Skip to main content
SpringerLink
Log in

Synthesis of thioether-containing carbosilane dendrimers with sterically shielded sulfur atoms

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Carbosilane thiols were synthesized as the first- and second-generation (in silicon) dendrons. It was demonstrated that the resulting bulky thiols successfully undergo the thiol—ene addition to third-generation polyallyl carbosilane dendrimer as a photoinitiated radical reaction to give the corresponding thioether-containing derivatives with sterically shielded sulfur atoms.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. W. J. Scott, O. M. Wilson, R. M. Crooks, J. Phys. Chem. B, 2005, 109, 692.

    Article  CAS  Google Scholar 

  2. L. M. Bronstein, Z. B. Shifrina, Chem. Rev., 2011, 111, 5301.

    Article  CAS  Google Scholar 

  3. M. Moreno-Manas, R. Pleixats, Acc. Chem. Res., 2003, 36, 638.

    Article  CAS  Google Scholar 

  4. E. Gross, J. M. Krier, L. Heinke, G. A. Somorjai, Top. Catal., 2012, 55, 13.

    Article  CAS  Google Scholar 

  5. Z. V. Feng, J. L. Lyon, J. S. Croley, R. M. Crooks, D. A. Van den Bout, K. J. Stevenson, J. Chem. Educ., 2009, 86, 368.

    Article  CAS  Google Scholar 

  6. W. Lesniak, A. U. Bielinska, K. Sun, K. W. Janczak, X. Shi, J. R. Baker, Jr., L. P. Balogh, Nano Lett., 2005, 5, 2123.

    Article  CAS  Google Scholar 

  7. R. W. J. Scott, O. M. Wilson, R. M. Crooks J. Phys. Chem., 2005, 109, 692.

    Article  CAS  Google Scholar 

  8. M. G. Weir, M. R. Knecht, A. I. Frenkel, R. M. Crooks, Langmuir, 2010, 26, 1137.

    Article  CAS  Google Scholar 

  9. H. Wu, C. R. Lucas, Inorg. Chem., 1993, 32, 526.

    Article  CAS  Google Scholar 

  10. C. Rim, H. Zhang, D. Y. Son, Inorg. Chem., 2008, 47, 11993.

    Article  CAS  Google Scholar 

  11. K. Lorenz, H. Frey, B. Stuhn, R. Mulhaupt, Macromolecules, 1997, 30, 6860.

    Article  CAS  Google Scholar 

  12. M. Galán, J. Sánchez-Rodríguez, J. L. Jiménez, M. Relloso, M. Maly, F. J. de la Mata, M. A. Muñoz-Fernández, R. Gómez, Org. Biomol. Chem., 2014, 12, 3222.

    Article  Google Scholar 

  13. K. L. Killops, L. M. Campos, C. J. Hawker, J. Am. Chem. Soc., 2008, 130, 5062.

    Article  CAS  Google Scholar 

  14. C. Rissing, D. Y. Son, Organometallics, 2009, 28, 3167.

    Article  CAS  Google Scholar 

  15. Z. Zhang, S. Feng, J. Zhang, Macromol. Rapid Commun., 2016, 37, 318.

    Article  CAS  Google Scholar 

  16. E. A. Tatarinova, E. A. Rebrov, V. D. Myakushev, I. B. Meshkov, N. V. Demchenko, A. V. Bystrova, O. V. Lebedeva, A. M. Muzafarov, Russ. Chem. Bull., 2004, 53, 2591.

    Article  CAS  Google Scholar 

  17. A. N. Tarasenkov, E. V. Getmanova, M. I. Buzin, N. M. Surin, A. M. Muzafarov, Russ. Chem. Bull., 2011, 60, 2544.

    Article  CAS  Google Scholar 

  18. A. N. Tarasenkov, V. G. Vasil´ev, M. I. Buzin, E. V. Getmanova, G. G. Pak, E. Yu. Kramarenko, A. M. Muzafarov, Russ. Chem. Bull., 2016, 65, 1086.

    Article  CAS  Google Scholar 

  19. A. Tarasenkov, E. Getmanova, E. Tatarinova, N. Surin, A. Muzafarov, Macromol. Symp., 2012, 317, 293.

    Article  Google Scholar 

  20. A. I. Alexandrov, I. Yu. Metlenkova, A. N. Tarasenkov, Yu. A. Borisov, Russ. Chem. Bull., 2016, 65, 407.

    Article  CAS  Google Scholar 

  21. C. Drohmann, M. Moller, O. B. Gorbatsevich, A. M. Muzafarov, J. Polym. Sci. Part A: Polym. Chem., 2000, 38, 741.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. S. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, 70 ul. Profsoyuznaya, 117393, Moscow, Russian Federation

    А. N. Tarasenkov, E. V. Getmanova, E. A. Tatarinova, N. V. Demchenko & G. V. Cherkaev

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    М. I. Buzin & А. М. Muzafarov

Authors
  1. А. N. Tarasenkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. V. Getmanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. A. Tatarinova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. М. I. Buzin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. N. V. Demchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. G. V. Cherkaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. А. М. Muzafarov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to А. N. Tarasenkov.

Additional information

Dedicated to Academician of the Russian Academy of Sciences G. A. Abakumov on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1675—1685, September, 2017.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Tarasenkov, А.N., Getmanova, E.V., Tatarinova, E.A. et al. Synthesis of thioether-containing carbosilane dendrimers with sterically shielded sulfur atoms. Russ Chem Bull 66, 1675–1685 (2017). https://doi.org/10.1007/s11172-017-1940-3

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-017-1940-3

Key words

Search

Navigation