Abstract
Cu(In,Ga)Se2 (CIGSe) thin film solar cells were fabricated by direct inkjet printing of Cu(In,Ga)S2 (CIGS) nanoparticles followed by rapid thermal annealing under selenium vapor. Inkjet printing is a low-cost, low-waste, and flexible patterning method which can be used for deposition of solution-based or nanoparticle-based CIGS films with high throughput. XRD and Raman spectra indicate that no secondary phase is formed in the as-deposited CIGS film since quaternary chalcopyrite nanoparticles are used as the base solution for printing. Besides, CIGSe films with various Cu/(In + Ga) ratios could be obtained by finely tuning the composition of CIGS nanoparticles contained in the ink, which was found to strongly influence the devices performance and film morphology. To date, this is the first successful fabrication of a solar device by inkjet printing of CIGS nanoparticles.
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References
Akhavan VA, Goodfellow BW, Panthani MG et al (2010) Spray-deposited CuInSe2 nanocrystal photovoltaics. Energy Environ Sci 3:1600. doi:10.1039/c0ee00098a
Akhavan VA, Harvey TB, Stolle JC et al (2013) Influence of composition on the performance of sintered Cu(in,Ga)Se2 nanocrystal thin-film photovoltaic devices. ChemSusChem 6:481–486. doi:10.1002/cssc.201200677
Bär M, Bohne W, Röhrich J et al (2004) Determination of the band gap depth profile of the penternary Cu(In1-xGax)(SySe1-y)2 chalcopyrite from its composition gradient. J Appl Phys 96:3857. doi:10.1063/1.1786340
Burgelman M, Engelhardt F, Guillemoles JF et al (1997) Defects in Cu(in,Ga)Se2 semiconductors and their role in the device performance of thin film solar cells. Prog Photovolt Res Appl 5:121–130. doi:10.1002/1099-159X
Contreras MA, Ramanathan K, AbuShama J, et al. (2005) Diode Characteristics in State-of-the-Art ZnO/CdS/Cu(In1-xGax)Se2 Solar Cells. 209–216. doi:10.1002/pip.626
Gifford J (2015) Solar Frontier hits 22.3% on CIGS cell. http://www.pv-magazine.com/news/details/beitrag/solar-frontier-hits-223-on-cigs-cell_100022342/#axzz4A1XiBckL.
Guo Q, Ford GM, Agrawal R, Hillhouse HW (2013) Ink formulation and low-temperature incorporation of sodium to yield 12% efficient Cu(In,Ga)(S,Se)2 solar cells from sulfide nanocrystal inks. Prog Photovolt Res Appl 21:64–71. doi:10.1002/pip
Habas SE, Platt HAS, Van Hest MFAM, Ginley DS (2010) Low-cost inorganic solar cells: from ink to printed device. Chem Rev 110:6571–6594. doi:10.1021/cr100191d
Klugius I, Miller R, Quintilla A et al (2012) Growth mechanism of thermally processed Cu(In,Ga)S2 precursors for printed Cu(In,Ga)(S,Se)2 solar cells. Phys status solidi - Rapid Res Lett 6:297–299. doi:10.1002/pssr.201206191
Lee DH, Chang YJ, Herman GS, Chang CH (2007) A general route to printable high-mobility transparent amorphous oxide semiconductors. Adv Mater 19:843–847. doi:10.1002/adma.200600961
Lim T, Yang J, Lee S et al (2012) Deposit pattern of inkjet printed pico-liter droplet. Int J Precis Eng Manuf 13:827–833. doi:10.1007/s12541-012-0108-1
Lin X, Kavalakkatt J, Lux-Steiner MC, Ennaoui A (2015) Inkjet-Printed Cu2ZnSn(S,Se)4 Solar Cells. Adv Sci 4:n/a–n/a. doi:10.1002/advs.201500028
McLeod SM, Hages CJ, Carter NJ, Agrawal R (2015) Synthesis and characterization of 15% efficient CIGSSe solar cells from nanoparticle inks. Prog Photovolt Res Appl 23:1550–1556
Mitzi DB, Yuan M, Liu W et al (2009) Hydrazine-based deposition route for device-quality CIGS films. Thin Solid Films 517:2158–2162. doi:10.1016/j.tsf.2008.10.079
Neophytou M, Georgiou E, Fyrillas MM, Choulis SA (2014) Two step sintering process and metal grid design optimization for highly efficient ITO free organic photovoltaics. Sol Energy Mater Sol Cells 122:1–7. doi:10.1016/j.solmat.2013.11.021
Park BK, Kim D, Jeong S et al (2007) Direct writing of copper conductive patterns by ink-jet printing. Thin Solid Films 515:7706–7711. doi:10.1016/j.tsf.2006.11.142
Pettersson J, Torndahl T, Platzer-Bjorkman C et al (2013) The unfluence of absorber thickness on Cu(In,Ga)Se2 solar cells with different buffer layers. IEEE J Photovoltaics 3:1376–1382. doi:10.1109/jphotov.2013.2276030
Todorov TK, Gunawan O, Gokmen T, Mitzi DB (2013) Solution-processed Cu(In,Ga)(S,Se)2 absorber yielding a 15.2% efficient solar cell. Prog Photovoltaics Res Appl 82–87. doi:10.1002/pip
Vidmar T, Topič M, Dzik P, Opara Krašovec U (2014) Inkjet printing of sol-gel derived tungsten oxide inks. Sol Energy Mater Sol Cells 125:87–95. doi:10.1016/j.solmat.2014.02.023
Virtuani A, Lotter E, Powalla M, et al. (2014) Influence of Cu content on electronic transport and shunting behavior of Cu(In,Ga)Se2 solar cells. 014906:0–11. doi:10.1063/1.2159548
Wang W, Su Y-W, Chang C (2011) Inkjet printed chalcopyrite CuInxGa1−xSe2 thin film solar cells. Sol Energy Mater Sol Cells 95:2616–2620. doi:10.1016/j.solmat.2011.05.011
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The research reported in this publication was supported by the King Abdullah University of Science and Technology (KAUST).
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Barbé, J., Eid, J., Ahlswede, E. et al. Inkjet printed Cu(In,Ga)S2 nanoparticles for low-cost solar cells. J Nanopart Res 18, 379 (2016). https://doi.org/10.1007/s11051-016-3686-5
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DOI: https://doi.org/10.1007/s11051-016-3686-5