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Stannylenes based on neutral, anionic, and dianionic 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene

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Abstract

The reaction of 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dpp-bian (1)) with one equivalent of SnCl2 gave the complex [(dpp-bian)0SnCl2] (2) containing the neutral dpp-bian ligand. Paramagnetic stannylene [(dpp-bian)−SnCl] (3) was prepared by the treatment of dpp-bian with a fivefold excess of SnCl2 and KC8. The treatment of dpp-bian with one equivalent of SnCl2 and two equivalents of KC8 in the presence of one equivalent of [CpFe(CO)2]2 afforded the diamagnetic stannylene complex [(dpp-bian)2−Sn] (4) based on the dpp-bian dianion. The diazastannacycle in complex 4 was proved to be aromatic by NMR spectroscopy. The new compounds were characterized by elemental analysis, IR spectroscopy (2–4), multinuclear NMR spectroscopy (2, 4), and EPR spectroscopy (3). The molecular structures of complexes 2–4 were determined by single-crystal X-ray diffraction.

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Funding

The study was financially supported by the Russian Science Foundation (Project No. 21-73-20153) using the equipment of the Center for Collective Use “Analytical Center of the IOMC RAS” with the financial support by the Ministry of Science and Higher Education of the Russian Federation (grant “Ensuring the Development of the Material and Technical Infrastructure of the Centers for Collective Use of Scientific Equipment,” unique identifier RF—2296.61321X0017).

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  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603137, Nizhny Novgorod, Russian Federation

    V. A. Dodonov, O. A. Kushnerova, D. A. Razborov, E. V. Baranov, E. A. Ulivanova, A. N. Lukoyanov & I. L. Fedushkin

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  1. V. A. Dodonov
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  2. O. A. Kushnerova
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Correspondence to V. A. Dodonov.

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Dedicated to the Director of the A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Corresponding Member of the Russian Academy of Sciences A. A. Trifonov on the occasion of his 60th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 322–329, February, 2022.

No human or animal subjects were used in this research.

The authors declare no competing interests.

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Dodonov, V.A., Kushnerova, O.A., Razborov, D.A. et al. Stannylenes based on neutral, anionic, and dianionic 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene. Russ Chem Bull 71, 322–329 (2022). https://doi.org/10.1007/s11172-022-3414-5

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