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Sulfonic acid pyridinium chloride-functionalized nanoparticles (MnCoFe2O4@Niacin-SO3H)+Cl− as a novel and reusable catalyst for synthesis of tetrahydrodipyrazolopyridines and pyranopyrazoles

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Abstract

The novel pyridinium chloride-functionalized MnCoFe2O4-SO3H nanoparticles, (MnCoFe2O4@Niacin-SO3H)+Cl−, were synthesized by coating the sulfonic group on the surface of MnCoFe2O4@Niacin. The activity of these nanoparticles was studied for the synthesis of tetrahydrodipyrazolopyridines and pyranopyrazole derivatives via the multi-component reactions of ethyl acetate, hydrazine, aldehydes, and ammonium acetate or malononitrile. The use of green solvent, easy separation of the catalyst from the reaction medium, easy deposition, high purity, and openness of products are some advantages of this procedure.

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Acknowledgements

The authors gratefully acknowledge the financial support of this work by the research council of Arak University.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Arak University, Arak, 38156-88138, Iran

    Mahdi Omidi & Akbar Mobinikhaledi

  2. Institute of Nanosciences and Nanotechnology, Arak University, Arak, Iran

    Akbar Mobinikhaledi

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  1. Mahdi Omidi
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Correspondence to Akbar Mobinikhaledi.

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Omidi, M., Mobinikhaledi, A. Sulfonic acid pyridinium chloride-functionalized nanoparticles (MnCoFe2O4@Niacin-SO3H)+Cl− as a novel and reusable catalyst for synthesis of tetrahydrodipyrazolopyridines and pyranopyrazoles. Res Chem Intermed 48, 4347–4371 (2022). https://doi.org/10.1007/s11164-022-04800-y

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