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Antiferromagnetic Coupling in a New Mn(III) Schiff Base Complex with Open-Cubane Core: Structure, Spectroscopic and Luminescence Properties

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Abstract

A new open-cubane MnIII, [{(H2O)MnIIIL}{MnIIIL}]2·2(CH3OH).2(CH3CH2OH)·2Cl, 1 where H 2 L=[N-(2-hydroxyethyl)-3-methoxysalicylaldimine] has been synthesized and characterized by element analysis, FT-IR, solid UV–Vis spectroscopy and single crystal X-ray diffraction. The crystal structure determination shows an open-cubane tetranuclear complex. The Mn1 (Mn1i) ions is hexacoordinate by NO5 donor sets while the Mn2 (Mn2i) is pentacoordinate by NO4 donor sets. The solid state photoluminescence properties of complex 1 and its ligand H 2 L have been investigated under UV light at 349 nm in the visible region. H 2 L exhibits blue emission while complex 1 shows orange-red emission at room temperature. Variable-temperature magnetic susceptibility measurements on the complex 1 in the range 2–300 K indicate an antiferromagnetic interaction.

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Acknowledgements

The authors are grateful to the Research Funds of Balikesir University (BAP–2017/200) for the financial support and Balikesir University, Science and Technology Application and Research Center (BUBTAM) for the use of the Photoluminescence Spectrometer. The authors are also very grateful to Prof. Dr. Andrea Caneschi (Laboratory of Molecular Magnetism, Department of Chemistry, University of Florence) for the use of SQUID magnetometer and helpful suggestions.

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Authors and Affiliations

  1. Department of Physics, Faculty of Science and Art, Balikesir University, 10145, Balikesir, Turkey

    Elif Gungor, Hulya Kara & Yasemin Acar

  2. Center of Science and Technology Application and Research, Balikesir University, 10145, Balikesir, Turkey

    Mustafa Burak Coban

  3. Department of Physics, Faculty of Science, Mugla Sitki Kocman University, 48170, Mugla, Turkey

    Hulya Kara

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  1. Elif Gungor
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Correspondence to Elif Gungor.

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Gungor, E., Coban, M.B., Kara, H. et al. Antiferromagnetic Coupling in a New Mn(III) Schiff Base Complex with Open-Cubane Core: Structure, Spectroscopic and Luminescence Properties. J Clust Sci 29, 533–540 (2018). https://doi.org/10.1007/s10876-018-1360-z

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