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Ultrasound assisted synthesis of pyrano[3,2-b]pyran and 7-tosyl-4,7-dihydropyrano[2,3-e]indole scaffolds using barium titanate nanoparticles

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Abstract

Barium titanate nanoparticles (BaTiO3 NPs) were synthesized under sonochemical conditions. The synthesized BaTiO3 NPs was characterized using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetry analysis (TGA), Brunauer–Emmett–Teller (BET), Field emission scanning electron microscopy (FE-SEM) and Transmission electron microscopy (TEM). Morphological study reveals that BaTiO3 NPs have spherical shape with particle size ranging between of 60 and 80 nm. BaTiO3 NPs were further utilized as an efficient and reusable heterogeneous catalyst for ultrasound assisted synthesis of pyrano[3,2-b]pyran. In addition, novel 7-tosyl-4,7-dihydropyrano[2,3-e]indole derivatives were also synthesized using ultrasonication. This new catalytic method displays several notable features such as simplicity, short reaction time, easy work up, easy purification, increased yield and green reaction conditions. The nanocatalyst was reusable up to five runs with marginal loss in its catalytic activity.

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Acknowledgements

The authors are thankful to DST-PURSE, New Delhi for award of research fellowship. We are also thankful to Microanalytical Laboratory, University of Mumbai for providing characterization facilities.

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  1. Department of Chemistry, University of Mumbai, Santacruz (E), Mumbai, 400 098, India

    Sarfaraz Shaikh, Sarika Rasal & M. M. V. Ramana

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  1. Sarfaraz Shaikh
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  2. Sarika Rasal
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Correspondence to M. M. V. Ramana.

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Shaikh, S., Rasal, S. & Ramana, M.M.V. Ultrasound assisted synthesis of pyrano[3,2-b]pyran and 7-tosyl-4,7-dihydropyrano[2,3-e]indole scaffolds using barium titanate nanoparticles. Reac Kinet Mech Cat 133, 405–424 (2021). https://doi.org/10.1007/s11144-021-01972-3

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