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Photolytic synthesis and hydrophobization of plates of porous polymer material based on dimethacrylate oligomer MDP-2

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Abstract

Plates of poly-MDP-2 porous material with a characteristic size of inhomogeneities of 0.3, 0.7, 2.5, 10, and 20 µm were synthesized by the photopolymerization technique. The conditions for the photolytic modification of the hydrophilic/hydrophobic properties of poly-MDP-2 by the graft copolymerization method under visible light irradiation were selected using 9,10-phenanthrenequinone as a photoinitiator and isodecyl methacrylate as a modifying monomer. It is shown on the samples with an inhomogeneity size of 10 µm that the stable hydrophobization effect (contact angle of water droplet θ = 135°) is achieved at a photoinitiator concentration of 2.4 · 10−3 mol L−1 and an irradiation time of the sample in the modifying solution of 1 h. The effect of photolytic hydrophobization increases with an increase in the size of inhomogeneities in the porous polymer material and reaches θ = 140° for inhomogeneities ∼20 µm in size.

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhny Novgorod, Russian Federation

    N. A. Lenshina, M. V. Arsenyev, M. A. Baten’kin & S. A. Chesnokov

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  1. N. A. Lenshina
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  2. M. V. Arsenyev
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  3. M. A. Baten’kin
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  4. S. A. Chesnokov
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Correspondence to M. V. Arsenyev.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1741–1747, September, 2019.

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Lenshina, N.A., Arsenyev, M.V., Baten’kin, M.A. et al. Photolytic synthesis and hydrophobization of plates of porous polymer material based on dimethacrylate oligomer MDP-2. Russ Chem Bull 68, 1741–1747 (2019). https://doi.org/10.1007/s11172-019-2619-8

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  • DOI: https://doi.org/10.1007/s11172-019-2619-8

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