For more complete description of the Al2O3–HfO2–La2O3 phase diagram, three vertical sections are constructed in a wide temperature and composition range. Isopleth 20 mol.% HfO2 (20H) shows the Al2O3–HfO2–La2O3 constitution in the Al2O3-rich region. Isopleth 60 mol.% HfO2 (60H) describes the ternary system in the Al2O3- and La2O3-rich regions and F ⇄ T phase transformation of HfO2 solid solutions. The radial La2O3–(50 mol.% Al2O3 · 50 mol.% HfO2) vertical section reveals the nature of X ⇄ H ⇄ A phase transformations of La2O3 solid solutions. The vertical sections intersect all three triangulating planes of the Al2O3–HfO2–La2O3 system and demonstrate variation in the width of their two-phase regions.
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References
S. M. Lakiza, Ya. S. Tishchenko, V. P. Red’ko, and L. M. Lopato, “The Al2O3–HfO2–La2O3 phase diagram. I. Liquidus and solidus surfaces,” Powder Metall. Met. Ceram., 49, No. 9–10, 516–527 (2011).
S. M. Lakiza, Ya. S. Tishchenko, V. P. Red’ko, and L. M. Lopato, “The Al2O3–HfO2–La2O3 phase diagram. II. Phase equilibria at 1250 and 1600°C,” Powder Metall. Met. Ceram., 50, No. 5–6, 345–349 (2011).
L. M. Lopato, A. V. Shevchenko, and G. I. Gerasimyuk, “The HfO2–Al2O3 system,” Inorg. Mater., 12, No. 6, 1623–1626 (1978).
A. V. Shevchenko, L. M. Lopato, and Z. A. Zaitseva, “Interaction of HfO2 with lanthanum, praseodymium, and neodymium oxides at high temperatures,” Inorg. Mater., 20, No. 9, 1530–1534 (1984).
I. A. Bondar and N. V. Vinogradova, “Phase equilibria in the lanthanum oxide–aluminum oxide system,” Izv. Akad. Nauk SSSR. Ser. Khimiya, No. 5, 785–790 (1964).
M. Mizuno, R. Berjoan, J. P. Coutures, and M. Foex, “Phase diagram of the system Al2O3–La2O3 at elevated temperatures,” J. Ceram. Soc. Jap., 82, No. 12, 631–636 (1974).
R. C. Ropp and G. G. Libovitz, “The nature of the alumina-rich phase in the system La2O3–Al2O3,” J. Am. Ceram. Soc., 61, Nos. 11–12, 473–475 (1978).
O. Yamaguchi, K. Sagiura, A. M. Mitsui, and K. Shimizu, “New compound in the system La2O3–Al2O3,” J. Am. Ceram. Soc., 68, No. 2, 44–45 (1985).
Yu. A. Kocherzhinskii, E. A. Shishkin, and V. I. Vasilenko, “DTA apparatus with a temperature sensor to 2200°C,” in: Phase Diagrams of Metallic Systems [in Russian], Nauka, Moscow (1971), pp. 245–249.
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L. M. Lopato is deceased.
Translated from Poroshkovaya Metallurgiya, Vol. 55, Nos. 1–2 (507), pp. 96–103, 2015.
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Lakiza, S.M., Tishchenko, Y.S. & Lopato, L.M. Vertical Sections of the Al2O3–HfO2–La2O3 Phase Diagram. Powder Metall Met Ceram 55, 72–77 (2016). https://doi.org/10.1007/s11106-016-9782-3
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DOI: https://doi.org/10.1007/s11106-016-9782-3