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Crystal and molecular structure of the reaction product of 7-mercapto-4-methylcoumarin with iodine

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Abstract

4-Methyl-7-(4-methyl-2-oxo-2H-chromen-6-yl)disulfanyl-2H-chromen-2-one hydrotriiodide was synthesized by the reaction of 7-mercapto-4-methylcoumarin with iodine, and its structure was determined by NMR spectroscopy and X-ray diffraction combined with Raman and IR spectroscopy. The molecular and crystal structure of the reaction product was determined.

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References

  1. V. K. Koltover, Russ. Chem. Bull., 2010, 59, 37.

    Article  CAS  Google Scholar 

  2. S. E. Yagunov, S. V. Khol’shin, N. V. Kandalintseva, A. E. Prosenko, Russ. Chem. Bull., 2013, 62, 1395.

    Article  CAS  Google Scholar 

  3. H. J. Kim, J. S. Noh, M. J. Kwon, S. Song, H. Suh, M. J. Kim, Y. O. Song, Bull. Korean Chem. Soc., 2010, 31, 3327.

    Article  CAS  Google Scholar 

  4. H. A. Zahalka, B. Robillard, L. Hughes, J. Lusztyk, G. W. Burton, E. G. Janzen, Y. Kotake, K. U. Ingold, J. Org. Chem., 1988, 53, 3739.

    Article  CAS  Google Scholar 

  5. Coumarins: Biology, Applications and Mode of Action, Eds R. O’Kennedy, R. D. Thornes, Wiley, Chichester, 1997.

    Google Scholar 

  6. M. B. Plotnikov, A. E. Prosenko, V. I. Smol’yakova, I. S. Ivanov, G. A. Chernysheva, N. V. Kandalintseva, Pharm. Chem. J., 2010, 44, 189.

    Article  CAS  Google Scholar 

  7. M. S. Chernov’yants, T. S. Kolesnikova, A. O. Karginova, Talanta, 2016, 149, 319.

    Article  CAS  PubMed  Google Scholar 

  8. M. S. Chernov’yants, A. O. Dolinkin, J. Struct. Chem., 2010, 51, 1176.

    Article  CAS  Google Scholar 

  9. A. J. Gordon, R. A. Ford, The Chemist’s Companion. A Handbook of Practical Data, Techniques and References, A Wiley-Interscience Publication John Wiley and Sons, New York-London-Sydney-Toronto, 1972, p. 54.

    Google Scholar 

  10. APEX2, Bruker AXS Inc., Madison, Wisconsin, USA, 2009.

  11. G. M. Sheldrick, Acta Crystfllogr., 2008, A64, 112.

    Article  CAS  Google Scholar 

  12. F. Pan, U. Englert, Cryst. Growth Des., 2014, 14, 1057.

    Article  CAS  Google Scholar 

  13. A. L. Spek, Acta Crystallogr., 2009, D65, 148.

    Google Scholar 

  14. F. H. Allen, O. Kennard, D. G. Watson, L. Brammer, A. G. Orpen, R. Taylor, Chem. Soc., Perkin Trans. 2, 1987, S1.

    Article  Google Scholar 

  15. M. S. Chernov’yants, T. S. Kolesnikova, K. Yu. Suponitsky, Russ. Chem. Bull., 2016, 65, 811.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Southern Federal University, 7 ul. Zorge, 344090, Rostov-on-Don, Russian Federation

    M. S. Chernov’yants & T. S. Kolesnikova

Authors
  1. M. S. Chernov’yants
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  2. T. S. Kolesnikova
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Correspondence to T. S. Kolesnikova.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1219–1222, June, 2019.

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Chernov’yants, M.S., Kolesnikova, T.S. Crystal and molecular structure of the reaction product of 7-mercapto-4-methylcoumarin with iodine. Russ Chem Bull 68, 1219–1222 (2019). https://doi.org/10.1007/s11172-019-2544-x

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  • DOI: https://doi.org/10.1007/s11172-019-2544-x

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