Abstract
Hydrolysis of [M4(hfac)4(MeO)4(MeOH)4] (М = Сo, Ni and hfac is hexafluoroacetylaceton ate) is a convenient way of obtaining polynuclear complexes [Ni7(hfac)6(OH)8(H2O)6]•2H2O, [Co12(hfac)10(OH)14(H2O)8]•2H2O•2MePh, [Co12(hfac)10(OH)14(H2O)4(Me2CO)4]•3PhMe, and [Co12(hfac)10(OH)14(H2O)6(Me2CO)2]•2H2O•2Me2CO, whose structures were confirmed by X-ray analysis.
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Cambridge Structural Database System, Version 5.39, 2017.
I. L. Eremenko, Nanotechnologies in Russia, 2008, 3,2.
E. Yu. Fursova, V. I. Ovcharenko, Russ. J. Gen. Chem., 2009, 79, 2731.
W. Bidell, V. Shklover, H. Berke, Inorg. Chem., 1992, 31, 5561.
M. N. Sokolov, A. V. Virovets, A. V. Rogachev, P. A. Abramov, V. P. Fedin, Russ. J. Coord. Chem., 2013, 39,175.
S. Petit, P. Neugebauer, G. Pilet, G. Chastanet, A.-L. Barra, A. B. Antunes, W. Wernsdorfer, D. Luneau, Inorg. Chem., 2012, 51, 6645.
G. M. Sheldrick, Acta Cryst., 2015, C71,3.
E. Yu. Fursova, O. V. Kuznetsova, V. I. Ovcharenko, G. V. Romanenko, A. S. Bogomyakov, Russ. Chem. Bull., 2008, 57, 1198.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1202–1205, July, 2018.
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Kuznetsova, O.V., Fursova, E.Y., Letyagin, G.A. et al. Polynuclear NiII and CoII hexafluoroacetylacetonates. Russ Chem Bull 67, 1202–1205 (2018). https://doi.org/10.1007/s11172-018-2202-8
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DOI: https://doi.org/10.1007/s11172-018-2202-8