Abstract
Superalloy 690 substrates containing mainly Cr and Ni aluminides on the uppermost surface, formed by atmospheric plasma spraying and heat treatment, were oxidized at 1273 K in air for 2 h. Quantitative X-ray photoelectron spectroscopy (XPS) analyses indicated that the outermost surface layer formed on aluminides is composed of ~ 21.0 at.% Al+3 (as Al2O3), 17.0 at.% Al0 (elemental aluminium), 1.4 at.% Cr+3 (as Cr2O3) and 60.5 at.% O (in Al2O3 and Cr2O3 and also includes oxygen contaminant). Surface sputtering for 5 min exhibited splitting of Cr2p3/2 peak into a doublet comprising Cr+3 (0.9 at.%) and Cr0 (0.4 at.%) with the presence of 1.15 at.% Ni0 in the surface layer that mainly contained ~ 37.3 at.% Al+3, 7.3 at.% Al0 and 52.9 at.% O. Surface sputtering for 15 min indicated surface composition similar to surface sputtered for 5 min but with a marked reduction in ratio of Al+3/Al0 (32.2 at.% Al+3/11.90 at.% Al0) in the surface layer.
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The work has been funded by Department of Atomic Energy, Government of India.
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Dutta, R.S., Banerjee, R.H. & Dey, G.K. An XPS Study with Depth Profiling for the Surface Oxide Layer Formed on Aluminides Produced on Superalloy 690 Substrates. Oxid Met 89, 699–711 (2018). https://doi.org/10.1007/s11085-017-9813-6
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DOI: https://doi.org/10.1007/s11085-017-9813-6