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Bimetallic 3d—4f-molecules [MEu(ButCOO)5(1,10-phen)] (M = Zn2+, Co2+, phen is phenanthroline): synthesis, structure, luminescent and magnetic properties

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Abstract

New heterometallic complexes [MEu(Piv)5(1,10-phen)]•MeCN (M = Zn2+ (1), Co2+ (2), Piv– = ButCOO–, 1,10-phen is 1,10-phenanthroline) were obtained. Luminescence spectra of compound 1 reveal a metal-centered Eu3+ luminescence, the luminescence lifetime is about 1 ms. Using TGA and DSC methods, it was shown that [ZnEu(Piv)5(1,10-phen)] is a stable binuclear molecule undergoing a structural transformation in the 210—230 °C temperature range, which leads to a partial transition of the sample into the glass state. Complex 2 does not exhibit luminescence due to the presence of high-spin cobalt(II) ions. The magnetic behavior of 2 according to calculations based on the molecular field model is determined by spin-orbit interactions of cobalt(II) and europium(III) ions.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    M. A. Kiskin, Zh. V. Dobrokhotova, S. A. Kozyukhin & I. L. Eremenko

  2. Institute “International Tomography Center”, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation

    A. S. Bogomyakov

  3. Tomsk State University, 36 prosp. Lenina, 634050, Tomsk, Russian Federation

    S. A. Kozyukhin & V. Yu. Timoshenko

  4. Department of Physics, M. V. Lomonosov Moscow State University, Build. 2, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    V. Yu. Timoshenko

Authors
  1. M. A. Kiskin
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  2. Zh. V. Dobrokhotova
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  3. A. S. Bogomyakov
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  4. S. A. Kozyukhin
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  5. V. Yu. Timoshenko
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  6. I. L. Eremenko
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Correspondence to M. A. Kiskin.

Additional information

Dedicated to Corresponding Member of the Russian Academy of Sciences V. K. Cherkasov on the occasion of his 70th birthday. Based on the Materials of International Conference "Organometallic and Coordination Chemistry: Achievements and Challenges (VI Razuvaev Lectures)" (September 18—23, 2015, Nizhnii Novgorod).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1488—1494, June, 2016.

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Kiskin, M.A., Dobrokhotova, Z.V., Bogomyakov, A.S. et al. Bimetallic 3d—4f-molecules [MEu(ButCOO)5(1,10-phen)] (M = Zn2+, Co2+, phen is phenanthroline): synthesis, structure, luminescent and magnetic properties. Russ Chem Bull 65, 1488–1494 (2016). https://doi.org/10.1007/s11172-016-1475-z

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  • DOI: https://doi.org/10.1007/s11172-016-1475-z

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