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Removal of anionic dyes with glycidyl methacrylate-grafted polyethylene terephthalate (PET) fibers modified with ethylenediamine

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Abstract

In this work, the epoxy groups of poly (ethylene terephthalate) PET copolymers grafted with glycidyl methacrylate (GMA) were modified with ethylenediamine (EDA) to form exclusive adsorbent for removal of congo red (CR) and acid violet7 (AV-7) in the aqueous environment. The graft copolymers (GMA-g-PET) were synthesized with different grafting yield by a radical polymerization process with using benzoyl peroxide (Bz2O2) as radical initiator. Amination of GMA-g-PET fibers using EDA was studied in different solvents, and maximum yield (w/w %) was obtained in the toluene. The grafted and modified fibers were analyzed by CHNS organic elemental analyzer, scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy and nuclear magnetic resonance spectroscopy (13C-NMR). By SEM analysis, the morphological changes have been shown after grafting. The chemical changes after grafting and addition of EDA to the fibers have been proven with FTIR, NMR and elemental analysis. The thermal properties of the grafted and aminated fibers were researched with thermogravimetric analysis and differential scanning calorimeter analysis. The removal of dyes by the EDA-GMA-g-PET fibers was investigated in aqueous medium at different conditions. Optimum conditions of different parameters such as pH of medium, graft yield of GMA on the fibers, adsorption duration, initial concentration of dye molecules and effect of graft yield on amination reaction were examined. The optimum pH of CR and AV-7 removal was found 5 and 3, respectively. The removal yield was found about 100% for both dyes while initial concentration of dyes was changed from 10 to 400 mg/L. Adsorbed dyes with the fibers were desorbed with 1 M NaOH at room conditions.

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Availability of data and materials

The datasets used and/or analyzed during the current study are available from the corresponding author on reasonable request.

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Acknowledgements

The authors are grateful to Kırıkkale University for its contribution.

Funding

The experimental studies were carried out in the laboratories at Kırıkkale University.

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Authors and Affiliations

  1. Kırıkkale University Scientific and Technological Research Application and Research Center, Yahsihan, Kırıkkale, Turkey

    Ogün Bozkaya

  2. Institute of Science, Kırıkkale University, Yahsihan, Kirikkale, Turkey

    Kübra Günay

  3. Chemistry and Chemical Processing Technologies Department, Kırıkkale Vocational High School, Kırıkkale University, Yahsihan, Turkey

    Metin Arslan

  4. Department of Bioengineering, Kırıkkale University, Yahsihan, Kırıkkale, Turkey

    Zehra Gün Gök

Authors
  1. Ogün Bozkaya
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  2. Kübra Günay
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  4. Zehra Gün Gök
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Contributions

We warrant that all authors have contributed to the article. All authors took part in the planning of the study. Kübra Günay and Zehra Gün Gök took part in material synthesis and adsorption experiments. Ogün Bozkaya and Metin Arslan took part in the characterization and analysis of the synthesized material. Metin Arslan also took part in finding the necessary financial contributions. All authors took part in investigating and interpreting the results and writing the article.

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Correspondence to Ogün Bozkaya.

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Bozkaya, O., Günay, K., Arslan, M. et al. Removal of anionic dyes with glycidyl methacrylate-grafted polyethylene terephthalate (PET) fibers modified with ethylenediamine. Res Chem Intermed 47, 2075–2093 (2021). https://doi.org/10.1007/s11164-021-04398-7

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