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Polynuclear NiII and CoII hexafluoroacetylacetonates

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Abstract

Hydrolysis of [M4(hfac)4(MeO)4(MeOH)4] (М = Сo, Ni and hfac is hexafluoroacetylaceton ate) is a convenient way of obtaining polynuclear complexes [Ni7(hfac)6(OH)8(H2O)6]•2H2O, [Co12(hfac)10(OH)14(H2O)8]•2H2O•2MePh, [Co12(hfac)10(OH)14(H2O)4(Me2CO)4]•3PhMe, and [Co12(hfac)10(OH)14(H2O)6(Me2CO)2]•2H2O•2Me2CO, whose structures were confirmed by X-ray analysis.

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Correspondence to O. V. Kuznetsova.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1202–1205, July, 2018.

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Kuznetsova, O.V., Fursova, E.Y., Letyagin, G.A. et al. Polynuclear NiII and CoII hexafluoroacetylacetonates. Russ Chem Bull 67, 1202–1205 (2018). https://doi.org/10.1007/s11172-018-2202-8

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  • DOI: https://doi.org/10.1007/s11172-018-2202-8

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