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Decay of H2O2 under the action of the colloidal catalyst based on iron(III) oxides in a neutral medium

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Abstract

The catalytic activity of the colloidal catalyst based on iron(III) hydroxide was studied in the decomposition of H2O2 in a neutral medium (pH 6.7). A colloidal micellar solution of iron(III) hydroxide after preparation was kept at 19–20 °С for 2 or 20 h without additives or with C2H5OH additives. The decomposition of H2O2 under the action of the colloidal catalyst (20 h) proceeds via the first-order reaction with the decay rate constant kd = 1.26•10–4 s–1, whereas the decay rate of the first-order reaction is kd = 0.77•10–4 s–1 for the colloidal catalyst (2 h) prepared in the presence of C2H5OH.

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 119991, Moscow, Russian Federation

    L. M. Pisarenko

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  1. L. M. Pisarenko
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Correspondence to L. M. Pisarenko.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1026–1030, June, 2018.

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Pisarenko, L.M. Decay of H2O2 under the action of the colloidal catalyst based on iron(III) oxides in a neutral medium. Russ Chem Bull 67, 1026–1030 (2018). https://doi.org/10.1007/s11172-018-2174-8

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  • DOI: https://doi.org/10.1007/s11172-018-2174-8

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