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Catalytic Properties of Rh-Containing Carbon Dots on SiO2, Al2O3, and ZrO2 Oxide Supports in the Glycerol Conversion

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Theoretical and Experimental Chemistry Aims and scope

It is shown that deposition of Rh-CD (CDs are carbon dots)onto SiO2, Al2O3, and ZrO2 oxide supports contributes to the appearance of the catalytic activity in the process of glycerol conversion. It is established that acrolein and acetaldehyde are oxygen-containing products in this reaction system. It is found that the yield of reaction products increases when using a support with a smaller specific surface area, which is caused by an increase in the surface concentration of acid sites.

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Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, NAS of Ukraine, Kyiv, Ukraine

    G. R. Kosmambetova, N. V. Vlasenko, V. I. Grytsenko & O. V. Shvets

  2. V. I. Vernadsky Institute of General and Inorganic Chemistry, NAS of Ukraine, Kyiv, Ukraine

    L. B. Kharkova, O. H. Yanko & V. M. Ogenko

Authors
  1. G. R. Kosmambetova
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  2. N. V. Vlasenko
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  3. L. B. Kharkova
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  4. O. H. Yanko
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  5. V. M. Ogenko
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  6. V. I. Grytsenko
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  7. O. V. Shvets
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Corresponding author

Correspondence to G. R. Kosmambetova.

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Translated from Teoretychna ta Eksperymentalna Khimiya, Vol. 59, No. 3, pp. 173-178, May-June, 2023

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Kosmambetova, G.R., Vlasenko, N.V., Kharkova, L.B. et al. Catalytic Properties of Rh-Containing Carbon Dots on SiO2, Al2O3, and ZrO2 Oxide Supports in the Glycerol Conversion. Theor Exp Chem 59, 200–206 (2023). https://doi.org/10.1007/s11237-023-09779-0

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  • DOI: https://doi.org/10.1007/s11237-023-09779-0

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