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Palladium carboxylate π-complexes with unsaturated hydrocarbons and the reactions catalyzed by them

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Abstract

This review summarizes the studies on the palladium carboxylate π-complexes with unsaturated hydrocarbons (alkenes, alkynes, and arenes) as well as with N-heterocyclic carbenes, phosphonyl-substituted ferrocene ligands, etc. In these complexes the palladium atoms are coordinated with unsaturated hydrocarbons via the carbon atoms forming the multiple bonds. These complexes are traditional objects in fundamental coordination chemistry including chemistry of polynuclear compounds. They are also applied as pre-catalysts and as model intermediates for catalytic transformations of unsaturated hydrocarbons, e.g., oxidation and isomerization of alkenes, hydrogenation and coupling reactions of alkenes, alkynes, and arenes.

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This work was financially supported by the Russian Science Foundation (Project No. 23-73-00123).

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Authors and Affiliations

  1. M. V. Lomonosov Institute of Fine Chemical Technologies, MIREA — Russian Technological University, 86 prosp. Vernadskogo, 119571, Moscow, Russian Federation

    O. N. Shishilov, S. A. Durakov & V. R. Flid

  2. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 49 Leninsky prosp., 119991, Moscow, Russian Federation

    N. S. Akhmadullina

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  1. O. N. Shishilov
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Dedicated to Academician of the Russian Academy of Sciences M. P. Egorov on the occasion of his 70th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 73, No. 2, pp. 297–327, February, 2024.

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Shishilov, O.N., Durakov, S.A., Akhmadullina, N.S. et al. Palladium carboxylate π-complexes with unsaturated hydrocarbons and the reactions catalyzed by them. Russ Chem Bull 73, 297–327 (2024). https://doi.org/10.1007/s11172-024-4139-4

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