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Ternary gallides of the Ce2+nRh3+3nGa1+2n (n = 0—5) structure family

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Abstract

The structures of nine ternary intermetallic compounds (IMCs) of the cerium—rhodium—gallium system containing 50 at.% rhodium were determined by single-crystal X-ray diffraction. The compounds are built up of alternating Ce2Rh3Ga fragments with the Mg2Cu3Si (MgZn2 type) or Mg2Ni3Si (MgCu2 type) structure and CeRh3Ga2 fragments with the CeCo3B2 (CaCu5 type) structure and form a homologous series of the composition R2+nT3+3nM1+2n (n = 0—5). These compounds can be classified into trigonal (R-3m) or hexagonal (P63/mmc) branches depending on the Laves phase-type fragment.

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References

  1. S. F. Matar, Progress in Solid State Chem., 2012, 41, 55.

    Article  Google Scholar 

  2. G. Knebel, D. Aok, J. Flouquet, C. R. Phys., 2011, 12, 542.

    Article  CAS  Google Scholar 

  3. E. Bauer, G. Hilscher, H. Michor, Ch. Paul, E. W. Scheidt, A. Gribanov, Yu. Seropegin, H. Noël, M. Sigrist, P. Rogl, Phys. Rev. Lett., 2004, 92, 027003.

    Article  CAS  Google Scholar 

  4. A. N. Fitch, J. Res. National Institute of Standards and Tech-nology, 2004, 109, 133–142.

    Article  CAS  Google Scholar 

  5. V. B. Zlokazov, V. V. Chernyshev, J. Appl. Crystallogr., 1992, 25, 447–451.

    Article  Google Scholar 

  6. P. Villars, K. Cenzual, J. Daams, L. Sysa, in Structure Types, Part 3: Space Groups (194) P63/mmc—(190) P-62c, Lan-dolt—Börnstein — Group III Condensed Matter, 43A3, Sprin-ger Verlag, Berlin—Heidelberg, 2006.

    Google Scholar 

  7. P. Villars, K. Cenzual, J. Daams, R. Gladyshevskii, in Struc-ture Types, Part 5: Space Groups (173) P63—(166) R-3m, Landolt—Börnstein — Group III Condensed Matter, 43A5, Springer Verlag, Berlin—Heidelberg, 2007.

    Book  Google Scholar 

  8. Yu. B. Kuz’ma, P. I. Kripyakevich, N. S. Bilonizhko, Dop-ov. Akad. Nauk USSR, Ser. A [Rep. Nation. Acad. Sci. Ukraine, Ser. A], 1969, 10, 939 (in Russian).

    Google Scholar 

  9. E. Parthe, B. Chabot, in Handbook on the Physics and Chem-istry of Rare Earths, Eds K. A. Gschneidner, L. Eyring, Elsevier, Amsterdam: North Holland, 1984, p. 113.

  10. E. Parthé, L. Gelato, B. Chabot, M. Penzo, K. Cenzual, R. Gladyshevskii, in Gmelin Handbook of Inorganic and Or-ganometallic Chemistry, 8th ed., Springer, Berlin, 1993, p. 145.

    Google Scholar 

  11. L. Paccard, D. Paccard, J. Less-Common Metals, 1985, 105, 229.

    Article  Google Scholar 

  12. K. Cenzual, B. Chabot, E. Parthe, Acta Crystallogr., Sect. C, 1988, 44, 400.

    Article  Google Scholar 

  13. L. Salamakha, E. Bauer, G. Hilscher, H. Michor, O. So-logub, P. Rogl, G. Giester, Inorg Chem., 2013, 52, 4185.

    Article  CAS  Google Scholar 

  14. J. Emsley, Elements, Clarendon Press, Oxford, 1989, 256 pp.aa

    Google Scholar 

  15. H. H. Hill, in Plutonium and Other Actinides, Ed. W. N. Mines, Nuclear Materials Series, American Institute of Min-ing, Metallurgical, and Petroleum Engineers, 1970, 17, 2.

    Google Scholar 

  16. S. Seidel, U. Ch. Rodewald, O. Janka, R. Pöttgen, Z. Kri-stallogr., 2017, 232, 365.

    CAS  Google Scholar 

  17. S. Seidel, O. Janka, C. Benndorf, B. Mausolf, F. Haar-mann, H. Eckert, L. Heletta, R. Pöttgen, Z. Naturforsch., Teil B, 2017, 72, 289.

    CAS  Google Scholar 

  18. G. F. Chen, I. Sakamoto, S. Ohara, Phys. Rev. B, 2004, 69, 014420.

    Article  Google Scholar 

  19. B. Buschinger, O. Trovarelli, M. Weiden, C. Geibel, F. Steglich, J. Alloys Compd., 1998, 275—277, 633.

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    V. A. Avzuragova, S. N. Nesterenko & A. I. Tursina

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  1. V. A. Avzuragova
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  2. S. N. Nesterenko
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  3. A. I. Tursina
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Correspondence to S. N. Nesterenko.

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Based on the Materials of the International Conference "Nanomaterials: New Methods of Synthesis" (May 16—18, 2017, Moscow, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2015—2020, November, 2017.

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Avzuragova, V.A., Nesterenko, S.N. & Tursina, A.I. Ternary gallides of the Ce2+nRh3+3nGa1+2n (n = 0—5) structure family. Russ Chem Bull 66, 2015–2020 (2017). https://doi.org/10.1007/s11172-017-1975-5

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  • DOI: https://doi.org/10.1007/s11172-017-1975-5

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