Abstract
New ruthenium carbene complexes with chelating N- and S-benzylidene ligands were synthesized by the reactions of second- and third-generation Grubbs catalysts with ortho-vinylbenzyl-substituted amines or sulfides. These complexes were shown to exhibit catalytic activity in ring-opening metathesis polymerization and ring-closing metathesis.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 0490—0497, February, 2016.
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Shcheglova, N.M., Kolesnik, V.D., Ashirov, R.V. et al. Latent ruthenium carbene complexes with six-membered N- and S-chelate rings. Russ Chem Bull 65, 490–497 (2016). https://doi.org/10.1007/s11172-016-1327-x
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DOI: https://doi.org/10.1007/s11172-016-1327-x