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Crystallization and melting behavior of poly(ether ketone ketone) (PEKK) copolymers synthesized by facile one-step method

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Abstract

Poly(ether ketone ketone) (PEKK) is a thermoplastic with excellent performance. To date, most PEKK copolymers are synthesized by a two-step method. However, in this work, a series of PEKK copolymers with diverse T/I (terephthaloyl/isophthaloyl) ratios were firstly synthesized by a facial one-step method. Then, the structure of PEKK copolymers was characterized and the crystallization and melting behavior were studied in detail. With the increase in meta isomers in the structure, the crystallization ability and melting point of copolymers reduced, as confirmed by non-isothermal and isothermal crystallization kinetics analysis. Furthermore, the double melting behavior of PEKK copolymers after isothermal annealing was researched employing differential scanning calorimetry (DSC) and temperature-modulated DSC (TMDSC). Unlike many other outcomes, our study demonstrate that the double melting behavior is mainly related to the superimposition of rigid amorphous devitrification and enthalpy relaxation. Finally, through the self-nucleation experiment of PEKK70 and PEKK80, the ideal self-nucleation temperatures (Ts,ideal) corresponding to the copolymers were determined, then the successive self-nucleation and annealing (SSA) technology was employed to analyze PEKK copolymers for the first time, and thermal classification was successfully achieved.

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Authors and Affiliations

  1. State Key Laboratory of Fine Chemicals, Liaoning Key Laboratory of Polymer Science and Engineering, Department of Polymer Science and Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian, 116024, Liaoning, China

    Jingzhao Shang, Ping Song, Yang Li & Zhiyong Wei

  2. School of Materials Science and Engineering, North University of China, Taiyuan, 030051, Shanxi, China

    Ping Song

  3. Shandong Kaisheng New Materials Co., Ltd, Zibo, 255185, Shandong, China

    Ping Song, Guanghui Li & Qingmin Sun

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  1. Jingzhao Shang
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  5. Yang Li
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Contributions

Conceptualization was contributed by JS and PS; methodology was contributed by ZW; formal analysis and investigation were contributed by JS and PS; writing—original draft preparation was contributed by JS; writing—review and editing, was contributed by PS, ZW; resources were contributed by GL and QS; Supervision was contributed by ZW and YL.

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Correspondence to Zhiyong Wei.

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Shang, J., Song, P., Li, G. et al. Crystallization and melting behavior of poly(ether ketone ketone) (PEKK) copolymers synthesized by facile one-step method. J Therm Anal Calorim 148, 11727–11741 (2023). https://doi.org/10.1007/s10973-023-12518-1

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