Abstract
Fluorinated graphene (FG) with various fluorine/carbon (F/C) ratios and graphene (G) employed as additions were incorporated into the polytetrafluoroethylene (PTFE) matrix aiming to improve the tribological properties of this self-lubricating polymer. The friction coefficients and wear rates of PTFE-based composites were tested under dry sliding condition using a ball-on-disc configuration. The performances of self-lubricity and wear resistance for four fabricated FG/PTFE composites were superior to those of G/PTFE composite, attributable to the specific surface area and chemical composition of FG sheets with various F/C ratios. Among them, the FG/PTFE composite with filler (F/C ≈ 0.5) loading of 5 wt% exhibited the best tribological property, i.e., the lowest friction coefficient (0.131) and the smallest steady-state wear rate (9.20 × 10–16 m3/Nm). This can be attributed to the formation of uniform and complete transfer film on the friction interface via the tribochemical reactions.
Graphic Abstract
Similar content being viewed by others
References
Blanchet, T.A., Kennedy, F.E.: Sliding wear mechanism of polytetrafluoroethylene (PTFE) and PTFE composites. Wear 153, 229–243 (1992)
Burris, D.L., Boesl, B., Bourne, G.R., Sawyer, W.G.: Polymeric nanocomposites for tribological applications. Macromol. Mater. Eng. 292, 387–402 (2007)
Blanchet, T.A., Kandanur, S.S., Schadler, L.S.: Coupled effect of filler content and countersurface roughness on PTFE nanocomposite wear resistance. Tribol. Lett. 40(1), 11–21 (2010)
Bahadur, S., Gong, D.: The action of fillers in the modification of the tribological behavior of polymers. Wear 158, 41–59 (1992)
Zuo, Z., Song, L.Z., Yang, Y.L.: Tribological behavior of polyethersulfone-reinforced polytetrafluoroethylene composite under dry sliding condition. Tribol. Int. 86, 17–27 (2015)
Pan, D., Fan, B.L., Qi, X.W., Yang, Y.L., Hao, X.H.: Investigation of PTFE tribological properties using molecular dynamics simulation. Tribol. Lett. 67, 28 (2019)
Zhao, Y.L., Qi, X.W., Zhang, W.L., Fan, B.L., Yang, Q.X.: Effects of copper nanoparticles located in different regions of polytetrafluoroethylene/polyimide blends on the morphology, mechanical and tribological properties of PTFE composites. Tribol. Lett. 67, 18 (2019)
Song, L.Z., Han, K.D., Zuo, Z., Yang, Y.L., Wang, X.L.: Tribological properties of α-, and β-manganese dioxide/polytetrafluoroethylene composites under the dry sliding condition. Tribol. Int. 94, 187–197 (2016)
Blanchet, T.A.: A model for polymer composite wear behavior including preferential load support and surface accumulation of filler particulates. Tribol. Trans. 38, 821–828 (1995)
Sawyer, W.G., Freudenberg, K.D., Bhimaraj, P., Schadler, L.S.: A study on the friction and wear behavior of PTFE filled with alumina nanoparticles. Wear 254, 573–580 (2003)
Burris, D.L., Sawyer, W.G.: Improved wear resistance in alumina-PTFE nanocomposites with irregular shaped nanoparticles. Wear 260, 915–918 (2006)
Burris, D.L., Zhao, S., Duncan, R., Lowitz, J., Perry, S.S., Schadler, L.S., Sawyer, W.G.: A route to wear resistant PTFE via trace loadings of functionalized nanofillers. Wear 267, 653–660 (2006)
Krick, B.A., Pitenis, A.A., Harris, K.L., Junk, C.P., Sawyer, W.G., Brown, S.C., Rosenfeld, H.D., Kasprzak, D.J., Johnson, R.S., Chan, C.D., Blackman, G.S.: Ultralow wear fluoropolymer composites: nanoscale functionality from microscale fillers. Tribol. Int. 95, 245–255 (2016)
Pitenis, A.A., Ewin, J.J., Harris, K.L., Sawyer, W.G., Krick, B.A.: In vacuo tribological behavior of polytetrafluoroethylene (PTFE) and alumina nanocomposites: the importance of water for ultralow wear. Tribol. Lett. 53, 189–197 (2014)
Pitenis, A.A., Harris, K.L., Junk, C.P., Blackman, G.S., Sawyer, W.G., Krick, B.A.: Ultralow wear PTFE and alumina composites: it is all about tribochemistry. Tribol. Lett. 57, 4 (2015)
Harris, K.L., Pitenis, A.A., Sawyer, W.G., Krick, B.A., Blackman, G.S., Kasprzak, D.J., Junk, C.P.: PTFE tribology and the role of mechanochemistry in the development of protective surface films. Macromolecules 48, 3739–3745 (2015)
Kandanur, S.S., Rafiee, M.A., Yavari, F., Schrameyer, M., Yu, Z.Z., Blanchet, T.A., Koratkar, N.: Suppression of wear in graphene polymer composites. Carbon 50(9), 3178–3183 (2012)
Kandanur, S.S., Schrameyer, M.A., Jung, K.F., Makowiec, M.E., Bhargava, S., Blanchet, T.A.: Effect of activated carbon and various other nanoparticle fillers on PTFE wear. Tribol. Trans. 57, 821–830 (2014)
Makowiec, M.E., Blanchet, T.A.: Improved wear resistance of nanotube- and other carbon-filled PTFE composites. Wear 374–375, 77–85 (2017)
Bhargava, S., Makowiec, M.E., Blanchet, T.A.: Wear reduction mechanisms within highly wear-resistant graphene- and other carbon-filled PTFE nanocomposites. Wear 444–445, 203163 (2020)
Bhargava, S., Koratkar, N., Blanchet, T.A.: Effect of platelet thickness on wear of graphene-polytetrafluoroethylene (PTFE) composites. Tribol. Lett. 59, 17 (2015)
Bahadur, S.: The development of transfer layers and their role in polymer tribology. Wear 245, 92–99 (2000)
Berman, D., Erdemir, A., Sumant, A.V.: Graphene: a new emerging lubricant. Mater. Today 17(1), 31–42 (2014)
Samarakoon, D.K., Chen, Z., Nicolas, C., Wang, X.Q.: Structural and electronic properties of fluorographene. Small 7(7), 965–969 (2011)
Min, C.Y., He, Z.B., Song, H.J., Liang, H.Y., Liu, D.D., Dong, C.K., Jia, W.: Fluorinated graphene oxide nanosheet: a highly efficient water-based lubricated additive. Tribol. Int. 140, 105867 (2019)
Huang, W., Pei, Q.X., Liu, Z., Zhang, Y.W.: Thermal conductivity of fluorinated graphene: a non-equilibrium molecular dynamics study. Chem. Phys. Lett. 552, 97–101 (2012)
Wang, L.F., Ma, T.B., Hu, Y.Z., Wang, H., Shao, T.M.: Ab Initio study of the friction mechanism of fluorographene and graphane. J. Phys. Chem. C 117(24), 12520–12525 (2013)
Rubio-Roy, M., Corbella, C., Bertran, E., Portal, S., Polo, M.C., Pascual, E., Andújar, J.L.: Effects of environmental conditions on fluorinated diamond-like carbon tribology. Diamond Relat. Mater. 18, 923–926 (2009)
Matsumura, K., Chiashi, S., Maruyama, S., Choi, J.: Macroscale tribological properties of fluorinated graphene. Appl. Surf. Sci. 432, 190–195 (2018)
Hou, K.M., Gong, P.P., Wang, J.Q., Yang, Z.G., Ma, L.M., Yang, S.R.: Construction of highly ordered fluorinated graphene composite coatings with various fluorine contents for enhanced lubrication performance. Tribol. Lett. 60, 6 (2015)
Ye, X.Y., Liu, X.H., Yang, Z.G., Wang, Z.F., Wang, H.G., Wang, J.Q., Yang, S.R.: Tribological properties of fluorinated graphene reinforced polyimide composite coatings under different lubricated conditions. Compos. A 81, 282–288 (2016)
Zhou, S.G., Li, W.T., Zhao, W.J., Liu, C., Fang, Z.W., Gao, X.L.: Tribological behaviors of polyimide composite films enhanced with fluorographene. Colloids Surf. A 580, 123707 (2019)
Li, W.T., Zhao, W.J., Mao, L.S., Zhou, S.G., Liu, C., Fang, Z.W., Gao, X.L.: Investigating the fluorination degree of FG nanosheets on the tribological properties of FG/PI composite coatings. Prog. Org. Coat. 139, 105481 (2020)
Padenko, E., Rooyen, L.J., Karger-Kocsis, J.: Transfer film formation in PTFE/oxyfluorinated graphene nanocomposites during dry sliding. Tribol. Lett. 65(2), 36 (2017)
Xu, L., Zheng, Y., Yan, Z., Zhang, W.: Preparation, tribological properties and biocompatibility of fluorinated graphene/ultrahigh molecular weight polyethylene composite materials. Appl. Surf. Sci. 370, 201–208 (2016)
Sun, L., Yan, Z.J., Duan, Y.X., Zhang, J.Y., Liu, B.: Improvement of the mechanical, tribological and antibacterial properties of glass ionomer cements by fluorinated graphene. Dent. Mater. 34, 115–127 (2018)
Thomas, P., Himmel, D., Mansot, J.L., Dubois, M., Guérin, K., Zhang, W., Hamwi, A.: Tribological properties of fluorinated carbon nanofibres. Tribol. Lett. 34, 49–59 (2009)
Delbé, K., Thomas, P., Himmel, D., Mansot, J.L., Dubois, M., Guérin, K., Delabarre, C., Hamwi, A.: Tribological properties of room temperature fluorinated graphite heat-treated under fluorine atmosphere. Tribol. Lett. 37, 31–41 (2010)
Thomas, P., Himmel, D., Mansot, J.L., Zhang, W., Dubois, M., Guérin, K., Hamwi, A.: Friction properties of fluorinated carbon nanodiscs and nanocones. Tribol. Lett. 41, 353–362 (2011)
Thomas, P., Mansot, J.L., Molza, A., Begarin, F., Dubois, M., Guérin, K.: Friction properties of fluorinated graphitized carbon blacks. Tribol. Lett. 56, 259–271 (2014)
Burris, D.L., Sawyer, W.G.: Measurement uncertainties in wear rates. Tribol. Lett. 36(1), 81–87 (2009)
Zboril, R., Karlicky, F., Bourlinos, A.B., Steriotis, T.A., Stubos, A.K.: Graphene fluoride: a stable stoichiometric graphene derivative and its chemical conversion to graphene. Small 6(24), 2885–2891 (2010)
Wang, X., Dai, Y.Y., Wang, W.M., Ren, M.M., Li, B.Y., Fan, C., Liu, X.Y.: Fluorographene with high fluorine/carbon ratio: a nanofiller for preparing low-κ polyimide hybrid film. ACS Appl. Mater. Inter. 6, 16182–16188 (2014)
Wu, Y.M., Zhao, W.J., Qiang, Y.J., Chen, Z.J., Wang, L.P., Gao, X.L., Fang, Z.W.: π–π interaction between fluorinated reduced graphene oxide and acridizinium ionic liquid: synthesis and anti-corrosion application. Carbon 159, 292–302 (2020)
Robinson, J.T., Burgess, J.S., Junkermeier, C.E., Badescu, S.C., Reinecke, T.L., Perkins, F.K., Zalalutdniov, M.K., Baldwin, J.W., Culbertson, J.C., Sheehan, P.E., Snow, E.S.: Properties of fluorinated graphene films. Nano Lett. 10(8), 3001–3005 (2010)
Sato, Y., Itoh, K., Hagiwara, R., Fukunaga, T., Ito, Y.: On the so called “semi-ionic” C–F bond character in fluorine-GIC. Carbon 42(15), 3243–3249 (2004)
Lee, J.H., Koon, G.K.W., Shin, D.W., Fedorov, V.E., Choi, J.Y., Yoo, J.B., Ozyilmaz, B.: Property control of graphene by employing “semi-ionic” liquid fluorination. Adv. Funct. Mater. 23, 3329–3334 (2013)
Zhou, S., Sherpa, S.D., Hess, D.W., Bongiorno, A.: Chemical bonding of partially fluorinated graphene. J. Phys. Chem. C 118, 26402–26408 (2014)
Feng, W., Long, P., Feng, Y.Y., Li, Y.: Two-dimensional fluorinated graphene: synthesis, structures, properties and applications. Adv. Sci. 3(7), 1500413 (2016)
Aderikha, V.N., Shapovalov, V.A.: Effect of filler surface properties on structure, mechanical and tribological behavior of PTFE-carbon black composites. Wear 268(11–12), 1455–1464 (2010)
Saravanan, P., Selyanchyn, R., Tanaka, H., Fujikawa, S., Lyth, S.M., Sugimura, J.: Ultra-low friction between polymers and graphene oxide multilayers in nitrogen atmosphere, mediated by stable transfer film formation. Carbon 122, 395–403 (2017)
Roosendaal, S.J., van Asselen, B., Elsenaar, J.M., Vredenberg, A.M., Habraken, F.H.P.M.: The oxidation state of Fe (100) after initial oxidation in O2. Surf. Sci. 442, 329–337 (1999)
Tan, B.J., Klabunde, K.J., Sherwood, P.M.A.: X-ray photoelectron spectroscopy studies of solvated metal atom dispersed catalysts. Monometallic iron and bimetallic iron-cobalt particles on alumina. Chem. Mater. 2, 186–191 (1990)
McIntyre, N.S., Zetaruk, D.G.: X-ray photoelectron spectroscopic studies of iron oxides. Anal. Chem. 49, 1521–1529 (1977)
Hawn, D.D., DeKoven, B.M.: Deconvalution as a correction for photoelectron inelastic energy losses in the core level XPS spectra of iron oxides. Surf. Interface Anal. 10, 63–74 (1987)
Ci, X.J., Zhao, W.J., Luo, J., Wu, Y.M., Ge, T.H., Shen, L., Gao, X.L., Fang, Z.W.: Revealing the lubrication mechanism of fluorographene nanosheets enhanced GTL-8 based nanolubricant oil. Tribol. Int. 138, 174–183 (2019)
Author information
Authors and Affiliations
Corresponding authors
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Liang, L., Song, L., Yang, Y. et al. Tribological Properties of Polytetrafluoroethylene Improved by Incorporation of Fluorinated Graphene with Various Fluorine/Carbon Ratios Under Dry Sliding Condition. Tribol Lett 69, 21 (2021). https://doi.org/10.1007/s11249-020-01398-3
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11249-020-01398-3