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Gas-phase pyrolysis of 1-chloro-1-fluoro-2-methylcyclopropanes in the presence of SiO2 or Al2O3 with the formation of 2-chloro- or 2-fluorobuta-1,3-dienes

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Abstract

Gas-phase pyrolysis of of 1-chloro-1-fluoro-2-methylcyclopropanes in an empty or filled with quartz pieces flow-tube reactor at 430—460 °C gives 2-fluorobuta-1,3-dienes (in 42—75% yields), whereas pyrolysis in the presence of Al2O3 at 150—250 °C gives 2-chlorobuta-1,3-dienes as the major products (in 58—68% yield).

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    N. V. Volchkov, M. B. Lipkind, M. A. Novikov & O. M. Nefedov

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  1. N. V. Volchkov
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  2. M. B. Lipkind
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  3. M. A. Novikov
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  4. O. M. Nefedov
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Correspondence to N. V. Volchkov.

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Dedicated to Academician of the Russian Academy of Sciences Yu. N. Bubnov on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2250–2254, October, 2014.

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Volchkov, N.V., Lipkind, M.B., Novikov, M.A. et al. Gas-phase pyrolysis of 1-chloro-1-fluoro-2-methylcyclopropanes in the presence of SiO2 or Al2O3 with the formation of 2-chloro- or 2-fluorobuta-1,3-dienes. Russ Chem Bull 63, 2250–2254 (2014). https://doi.org/10.1007/s11172-014-0730-4

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  • DOI: https://doi.org/10.1007/s11172-014-0730-4

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