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Synthesis, magnetic and magnetocaloric properties of transition element doped La0.67Ba0.33MnO3

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Abstract

Colossal magnetoresistance materials have demonstrated large changes in resistance in the presence of magnetic fields. In the current work, a group of such materials, with the compositional formula La0.67Ba0.33MnO3 and 10% Fe, Co, Ni, Zn doped La0.67Ba0.33MnO3 have been prepared by conventional solid-state method. Structural analysis has been carried out by X-Ray diffraction method followed by Rietveld analysis. Magnetic transition between ferromagnetism to paramagnetism has been observed from the magnetic characterizations. Parameters such as Curie temperature (θP) and effective magnetic moment (µeff) are obtained from susceptibility analysis subject to Curie–Weiss law. Furthermore, magnetocaloric nature of the samples is examined from the M-H isotherms. Using Maxwell’s relations, isothermal entropy change, ∆Smax are determined to check whether the prepared samples can be used for magnetic refrigeration around the room temperature.

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Acknowledgements

The authors are thankful to the Matrusri Educational Society for providing financial support to carry out this research. We also thankful to the Principal and Head, Department of Sciences and Humanities, Matrusri Engineering College, Hyderabad, for providing a platform to carry out this research work. The authors also thank Dr. Himalay Basumatary, Scientist, DMRL, Hyderabad, for providing X-ray diffraction facilities.

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Authors and Affiliations

  1. Department of Mechanical Engineering, Matrusri Engineering College, Saidabad, Hyderabad, 500 059, India

    B. Priyanka & K. Krishna Teja

  2. Vidya Jyothi Institute of Technology, Aziz Nagar Gate, Hyderabad, 500 075, India

    E. Sagar

  3. Department of Physics, Telangana University, Nizamabad, Telangana, 503 322, India

    K. Ganesh

  4. Department of Sciences & Humanities, Matrusri Engineering College, Saidabad, Hyderabad, 500 059, India

    M. Sreelatha, T. Shekharam & N. Pavan Kumar

  5. Advanced Magnetic Group, Defence Metallurgical Research Laboratory, Hyderabad, 500058, India

    Arout Chelvane

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  1. B. Priyanka
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Correspondence to N. Pavan Kumar.

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Priyanka, B., Krishna Teja, K., Sagar, E. et al. Synthesis, magnetic and magnetocaloric properties of transition element doped La0.67Ba0.33MnO3. J Therm Anal Calorim 147, 14123–14132 (2022). https://doi.org/10.1007/s10973-022-11714-9

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  • DOI: https://doi.org/10.1007/s10973-022-11714-9

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