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New functional materials based on conductive polymer—metal complexes modified with metallic nanoelectrodes

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The results of the synthesis and investigation of new composite functional materials are presented. The new materials are conductive polymer layers of the cobalt, nickel, and palladium complexes with the Schiff bases (poly[MSchiff)]) with gold and platinum nanoelectrodes inserted into the layers using the electrochemical deposition method. The materials were studied by cyclic voltammetry, impedance spectroscopy, scanning electron microscopy with X-ray microanalysis, and a quartz crystal microbalance. The composite materials poly[Ni(Schiff)]/Pt and poly[Co(Schiff)]/Au exhibit catalytic activity in the reactions of hydrogen evolution and electroreduction of molecular oxygen, respectively.

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Authors and Affiliations

  1. Herzen State Pedagogical University of Russia, 48 nab. Reki Moiki, 191186, St. Petersburg, Russian Federation

    E. A. Smirnova, M. P. Karushev & A. M. Timonov

  2. St. Petersburg State University, 26 Universitetskii prosp., 198504, St. Petersburg, Petrodvorets, Russian Federation

    E. V. Alekseeva, O. V. Levin & V. V. Malev

Authors
  1. E. A. Smirnova
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  2. M. P. Karushev
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  3. A. M. Timonov
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  4. E. V. Alekseeva
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  5. O. V. Levin
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  6. V. V. Malev
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Corresponding author

Correspondence to V. V. Malev.

Additional information

Based on the materials of the XXVI International Chugaev Conference on Coordination Chemistry (October 6—10, 2014, Kazan).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1919—1925, August, 2015.

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Smirnova, E.A., Karushev, M.P., Timonov, A.M. et al. New functional materials based on conductive polymer—metal complexes modified with metallic nanoelectrodes. Russ Chem Bull 64, 1919–1925 (2015). https://doi.org/10.1007/s11172-015-1094-0

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  • DOI: https://doi.org/10.1007/s11172-015-1094-0

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