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Potentiometric method for determination of kinetic characteristics of radical reactions in aqueous media

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Abstract

Kinetic features of the reactions of K4[Fe(CN)6] with radicals initiated by water-soluble azo-initiator 2,2′-azobis(2-amidinopropane) dihydrochloride (AAPH) at 37 °C were studied using the potentiometric method. Potassium ferrocyanide was shown to be a radical acceptor, whereas K3[Fe(CN)6] formed by the oxidation with the radicals in combination with K4[Fe(CN)6] is an electrochemical system, the study of which makes it possible to determine kinetic characteristics of radical reactions. The rate constants for the reactions of peroxide radicals RO2 · with K4[Fe(CN)6] were calculated.

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Authors and Affiliations

  1. Ural Federal University named after the First President of Russia B. N. Yeltsin, Chemical Technological Institute, 19 ul. Mira, 620002, Ekaterinburg, Russian Federation

    A. V. Ivanova, E. L. Gerasimova, E. R. Gazizullina, A. G. Davletchurina & A. N. Kozitsina

  2. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 119991, Moscow, Russian Federation

    O. T. Kasaikina

Authors
  1. A. V. Ivanova
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  2. E. L. Gerasimova
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  3. E. R. Gazizullina
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  4. A. G. Davletchurina
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  5. A. N. Kozitsina
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  6. O. T. Kasaikina
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Corresponding author

Correspondence to A. V. Ivanova.

Additional information

Based on the Materials of the XX Mendeleev Congress on General and Applied Chemistry (September 26—30, 2016, Ekaterinburg, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1428—1432, August, 2017.

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Ivanova, A.V., Gerasimova, E.L., Gazizullina, E.R. et al. Potentiometric method for determination of kinetic characteristics of radical reactions in aqueous media. Russ Chem Bull 66, 1428–1432 (2017). https://doi.org/10.1007/s11172-017-1903-8

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  • DOI: https://doi.org/10.1007/s11172-017-1903-8

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