Abstract
Two trinuclear Ni(II) and Cu(II) coordination compounds [{Ni(L1)(C2H5OH)}2(μ-OAc)2Ni]·2C2H5OH (1) and [{Cu(L2)(CH3OH)}2(μ-OAc)2Cu]·2CH3OH (2) constructed from asymmetrical Salamo-type ligands H2L1 and H2L2 (H2L1 = 5-(N,Nʹ-diethylamino)-2,2ʹ-[ethylenediyldioxybis(nitrilomethylidyne)]diphenol and H2L2 = 2,2ʹ-[ethylenediyldioxybis(nitrilomethylidyne)]naphtholphenol) were synthesized and characterized by physicochemical and spectroscopic methods. Complex 1 is a centrosymmetrical trinuclear Ni(II) coordination compound. Three hexa-coordinated Ni(II) atoms have slightly distorted octahedral geometries. Complex 2 contains three hexa-coordinated Cu(II) atoms bearing distorted octahedral geometries too. In addition, the thermal analyses and Hirshfeld surfaces analyses of complexes 1 and 2 have been discussed in detail.
Similar content being viewed by others
References
Wu HL, Pan GL, Bai YC, Wang H, Kong J (2015) Res Chem Intermed 41:3375
Song XQ, Liu PP, Liu YA, Zhou JJ, Wang XL (2016) Dalton Trans 45:8154
Liu PP, Sheng L, Song XQ, Xu WY, Liu YA (2015) Inorg Chim Acta 434:252
Li LH, Dong WK, Zhang Y, Akogun SF, Xu L (2017) Appl Organomet Chem 31:e3818
Chen CY, Zhang JW, Zhang YH, Yang ZH, Wu HL (2015) J Coord Chem 68:1054
Hao J, Li XY, Zhang Y, Dong WK (2018) Materials 11:523
Wang F, Gao L, Zhao Q, Zhang Y, Dong WK, Ding YJ (2018) Spectrochim Acta Part A 190:111
Dong XY, Zhao Q, Kang QP, Li XY, Dong WK (2018) Crystals 8:230
Dong XY, Gao L, Wang F, Zhang Y, Dong WK (2018) Chin J Inorg Chem 34:739
Dong XY, Kang QP, Li XY, Ma JC, Dong WK (2018) Crystals 8:139
Li J, Zhang HJ, Chang J, Jia HR, Sun YX, Huang YQ (2018) Crystals 8:176
Akine S, Taniguchi T, Nabeshima T (2001) Chem Lett 30:682
Wang L, Hao J, Zhai LX, Zhang Y, Dong WK (2017) Crystals 7:277
Chang J, Zhang HJ, Jia HR, Sun YX (2018) Chin J Inorg Chem 34:2097
Zhang HJ, Chang J, Jia HR, Sun YX (2018) Chin J Inorg Chem 34:2261
Zhang LW, Liu LZ, Wang F, Dong WK (2018) Molecules 23:1141
Guo JQ, Sun YX, Yu B, Li J, Jia HR (2017) Chin J Inorg Chem 33:1481
Jia HR, Chang J, Zhang HJ, Li J, Sun YX (2018) Crystals 8:272
Dong WK, Ma JC, Zhu LC, Zhang Y, Li XL (2016) Inorg Chim Acta 445:140
Dong WK, Ma JC, Zhu LC, Zhang Y (2016) New J Chem 40:6998
Akine S, Taniguchi T, Dong WK, Masubuchi S, Nabeshima T (2005) J Org Chem 70:1704
Dong WK, Zhang F, Li N, Xu L, Zhang Y, Zhang J, Zhu LC (2016) Z Anorg Allg Chem 642:532
CrysAlisPRO (2014) Agilent Technologies Ltd, Yarnton, Oxfordshire, England
Palatinus L, van der Lee A (2008) J Appl Cryst 41:975
Palatinus L, Prathapa SJ, van Smaalen S (2012) J Appl Cryst 45:575
Sheldrick GM (2016) SHELXS-2016, program for crystal structure solution. University of Göttingen, Göttingen
Sheldrick GM (2016) SHELXL-2016, program for crystal structure refinement. University of Göttingen, Göttingen
Gao L, Wang F, Zhao Q, Zhang Y, Dong WK (2018) Polyhedron 139:7
Hao J, Liu LZ, Dong WK, Zhang J, Zhang Y (2017) J Coord Chem 70:1936
Peng YD, Wang F, Gao L, Dong WK (2018) J Chin Chem Soc 65:893
Wang L, Hao J, Dong YJ, Dong XY, Dong WK (2018) J Struct Chem 59:928
Zhang Y, Liu LZ, Pan YQ, Dong WK (2018) Crystals 8:259
Sun YX, Liu LZ, Wang F, Shang XY, Chen L, Dong WK (2018) Crystals 8:227
Su Q, Zhao Q, An XX, Wang YB, Li XY, Dong WK (2019) Chin J Inorg Chem 35:524
Zhao Q, Wei ZL, Kang QP, Zhang H, Dong WK (2018) Spectrochim Acta Part A 203:472
Acknowledgements
Fundings from the National Science Foundation (21761018) and the Program for Excellent Team of Scientific Research in Lanzhou Jiaotong University (201706) are gratefully acknowledged.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Zhang, Y., Liu, LZ., Peng, YD. et al. Structurally characterized trinuclear nickel(II) and copper(II) Salamo-type complexes: syntheses, Hirshfeld analyses and fluorescent properties. Transit Met Chem 44, 627–639 (2019). https://doi.org/10.1007/s11243-019-00325-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11243-019-00325-3