Abstract
\( {\text{CN}} (B^{2}\Sigma ^{ + } \to X^{2}\Sigma ^{ + } ) \) violet system was investigated using optical emission spectroscopy in a non-equilibrium microwave atmospheric-pressure plasma jet in argon expanding in air. From the analysis of the emission spectra of the discharge in the range of 380 and 400 nm, the violet system of CN was found to be overlapped with the \( {\text{N}}_{2}^{ + } \left( {B^{2}\Sigma _{u}^{ + } , v = 1 \to X^{2}\Sigma _{g}^{ + } , v = 1} \right) \) and \( {\text{N}}_{2} \left( {C^{3}\Pi _{u} \to B^{3}\Pi _{g} } \right) \) bands, sequence \( \Delta \upsilon = - \;3 \). A numerical disentangle technique, developed in this work, permitted to obtain a well resolved violet system from the different systems observed, namely the nitrogen First Negative and the Second Positive systems. The \( {\text{CN}} (B^{2}\Sigma ^{ + } \to X^{2}\Sigma ^{ + } ) \) band head intensity was determined and analysed as function of discharge powers between 30 and 150 W and fluxes between 2.5 and 10.0 slm. With aid of this numerical approach it was also possible to obtain the rotational temperature, from (1600 ± 100) to (2300 ± 100) K and vibrational temperature between (9000 ± 800) and (14,000 ± 800) K along the plasma jet. The kinetics of \( {\text{CN}} (B^{2}\Sigma ^{ + } ) \) state was analysed as well.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11090-017-9867-x/MediaObjects/11090_2017_9867_Fig1_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11090-017-9867-x/MediaObjects/11090_2017_9867_Fig2_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11090-017-9867-x/MediaObjects/11090_2017_9867_Fig3_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11090-017-9867-x/MediaObjects/11090_2017_9867_Fig4_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11090-017-9867-x/MediaObjects/11090_2017_9867_Fig5_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11090-017-9867-x/MediaObjects/11090_2017_9867_Fig6_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11090-017-9867-x/MediaObjects/11090_2017_9867_Fig7_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11090-017-9867-x/MediaObjects/11090_2017_9867_Fig8_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11090-017-9867-x/MediaObjects/11090_2017_9867_Fig9_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11090-017-9867-x/MediaObjects/11090_2017_9867_Fig10_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11090-017-9867-x/MediaObjects/11090_2017_9867_Fig11_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11090-017-9867-x/MediaObjects/11090_2017_9867_Fig12_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11090-017-9867-x/MediaObjects/11090_2017_9867_Fig13_HTML.gif)
Similar content being viewed by others
References
Solomon P, Vanden Bout P, Carilli C, Guelin M (2003) Nature 426:636–638
Lieberei R, Biehl B, Giesemann A, Junqueira NTV (1989) Plant Physiol 90:33–36
Moller BL (2010) Current Opin Plant Biol 13:338–347
Bhattacharya R, Lakshmana Rao PV (1997) Toxicology 123:207–215
Okolie NP, Osagie AU (2000) Food Chem Toxicol 38:543–548
Loureiro J, Amorim J (2016) Kinetics and spectroscopy of low temperature plasmas, 1st edn. Springer, Berlin
www.co2.earth. Accessed 03 Mar 2017
Dilecce G, Ambrico PF, Scarduelli G, Tosi P, De Benedictis S (2009) Plasma Sources Sci Technol 18:015010
Setser DW, Trush BA (1968) Proc R Soc A 288:256–291
Boden JC, Trush BA (1968) Proc R Soc A 305:93–105, 107–123
Grigorian G, Cenian A (2011) Plasma Chem Plasma Process 31:337–352
Washida N, Kley D, Becker KH, Groth W (1975) J Chem Phys 63:4230–4241
Pintassilgo CD, Cernogora G, Loureiro J (2001) Plasma Sources Sci Technol 10:147–161
Broida HP, Heath DF (1957) J Chem Phys 26:1352
Iseni S, Bruggeman PJ, Weltmann KD, Reuter S (2016) Appl Phys Lett 108:184101
Schmidt-Bleker A, Norberg SA, Winter J, Johnsen E, Reuter S, Weltmann KD, Kushner MJ (2015) Plasma Sources Sci Technol 24:035022
Tsuji M, Yamaguchi K, Nishimura Y (1988) Chem Phys 123:151–157
Ridenti MA, Souza-Corrêa JA, Amorim J (2014) J Phys D Appl Phys 47:045204
Foltin V, Leštinská L, Machala A (2006) Czech J Phys 56:B712–B720
Amorim J, Ridenti MA, Guerra V (2015) Plasma Phys Control Fusion 57:074001
Specair User Manual Version 3.0 (2012) SpectralFit, S.A.S. www.specair-radiation.net/manual.php. Accessed 13 April 2017
Silva MLD, Vacher D, Duceck M, André P, Faure G (2008) Plasma Sources Sci Technol 17:035013
Bazavan M, Iova I (2008) Rom Rep Phys 60:671–678
Herzberg GH (1950) Molecular spectra and molecular structure: I. Spectra of diatomic molecules, 2nd edn. Van Nostrand, New York
Michaud F, Roux F, Davis SP, Nguyen AD, Laux CO (2000) J Mol Spectrosc 203:1–8
Prasad CVV, Bernath PF (1992) J Mol Spectrosc 156:340–372
Silva MLD (2005) Guidelines for the calculation of bound molecular spectra. arXiv preprint physics/0509132
Michaud F, Roux F, Davies SP, Nguyen AD (1996) Appl Opt 35:2867–2873
Zare RN, Schmeltkoff AL, Harrop WJ, Albritton DL (1973) J Mol Spectrosc 46:37–66
Brown JM, Colbourn EA, Watson JKG, Wayne FD (1979) J Mol Spectrosc 74:294–318
Chauveau S, Perrin MY, Rivière P, Soufiani A (2002) J Quant Spectrosc Radiat Transf 72:503–530
Roux F, Michaud F, Vervloet M (1993) J Mol Spectrosc 158:270–277
Knowles PJ, Werner HJ, Hay PJ, Cartwright DC (1988) J Chem Phys 89:7334–7343
Laux CO, Kruger CH (1992) J Quant Spectrosc Radiat Transf 48:9–24
Ochkin VN (2009) Spectroscopy of Low temperature plasma. Wiley, Weinheim
Lomax RG, Hans-Vaughn DL (2012) Statistical concepts: a second course, 4th edn. Taylor & Francis, Routledge
Levenberg D (1944) Q Appl Math 2:164–168
Marquardt D (1963) SIAM J Appl Math 11:431–441
Ridenti MA, Spyrou N, Amorim J (2014) J Chem Phys Lett 595–596:83–86
Dünnbier M, Schmidt-Bleker A, Winter J, Wolfram M, Hippler R, Weltmann K-D, Reuter S (2013) J Phys D Appl Phys 46:435203
Voráč J, Petr S, Potočňáková L, Hnilica J, Kudrle V (2017) Plasma Sources Sci Technol 26:025010
Levaton J, Amorim J, Monna V, Nagai J, Ricard A (2004) Eur Phys J Appl Phys 26:59–64
Ridenti MA, Souza-Corrêa JA, Amorim J (2016) J Phys Conf Ser 715:012003
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Ridenti, M.A., Amorim, J. CN (B 2Σ+ → X 2Σ+) Violet System in a Cold Atmospheric-Pressure Argon Plasma Jet. Plasma Chem Plasma Process 38, 311–329 (2018). https://doi.org/10.1007/s11090-017-9867-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11090-017-9867-x