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Nickel complex-catalyzed codimerization of allyl esters with compounds in the norbornene series

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The basic principles governing the cyclocodimerization of norbornene with allyl compounds have been elucidated for their reaction in the presence of a three-component catalyst system, Ni(acac)2-P(OR)3-AlR′3 (or MgR″2); a highly selective method has also been developed for the introduction of a methylenecyclobutane fragment to a norbornene hydrocarbon derivative.

  2. 2.

    A new Ni complex has been prepared; it appears to be the catalyst which is active for the cyclocodimerization of norbornene with allylic compounds.

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Authors and Affiliations

  1. Institute of Chemistry, Bashkirskii Affiliate, Academy of Sciences of the USSR, Ufa

    U. M. Dzhemilev, R. I. Khusnutdinov, D. K. Galeev, O. M. Nefedov & G. A. Tolstikov

  2. N. D. Zelinsky Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    U. M. Dzhemilev, R. I. Khusnutdinov, D. K. Galeev, O. M. Nefedov & G. A. Tolstikov

Authors
  1. U. M. Dzhemilev
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  2. R. I. Khusnutdinov
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  3. D. K. Galeev
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  4. O. M. Nefedov
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  5. G. A. Tolstikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 138–148, January, 1987.

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Dzhemilev, U.M., Khusnutdinov, R.I., Galeev, D.K. et al. Nickel complex-catalyzed codimerization of allyl esters with compounds in the norbornene series. Russ Chem Bull 36, 122–131 (1987). https://doi.org/10.1007/BF00953861

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  • DOI: https://doi.org/10.1007/BF00953861

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