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Tributylborane in the synthesis of graft copolymers of collagen and polymethyl methacrylate

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Abstract

Graft copolymers of collagen and polymethyl methacrylate were synthesized in a suspension of an acetic acid dispersion of fish collagen and methyl methacrylate in the presence of tributylborane. The copolymers were characterized by IR spectroscopy, gel permeation chromatography, and differential scanning calorimetry. The glass transition temperature is determined for the obtained copolymers. Changes in the synthesis temperature in a range of 25–60 °C did not significantly affect the fraction and molecular weight of the graft polymethyl methacrylate. Microphotographs obtained by scanning electron microscopy and atomic force microscopy indicate the destruction of the fibrillous structure of collagen in the copolymer at the synthesis temperature higher than 25 °C. The hydrophilicity and light transmission of films of the synthesized copolymer samples were studied.

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Funding

This work was carried out using the Center for Collective Use “Novel Materials and Resource Saving Technologies.”

This work was financially supported by the Ministry of Science and Higher Education of the Russian Federation (base part of state assignment, Project No. 0729-2020-0039).

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Authors and Affiliations

  1. N. I. Lobachevsky Nizhny Novgorod State University, 23 prosp. Gagarina, 603950, Nizhny Novgorod, Russian Federation

    Yu. L. Kuznetsova, E. A. Morozova, K. S. Sustaeva, A. V. Markin, A. V. Mitin, E. V. Salomatina, K. S. Gushchina & L. L. Semenycheva

  2. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603137, Nizhny Novgorod, Russian Federation

    M. A. Baten’kin & M. P. Shurygina

  3. Near-Volga Research Medical University, 10/1 pl. Minina i Pozharskogo, 603005, Nizhny Novgorod, Russian Federation

    M. I. Pryazhnikova

Authors
  1. Yu. L. Kuznetsova
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  2. E. A. Morozova
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  3. K. S. Sustaeva
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  4. A. V. Markin
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  5. A. V. Mitin
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  6. M. A. Baten’kin
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  7. E. V. Salomatina
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  8. M. P. Shurygina
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  9. K. S. Gushchina
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  10. M. I. Pryazhnikova
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  11. L. L. Semenycheva
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Corresponding author

Correspondence to Yu. L. Kuznetsova.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 389–398, February, 2022.

No human or animal subjects were used in this research.

The authors declare no competing interests.

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Kuznetsova, Y.L., Morozova, E.A., Sustaeva, K.S. et al. Tributylborane in the synthesis of graft copolymers of collagen and polymethyl methacrylate. Russ Chem Bull 71, 389–398 (2022). https://doi.org/10.1007/s11172-022-3424-3

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  • DOI: https://doi.org/10.1007/s11172-022-3424-3

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