Abstract
Nickel (Ni) nanoparticles were immobilized on the surface of magnetic MgAl layered double hydroxide intercalated 10-molybdo-2-vanadophosphate (Fe–MgAl/Mo10V2–Ni) for the first time. The presence of Ni nanoparticles onthe high-surface area Fe–MgAl LDH structure in the presence of Mo10V2 makes this catalyst an ideal option in terms of efficiency and selectivity for Heck coupling reaction. Synergic effects of Mo10V2 and Ni were investigated by an electrochemical technique. Increasing of the ECSA of the catalyst compared to Fe–Mg–Al–Ni leads to enhancement of the catalytic activity and proves the synergic effect. A new catalytic mechanism was introduced for this kind of reaction. The resulting structure and its catalytic behavior were characterized by FT-IR, XRD, ICP-AES, TEM, SEM, EDX, EBSD, XPS, BET, VSM, CV, LSV and zeta potential analyses. More importantly, Fe–MgAl/Mo10V2–Ni can easily be separated from the reaction mixture using an external magnet and reused for at least four successive runs without any substantial reduction in its catalytic activity.
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The authors thank the Razi University Research Council and Iran National Science Foundation (INSF) for support of this work.
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Rafiee, E., Kahrizi, M. Collaboration of Ni, polyoxometalates and layered double hydroxides: synthesis, characterization, electrochemical and mechanism investigations as nano-catalyst in the Heck coupling reaction. Res Chem Intermed 44, 7289–7309 (2018). https://doi.org/10.1007/s11164-018-3557-z
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DOI: https://doi.org/10.1007/s11164-018-3557-z