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Energy of Atom Delocalization and Thermal Motion in the Region of Vitrification

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A linear correlation has been established between the empirical parameter D of the Enkel equation for the viscosity and the vitrification temperature Tg of inorganic glasses, which is discussed within the framework of the model of delocalized atoms. From an analysis of this correlation, certain information on the vitrification and the viscous flow of glass-forming liquids follows. The value of D is an unambiguous function of the atom delocalization energy.

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References

  1. D. S. Sanditov and G. M. Bartenev, Physical Properties of Disordered Structures [in Russian], Nauka, Novosibirsk (1982).

  2. D. S. Sanditov, Sov. Phys. J., 14, No. 2, 151–156 (1971).

    Google Scholar 

  3. D. S. Sanditov, I. V. Razumovskaya, G. Bartenev, and I. A. Luk’yanov, Sov. Phys. J., 11, No. 11, 72–79 (1968).

    Article  Google Scholar 

  4. G. Meerlender, Rheol. Acta, 6, Nо. 4, 309–377 (1967).

  5. E. Jenckel, Z. Physik. Chem., 184, No. 1, 309–319 (1939).

  6. D. S. Sanditov, Dokl. Akad. Nauk, 451, No. 6, 650–654 (2013).

    Google Scholar 

  7. D. S. Sanditov and M. I. Ojovan, Physica B, 523, 96–113 (2017).

    Article  ADS  Google Scholar 

  8. D. S. Sanditov, Zh. Eksp. Teor. Fiz., 142, 1 (7), 123–137 (2012).

  9. D. S. Sanditov, S. S. Badmaev, B. D. Sanditov, and B. S. Sydykov, Russ. Phys. J., 57, No. 4, 441–450 (2012).

    Article  Google Scholar 

  10. MDL® SciGlass – 7.8, Institute of Theoretical Chemistry, Shrewsbury, MA (2012); www.sciglass.info.

  11. A. I. Burshtein, Molecular Physics [in Russian], Nauka, Novosibirsk (1986).

  12. D. S. Sanditov, Zh. Eksp. Teor. Fiz., 150, 3 (9), 501–515 (2016).

  13. N. Kauzmann, Chem. Rev., No. 2, 219–256 (1948).

    Article  Google Scholar 

  14. S. V. Nemilov, Fiz. Khim. Stekla, 6, No. 3, 257–268 (1980).

    Google Scholar 

  15. I. V. Razumovskaya and G. M. Bartenev, in: Glassy State, Proc. of the Vth All-Union Meeting on Glassy State [in Russian], Nauka, Leningrad (1971), pp. 34–39.

  16. D. S. Sanditov, Dokl. Akad. Nauk, 461, No. 5, 542–545 (2015).

    Google Scholar 

  17. D. S. Sanditov, Zh. Eksp. Teor. Fiz., 138, 3 (9), 912–924 (2010).

  18. A. I. Slutsker, Yu. I. Polikarpov, and D. D. Karpov, Vysokomolek. Soed. Ser. А, 53, No. 11, 1916–1920 (2011).

    Google Scholar 

  19. D. S. Sanditov and B. S. Sydykov, Zh. Tekh. Fiz., 84, No. 5, 52–54 (2014).

    Google Scholar 

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Correspondence to D. S. Sanditov.

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Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 6, pp. 129–134, June, 2019.

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Sanditov, D.S., Darmaev, M.V. Energy of Atom Delocalization and Thermal Motion in the Region of Vitrification. Russ Phys J 62, 1066–1072 (2019). https://doi.org/10.1007/s11182-019-01815-8

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  • DOI: https://doi.org/10.1007/s11182-019-01815-8

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