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Synthesis of metallacarborane ruthenium(ii) and ruthenium(iii) complexes with chelate 1,3-bis(diphenylphosphino)propane ligand and their mutual transformation in one-electron redox reactions

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Abstract

The first example of 12-vertex metallapolyhedra, namely, tris-phosphorus-containing closo-metallacarborane ruthenium(II) cluster , was synthesized and structurally studied. A principal possibility of the use of aliphatic amines as one-electron reducing agents converting carborane ruthenium(III) complexes to structurally close ruthenium(II) compounds was experimentally demonstrated.

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Authors and Affiliations

  1. N. I. Lobachevsky State University of Nizhny Novgorod, 23 prosp. Gagarina, 603950, Nizhny Novgorod, Russian Federation

    I. D. Grishin, K. S. Agafonova & D. F. Grishin

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. Yu. Kostyukovich, D. I. D’yachihin, I. A. Godovikov, F. M. Dolgushin & I. T. Chizhevsky

Authors
  1. I. D. Grishin
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  2. K. S. Agafonova
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  3. A. Yu. Kostyukovich
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  4. D. I. D’yachihin
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  5. I. A. Godovikov
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  6. F. M. Dolgushin
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  7. D. F. Grishin
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  8. I. T. Chizhevsky
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Correspondence to I. D. Grishin.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1574—1579, June, 2016.

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Grishin, I.D., Agafonova, K.S., Kostyukovich, A.Y. et al. Synthesis of metallacarborane ruthenium(ii) and ruthenium(iii) complexes with chelate 1,3-bis(diphenylphosphino)propane ligand and their mutual transformation in one-electron redox reactions. Russ Chem Bull 65, 1574–1579 (2016). https://doi.org/10.1007/s11172-016-1484-y

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  • DOI: https://doi.org/10.1007/s11172-016-1484-y

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