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Effect of PANI addition on structural, optical and electrical characteristics of PVC/Sn0.9Fe0.1S2 polymer

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Abstract

Poly (vinyl chloride) (PVC)/Sn0.9Fe0.1S2/x wt% Polyaniline (PANI) polymers were produced using the solid state reaction method under flows of nitrogen and casting methods. The structure and microstructure characteristics of the Sn0.9Fe0.1S2 were performed using Rietveld analysis. X-ray diffraction, Fourier transform infrared, Energy dispersive x-ray and scanning electron microscope techniques were used to investigate the constituent elements and surface morphology of the different polymers. The possibility of doping PVC to apply in UV spectra shielding or use as band pass filter for laser protection was investigated. The direct/indirect optical band gaps for PVC (4.94/4.57) eV were reduced to 3.23/1.81 eV as it doped with Sn0.9Fe0.1S2 and PANI. The impact of PANI and Sn0.9Fe0.1S2 on the refractive index, extinction coefficient, dielectric parameters, optical conductivity, nonlinear optical parameters and dc conductivity and activation energy of PVC was explored. The fluorescence intensity of PVC was improved as it was loaded with Sn0.9Fe0.1S, and greatly enhanced for PVC/Sn0.9Fe0.1S2/PANI.

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References

  • Abdel-Fattah, E., Alharthi, A.I., Fahmy, T.: Spectroscopic, optical and thermal characterization of polyvinyl chloride-based plasma-functionalized MWCNTs composite thin films. Appl. Phys. a. 125, 475 (2019)

    ADS  Google Scholar 

  • Abdelhamied, M.M., Atta, A., Abdelreheem, A.M., Farag, A.T.M., El Okr, M.M.: Synthesis and optical properties of PVA/ PANI/Ag nanocomposite films synthesis and optical properties of PVA/PANI/Ag nanocomposite films. J. Mater. Sci. Mater. Electron. 31, 22629–22641 (2020)

    Google Scholar 

  • Abed, R.N., Yousif, E., Abed, A.R.N., Rashad, A.A.: Synthesis thin films of poly (Vinyl Chloride) doped by aromatic organosilicon to absorb the incident light. Silicon 14, 11829–11845 (2022)

    Google Scholar 

  • Ahmad, A.A., Bani-Salameh, A.A., Al-Bataineh, Q.M., Jum’h, I., Telfah, A.D.: Optical, structural and morphological properties of synthesized PANI-CSA-PEO-based GaN nanocomposite films for optoelectronic applications. Polym. Bull. 80, 809 (2023)

    Google Scholar 

  • Ahmed, R.M., Atta, M.M., Taha, E.O.: Optical spectroscopy, thermal analysis, and dynamic mechanical properties of graphene nano-platelets reinforced polyvinylchloride. J. Mater. Sci. Mater. Electron. 32, 22699–22717 (2021)

    Google Scholar 

  • Biswas, M.R.U.D., Ho, B.S., Oh, W.-C.: Eco-friendly conductive polymer-based nanocomposites, BiVO4/graphene oxide/polyaniline for excellent photocatalytic performance. Polym. Bull. 77, 4381 (2020)

    Google Scholar 

  • Brunner, A.J.: X-ray diffraction pattern of poly (vinyl chloride). Polym. Lett. 10, 379–383 (1972)

    Google Scholar 

  • Chen, J., Nie, X.A., Jiang, J.C., Zhou, Y.H.: Thermal degradation and plasticizing mechanism of poly(vinyl chloride) plasticized with a novel cardanol derived plasticizer. IOP Conf. Ser. Mater. Sci. Eng. 292, 01200 (2017)

    Google Scholar 

  • Chen, Y., Wang, T., Pan, J., Wang, M., Chen, A., Chen, Y.: Fabrication, characterization and photocatalytic degradation activity of PS/PANI/CeO2 tri-layer nanostructured hybrids. Bull. Mater. Sci. 45, 45 (2022). https://doi.org/10.1007/s12034-021-02635-8

    Article  Google Scholar 

  • El-Hachemi, B., Miloud, S., Sabah, M., Souad, T., Zineddine, O., Boubekeur, B., Toufik, S.M., Ouahiba, H.: Structural, electrical and optical properties of PVC/ZnTe nanocomposite. J. Inorg. Organomet. Polym. 31, 3637–3648 (2021a)

    Google Scholar 

  • El-Hachemi, B., Miloud, S., Sabah, M., Souad, T., Zineddine, O., Boubekeur, B., Toufik, S.M.: Halimi, Ouahiba, structural, electrical and optical properties of PVC/ZnTe nanocomposite. J. Inorg. Organomet. Polym. 31, 3637–3648 (2021b)

    Google Scholar 

  • El-Naggar, A.M., Heiba, Z.K., Mohamed, M.B., Kamal, A.M., Osman, M.M., Albassam, A.A., Lakshminarayana, G.: Embedding of 50%PVA/50%PVP blend with Sn0.75M0.25S2, (M = Y, Fe, Cr, V); structural and optical study. Appl. Phys. A 127, 1–7 (2021)

    Google Scholar 

  • El-naggar, A.M., Heiba, Z.K., Mohamed, M.B., Kamal, A.M., Osman, M.M., Albassam, A.A., Lakshminarayana, G.: Improvement of the optical characteristics of PVA/PVP blend with different concentrations of SnS2/Fe. J. Vinyl Addit. Technol. 28(1), 82–93 (2022a)

    Google Scholar 

  • El-naggar, A.M., Heiba, Z.K., Mohamed, M.B., Kamal, A.M., Lakshminarayana, G.: M AShar, Structural, linear and nonlinear optical properties of poly (vinyl alcohol)(PVA)/polyethylene glycol (PEG)/SnS2: Y nanocomposite films. Optik 258, 168941 (2022b)

    ADS  Google Scholar 

  • El-naggar, A.M., Alsaggaf, A., Heiba, Z.K., Kamal, A.M., Aldhafiri, A.M., Fatehmulla, A., Mohamed, M.B.: Exploring the structural, optical and electrical characteristics of PVA/PANi blends. Opt. Mater. 139, 113771 (2023)

    Google Scholar 

  • El-naggar, A.M., Heiba, Z.K., Kamal, A.M., Mohamed, M.B.: The role of cobalt amount in ZnCdS nanofiller on the optical, thermal, dielectric and structure properties of PVA/PVP/PEG blends. Opt. Quant. Electron. 55(7), 609 (2023b)

    Google Scholar 

  • Gaabou, L.H.: Effect of addition of TiO2 nanoparticles on structural and dielectric properties of polystyrene/polyvinyl chloride polymer blend. AIP Adv. 11(10), 105120 (2021)

    ADS  Google Scholar 

  • Graeme, A.G.: Characterization of solid polymers by luminescence techniques. Pure. Appl. Chem. 57(7), 945–954 (1985)

    Google Scholar 

  • Harshvardhan, P Yadav, Singh, B.: Systematic investigation of the effect of SnS2 nanofiller content on the piezoelectric performance of the PVDF-TrFE-based nanogenerator. Mater. Today Proc. (2023). https://doi.org/10.1016/j.matpr.2023.05.607

    Article  Google Scholar 

  • Jia, P., Zhang, M., Hu, L., Wang, R., Sun, C., Zhou, Y.: Cardanol groups grafted on poly(vinyl chloride)—synthesis. Perform. Plasticization Mech. Polym. 9, 621 (2017)

    Google Scholar 

  • Kroschwitz, I.: Electronic Properties of Polymers. Wiley, Hoboken (1988)

    Google Scholar 

  • Laourari, I., Lakhdari, N., Belgherbi, O., Medjili, C., Berkani, M., Vasseghian, Y., Golzadeh, N., Lakhdari, D.: Antimicrobial and antifungal properties of NiCu-PANI/PVA quaternary nanocomposite synthesized by chemical oxidative polymerization of polyaniline. Chemosphere 291, 132696 (2022)

    ADS  Google Scholar 

  • Makled, M.H., Sheha, E., Shanap, T.S., El-Mansy, M.K.: Electrical conduction and dielectric relaxation in p-type PVA/CuI polymer composite. J. Adv. Res. 4, 531–538 (2013)

    Google Scholar 

  • Mallakpour, S., Sadaty, M.A.: Thiamine hydrochloride (vitamin B1) as modifier agent for TiO2 nanoparticles and the optical, mechanical, and thermal properties of poly(vinyl chloride) composite films. RSC Adv 6, 92596–92604 (2016)

    ADS  Google Scholar 

  • Mallakpour, S., Shamsaddinimotlagh, S.: Ultrasonic-promoted rapid preparation of PVC/TiO2-BSA nanocomposites: characterization and photocatalytic degradation of methylene blue. Ultrason. Sonochem. 41, 361–374 (2018)

    Google Scholar 

  • Mansour, A.F., Elfalaky, A., Abdel Maged, F.: Synthesis, characterization and optical properties of PANI/PVA Blends. IOSR J. Appl. Phys. (IOSR-JAP) 7(4), 37–45 (2015)

    Google Scholar 

  • Mirmohseni, A., Wallace, G.G.: Preparation and characterization of processable electroactive polyaniline–polyvinyl alcohol composite. Polymer 44, 3523–3528 (2003)

    Google Scholar 

  • Mohamed, M.B., Heiba, Z.K.: Structural and properties correlation in PANI–Mo doped CoFe2O4 nanocomposite. J. Mater. Sci. Mater. Electron. 28(23), 17578–17586 (2017)

    Google Scholar 

  • Rajendran, S., Sivakumar, P., Babu, R.S.: Studies on the salt concentration of a PVdF–PVC based polymer blend electrolyte. J. Power Source 164, 815–821 (2007)

    ADS  Google Scholar 

  • Ramazanov, M.A., Rahimli, A.M., Hajiyeva, F.V.: The influence of titanium dioxide (TiO2) nanoparticles on the structure, optical and dielectric properties of polyvinyl chloride (PVC). Mod. Phys. Lett. B 34(28), 2050310 (2020)

    ADS  Google Scholar 

  • Rouabah, N., Boudine, B., Nazir, R., Zaabat, M., Sebais, M., Halimi, O., Soltani, M.T., Chala, A.: Structural, optical and photocatalytic properties of PVC/CdS nanocomposites prepared by soft chemistry method. J. Inorg. Organomet. Polym. 31, 1102–1110 (2021)

    Google Scholar 

  • Sadek, E.M., Mansour, N.A., Ahmed, S.M., Abd-El-Messieh, S.L., El-Komy, D.: Synthesis, characterization and applications of poly (vinyl chloride) nanocomposites loaded with metal oxide nanoparticles. Polym. Bull 78, 5481–5502 (2021)

    Google Scholar 

  • Sayed, W.M., Soliman, L.I.: Optical properties of polyaniline salt and polyaniline base with KBr, Co (CH~ 3COO)~ 2 and picric acid composites. Fizika (zagreb) 4, 147–152 (2000)

    ADS  Google Scholar 

  • Selvi, J., Mahalakshmi, S., Parthasarathy, V.: Synthesis, structural, optical, electrical and thermal studies of poly(vinyl alcohol)/CdO nanocomposite films. J. Inorg. Organomet. Polym. 27, 1918–1926 (2017)

    Google Scholar 

  • Sharma, S., Singh, K.L., Kumar, M., Prasher, S.: Structural, optical and thermal properties of PVC/polyaniline composite thin films. JOM 74(2), 1–7 (2021)

    Google Scholar 

  • Soman, V.V., Kelkar, D.S.: FTIR studies of doped PMMA-PVC blend system. Macromol Symp 277, 152–161 (2009)

    Google Scholar 

  • Taha, T.A., Saleh, A.: Dynamic mechanical and optical characterization of PVC/fGO polymer nanocomposites. Appl. Phys. A 124, 600 (2018)

    ADS  Google Scholar 

  • Taha, T.A., Hendawy, N., El-Rabaie, S., Esmat, A., El-Mansy, M.K.: Effect of NiO NPs doping on the structure and optical properties of PVC polymer films. Polym. Bull 76, 4769–4784 (2019)

    Google Scholar 

  • Taha, T.A., Hendawy, N., El-Rabaie, S., Esmat, A., El-Mansy, M.K.: Fluorescence and dielectric spectroscopy identification of polyvinyl chloride/NiO nanocomposites. J. Mol. Struct. 1212, 128162 (2020)

    Google Scholar 

  • Tao, S., Zhu, S., Feng, T., Zheng, C., Yang, B.: Crosslink-enhanced emission effect on luminescence in polymers: advances and perspectives. Angew. Chem. Int. Ed. 59, 9826–9840 (2020)

    Google Scholar 

  • Tauc, J.: Optical properties and electronic structure of amorphous Ge and Si. Mater. Res. Bull. 3(1), 37–46 (1968)

    Google Scholar 

  • Wadatkar, N.S., Waghuley, S.A.: Characterizing the electro-optical properties of polyaniline/poly(vinyl acetate) composite films as-synthesized through chemical route. Results Surf. Interfaces 4, 100016 (2021)

    Google Scholar 

  • Wang, B., Jiang, F., Ma, X., Dong, Z., Liu, Y.: Preparation of highly dispersed ZnO nanoparticles to fabricate ultraviolet-shielding poly(vinyl chloride) films. Colloid Polym. Sci. 300, 51–57 (2022)

    Google Scholar 

  • Wu, C., Wicks, D.A.: Use of fluorescence for the high-throughput evaluation of synergistic thermal and photo stabilizer interactions in poly (vinyl chloride). Rev. Sci. Instrum 76, 062212 (2005)

    ADS  Google Scholar 

  • Yazid, M.I.B.M., Ghani, S.A., Jin, T.S., Osman, A.F., Mohd Din, S.H.: Utilization of polyaniline (PAni) as conductive filler on poly (Ethylene Oxide)/poly (Vinyl Chloride) films: effects of naphthalene as surface modifier on electrical conductivity. J. Phys. Conf. Ser. 908, 012006 (2017)

    Google Scholar 

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Acknowledgements

The authors extend their appreciation to the Deputyship for Research & Innovation, Ministry of Education in Saudi Arabia for funding this research. (IFKSURC-1-1004)

Funding

This work is supported by  Deputyship for Research & Innovation, Ministry of Education in Saudi Arabia.

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Authors and Affiliations

  1. Research Chair of Exploitation of Renewable Energy Applications in Saudi Arabia, Physics and Astronomy Department, College of Science, King Saud University, P.O. Box 2455, 11451, Riyadh, Saudi Arabia

    A. M. El-naggar

  2. Physics Department, Faculty of Science, Ain Shams University, Cairo, Egypt

    Zein K. Heiba & Mohamed Bakr Mohamed

  3. Physics and Astronomy Department, College of Science, King Saud University, P.O. Box 2455, 11451, Riyadh, Saudi Arabia

    A. M. Kamal & Omar H. Abd-Elkader

  4. Physics Department, Faculty of Science, Taibah University, Al‑Madina al Munawarah, Saudi Arabia

    Mohamed Bakr Mohamed

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El-naggar, A.M., Heiba, Z.K., Kamal, A.M. et al. Effect of PANI addition on structural, optical and electrical characteristics of PVC/Sn0.9Fe0.1S2 polymer. Opt Quant Electron 55, 998 (2023). https://doi.org/10.1007/s11082-023-05293-8

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