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A family of 1D coordination polymers based on Ln–Cu 15-metallacrown-5 units with two topological sorting: syntheses, structures, and single-chain magnet behaviour

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Abstract

Three one-dimensional coordination polymers based on Ln–Cu 15-metallacrown-5 units were self-assembled via covalent bonds between pyrazine hydroxamic acid ligands and Cu atoms in the adjacent MC units. Due to the presence of different coordination anion ligands, complexes TbIII (1) and GdIII (2) show zig-zag-like topological structures, while complex DyIII (3) displays wheatear-like topological structure. The frequency dependence of the out-of-phase reveals that complexes 1 and 2 show slow relaxation of the magnetization, and complex 3 displays single-chain magnet behaviour.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 21671093 and 21271097).

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Authors and Affiliations

  1. Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, 252059, People’s Republic of China

    Man-Yun Zhuang, Hua Yang, Hong-Gang Zhang, Hai-Quan Tian, Da-Cheng Li & Jian-Min Dou

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  1. Man-Yun Zhuang
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  2. Hua Yang
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  3. Hong-Gang Zhang
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  4. Hai-Quan Tian
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Correspondence to Hua Yang or Jian-Min Dou.

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11243_2022_497_MOESM1_ESM.docx

CCDC 2041611 (1), CCDC 2041611 (2) and 2041613 (3) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif. Supplementary data to this article can be found online. (DOCX 1751 kb)

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Zhuang, MY., Yang, H., Zhang, HG. et al. A family of 1D coordination polymers based on Ln–Cu 15-metallacrown-5 units with two topological sorting: syntheses, structures, and single-chain magnet behaviour. Transit Met Chem 47, 139–146 (2022). https://doi.org/10.1007/s11243-022-00497-5

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  • DOI: https://doi.org/10.1007/s11243-022-00497-5

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