Skip to main content
Log in

Influence of Chromium on the Phase Composition and Specific Features of Hardening of the MnFeCoNiCu High-Entropy Alloy

  • Published:
Materials Science Aims and scope

A six-component system of CoNiCuCrx high-entropy alloys with different contents of chromium (where x = 0, 0.5, 1.0, 2.0, and 3.0 mole) is obtained by the method of argon-arc melting in a МІFІ-9 study. By the methods of X-ray diffraction analysis, scanning-electron microscopy, and indentation, we investigate the influence of chromium on the crystalline structure, microstructure, and hardness of these alloys in the as-cast state. In their structure, depending on the chromium content, we detect a mixture of the following phase components: two face-centered cubes + a body-centered cube + an intermetallic σ-phase (FCC1 + FCC2 + BCC + σ). It is also established that, as the chromium content increases, we observe the formation of the bcc structure and the σ-phase, which is the predominant factor of hardening of the alloy.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. J. W. Yeh, S.-K. Chen, S.-J. Lin, J.-Y. Gan, T.-S. Chin, T.-T. Shun, C.-H. Tsau, and S.-Y. Chang, “Nanostructured high-entropy alloys with multiple principal elements: novel alloy design concepts and outcomes,” Adv. Eng. Mater., 6, No. 5, 299–303 (2004).

    Article  CAS  Google Scholar 

  2. M. V. Demchenko, O. P. Gaponova, O. M. Myslyvchenko, B. Antoszewski, and M. M. Bychenko, “Microstructure and properties of AlCrFeCoNiCux high-entropy alloys,” J. Eng. Sci., 5, No. 1, 11–16 (2018).

    Google Scholar 

  3. O. N. Senkov, G. B. Wilks, D. B. Miracle, C. P. Chuang, and P.K. Liawd, “Refractory high-entropy alloys,” Intermetallics, 18, No. 9, 1758–1765 (2010).

    Article  CAS  Google Scholar 

  4. T. K. Biswas and N.P. Gurao, “Deciphering micromechanisms of plastic deformation in a novel single phase FCC based MnFeCo-NiCu high entropy alloy using crystallographic texture,” Mater. Sci. Eng.: A, 657, 224–233 (2016).

    Article  Google Scholar 

  5. S. Huang, A. Vida, A. Heczel, and E. Holmström, “Thermal expansion, elastic and magnetic properties of FeCoNiCu-based highentropy alloys using first-principle theory,” J. Miner. Met. Mater. Soc., 69, No. 11, 2107–2112 (2017).

    Article  CAS  Google Scholar 

  6. V. F. Gorban', N. A. Krapivka, and S. A. Firstov, “High-entropy alloys: interrelations between electron concentration, phase composition, lattice constant, and properties,” Fiz. Met. Metalloved., 118, No. 10, 1017–1029 (2017); English translation: Phys. Met. Metallogr., 118, 970–981(2017).

  7. M. Ren, B. Li, and H. Fu, “Formation condition of solid solution type high-entropy alloy,” Trans. Nonferr. Met. Soc. China, 23, No. 4, 991–995 (2013).

    Article  CAS  Google Scholar 

  8. A. Takeuchi and A. Inoue, “Classification of bulk metallic glasses by atomic size difference, heat of mixing and period of constituent elements and its application to characterization of the main alloying element,” Mater. Trans., No. 12, 2817–2829 (2005).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to О. M. Myslyvchenko.

Additional information

Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 56, No. 3, pp. 81–85, May–June, 2020.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Myslyvchenko, О.M., Krapivka, М.О., Tereshchenko, О.S. et al. Influence of Chromium on the Phase Composition and Specific Features of Hardening of the MnFeCoNiCu High-Entropy Alloy. Mater Sci 56, 375–380 (2020). https://doi.org/10.1007/s11003-020-00440-y

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11003-020-00440-y

Keywords

Navigation