Skip to main content
SpringerLink
Log in

Properties of platinum-containing glass-fiber catalysts in the SO2 oxidation reaction

  • Published:
Reaction Kinetics, Mechanisms and Catalysis Aims and scope Submit manuscript

Abstract

SO2 oxidation catalysts containing small amounts (0.01–0.03 mass%) of platinum at the zirconia-promoted silica glass fibers (Pt-GFCs) demonstrate relatively high activity at moderate temperatures (below 400 °C) and the appropriate thermal stability (up to 700 °C). The catalytic activity of Pt-GFC in the SO2 oxidation reaction is provided by the small (< 1 nm) partially charged platinum clusters, while platinum in a form of large metal particles is practically inactive. Pt-GFCs have the high (up to ~20 mass%) sorption capacity with respect to SO2. Such sorption occurs via the interaction of SO2 with oxygen, either present in the gaseous reaction mixture or pre-adsorbed in the fresh GFC structure, with the possible formation of the intermediate sulfates in the glass bulk of the catalyst. Besides, Pt-GFC may effectively oxidize CO in the presence of significant amounts of sulfur dioxide.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. Amelin AG (1983) Technology of sulfuric acid. Khimiya, Moscow (Chemistry)

    Google Scholar 

  2. Kuznetsov DA (1968) Production of sulfuric acid. Higher school, Moscow

    Google Scholar 

  3. Vasilyev BT, Otvagina MI (1985) Technology of sulfuric acid. Khimiya, Moscow (Chemistry)

    Google Scholar 

  4. Simonova LG, Barelko VV, Toktarev AV, Cherashev AF, Chumachenko VA, Balzhinimaev BS (2002) Kinet Catal 43:67

    Article  Google Scholar 

  5. Balzhinimaev BS, Simonova LG, Barelko VV, Toktarev AV, Zaikovskii VI, Chumachenko VA (2003) Chem Eng J 91:181

    Article  Google Scholar 

  6. Balzhinimaev BS, Paukshtis EA, Vanag SV, Suknev AP, Zagoruiko AN (2010) Catal Today 151:195

    Article  CAS  Google Scholar 

  7. Zagoruiko AN, Vanag SV, Balzhinimaev BS, Paukshtis EA, Simonova LG, Zykov AM, Anichkov SN, Hutson ND (2009) Chem Eng J 154:325

    Article  CAS  Google Scholar 

  8. Abkhalimov EV (2008) PhD thesis (Moscow)

  9. Zagoruiko AN, Balzhinimaev BS, Vanag SV, Goncharov VB, Lopatin SA, Zykov AM, Anichkov SN, Zhukov YN, Yankilevich VM, Proskokov NN, Hutson ND (2010) J Air Waste Manag Assoc 60:1002

    Article  CAS  Google Scholar 

  10. Zagoruiko AN, Vanag SV (2014) Chem Eng J 238:86

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Boreskov Institute of Catalysis, prospekt Lavrentieva 5, Novosibirsk, 630090, Russia

    S. V. Vanag, E. A. Paukshtis & A. N. Zagoruiko

  2. Novosibirsk Technical State University, prospekt K.Marksa, Novosibirsk, 630073, Russia

    S. V. Vanag & A. N. Zagoruiko

  3. Tomsk Polytechnic University, prospekt Lenina, 30, Tomsk, 634050, Russia

    A. N. Zagoruiko

  4. Novosibirsk State University, Pirogova Str. 2, Novosibirsk, 630090, Russia

    E. A. Paukshtis & A. N. Zagoruiko

  5. Tomsk State University, prospekt Lenina, 43, Tomsk, 634050, Russia

    E. A. Paukshtis

Authors
  1. S. V. Vanag
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. A. Paukshtis
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. N. Zagoruiko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. N. Zagoruiko.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Vanag, S.V., Paukshtis, E.A. & Zagoruiko, A.N. Properties of platinum-containing glass-fiber catalysts in the SO2 oxidation reaction. Reac Kinet Mech Cat 116, 147–158 (2015). https://doi.org/10.1007/s11144-015-0875-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11144-015-0875-7

Keywords

Search

Navigation