at the cloud point. J. Chem. Thermodyn. 43, 1800–1803 (2011)
Rajathi, K., Rajendran, A.: Synthesis, characterization and biological evaluation of imidazolium based ionic liquids. Res. Rev. J. Chem. 2, 36 (2013)
Williamson, C.L., Maly, K.E., MacNeil, S.L.: Synthesis of imidazolium room-temperature ionic liquids: a follow-up to the procedure of Dzyuba, Kollar, and Sabnis. J. Chem. Educ. 90, 799–801 (2013)
Khatri, O. P., Gusain, R.: Halogen free ionic liquids as lubricant or lubricant additives and a process for the preparation thereof. US20170096614A1 (2017)
Rajkumar, T., Rao, G.R.: Synthesis and characterization of hybrid molecular material prepared by ionic liquid and silicotungstic acid. Mater. Chem. Phys. 112, 853–857 (2008)
Berzina-Cimdina, L., Borodajenko, N.: Research of calcium phosphates using Fourier transform infrared spectroscopy. Infrared Spectrosc. Mater. Sci. Eng. Technol. 12(7), 251–263 (2012)
Labidi, N.S., Iddou, A.: Adsorption of oleic acid on quartz/water interface. J. Saudi Chem. Soc. 11, 221–234 (2007)
Beliciu, C., Moraru, C.: Effect of solvent and temperature on the size distribution of casein micelles measured by dynamic light scattering. J. Dairy Sci. 92, 1829–1839 (2009)
Darabi, L., Zare, M.: Theoretical study on the structure and electronic properties of alkylimidazolium iodide ionic liquids: the effect of alkyl chain length. New J. Chem. 44, 4023–4032 (2020)
Marx, N., Fernández, L., Barceló, F., Spikes, H.: Shear thinning and hydrodynamic friction of viscosity modifier-containing oils. Part I: shear thinning behaviour. Tribol. Lett. 66, 92 (2018)
Spikes, H.A.: Film-forming additives—direct and indirect ways to reduce friction. Lubr. Sci. 14, 147–167 (2002)
Ye, Q., Liu, S., Zhang, J., Xu, F., Zhou, F., Liu, W.: Superior lubricity and antiwear performances enabled by porous carbon nanospheres with different shell microstructures. ACS Sustain. Chem. Eng. 7(14), 12527–12535 (2019)
Minami, I.: Ionic liquids in tribology. Molecules 14, 2286 (2009)
Khan, A., Gusain, R., Khatri, O.P.: Organophosphate anion based low viscosity ionic liquids as oil-miscible additives for lubrication enhancement. J. Mol. Liquids 272, 430–438 (2018)
Ghatee, M.H., Zare, M., Moosavi, F., Zolghadr, A.R.: Temperature-dependent density and viscosity of the ionic liquids 1-Alkyl-3-methylimidazolium Iodides: experiment and molecular dynamics simulation. J. Chem. Eng. Data 55, 3084–3088 (2010)
Yu, B., Bansal, D.G., Qu, J., Sun, X., Luo, H., Dai, S., Blau, P.J., Bunting, B.G., Mordukhovich, G., Smolenski, D.J.: Oil-miscible and non-corrosive phosphonium-based ionic liquids as candidate lubricant additives. Wear 289, 58–64 (2012)
Grossiord, C., Martin, J.M., Varlot, K., Vacher, B., Le Mogne, T., Yamada, Y.: Tribochemical interactions between Zndtp, Modtc and calcium borate. Tribol. Lett. 8, 203–212 (2000)
Pulles, T., van der Gon, H.D., Appelman, W., Verheul, M.: Emission factors for heavy metals from diesel and petrol used in European vehicles. Atmos. Environ. 61, 641–651 (2012)
Yang, H., Guo, R., Wang, H.J.C.: Lubrication of the mixed system of Triton X-100/n-C10H21OH/H2O lamellar liquid crystal and ZnS nanoparticles. Colloids Surf. Physicochem Eng. Aspects 180, 243–251 (2001)
Kontou, A., Southby, M., Morgan, N., Spikes, H.: The role of the Counterbody’s oxide on the wear behavior of HSS and Hi-Cr. Tribol. Lett. 66, 1–15 (2018)
Gusain, R., Khatri, O.P.: Fatty acid ionic liquids as environmentally friendly lubricants for low friction and wear. RSC Adv. 6, 3462–3469 (2016)
Cao, H., Hu, Y., Xu, W., Wang, Y., Guo, X.: Recent progress in the assembly behavior of imidazolium-based ionic liquid surfactants. J. Mol. Liquids 319, 114354 (2020)
Somers, A.E., Biddulph, S.M., Howlett, P.C., Sun, J., MacFarlane, D.R., Forsyth, M.: A comparison of phosphorus and fluorine containing IL lubricants for steel on aluminium. Phys. Chem. Chem. Phys. 14, 8224–8231 (2012)
Acknowledgements
The author is thankful to the management of Indian Oil Corporation Ltd Research & Development Centre and Deakin University for granting fellowship under Deakin-India Research Fellowship Programme and providing permission to publish this paper.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
There are no known conflicts of interest and competing financial interests that could have influence on the work reported here.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Pandey, P., Somers, A.E., Hait, S.K. et al. Short Chain Imidazolium Ionic Liquids: Synthesis and Oil Miscibility in Various Base Oil by use of Surfactant as High Performance Friction and Antiwear Lubricant Additive. Tribol Lett 69, 95 (2021). https://doi.org/10.1007/s11249-021-01472-4
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11249-021-01472-4