Abstract
The present work reports a catalytic application of aluminized polyborate for the solvent-free one pot four-component green, efficient and cost-effective synthesis of polydroquinoline derivatives. The aluminized polyborate was synthesized from readily available non-toxic, inexpensive boric acid and aluminium trichloride and characterized by IR, XRD, SEM and EDAX techniques. The polyhydroquinolines were successfully synthesized by well-known Hantzsch condensation reaction of differently substituted aldehydes, dimedone, ethylacetoacetate and NH4OAc at 100 °C under solvent-free condition. The catalyst is stable and easy to use with some significant features such as good acidic catalytic activity, inexpensive and eco-friendly nature. Along with this, excellent product yields, short reaction time, clean reaction, operational simplicity, solvent-free condition and non-column purification are some more additional aspects of this protocol.
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Acknowledgements
The authors are grateful to Principal (P.V.P. College, Pravaranagar & A.S.C. College, Satral) for providing necessary facilities and constant encouragement. We express our gratitude towards Principal Dr. B. K. Karale for valuable guidance. We also thank to SAIF, Punjab University, Chandigarh, for spectral analysis.
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Aute, D., Kshirsagar, A., Uphade, B. et al. Aluminized polyborate-catalysed green and efficient synthesis of polyhydroquinolines under solvent-free conditions. Res Chem Intermed 46, 3491–3508 (2020). https://doi.org/10.1007/s11164-020-04158-z
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DOI: https://doi.org/10.1007/s11164-020-04158-z