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Heat capacity by differential scanning calorimetry and thermodynamic functions of BaCe0.8Gd0.1Y0.1O2.9 in the temperature range of 166–790 K

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Abstract

In the present study, the heat capacities of barium cerate doped by gadolinium and yttrium oxides were measured for the first time in the temperature range of 166–790 K. The differential scanning calorimeter was used for investigation. There was reproducible anomaly with maximum at 601 K and minimum at 679 K. The experimental results were used to calculate the thermodynamic functions: smoothed heat capacities, enthalpy increment (H om (T) − H om (298.15)), and entropy (S om (T)). The heat capacity in the temperature range of 166–602 K was described by a polynomial of the form: C op,m (T) = 83.140 + 0.14943 T − 1.1537 × 10−4 T2 − 3.6358 × 105/T2 (J mol−1 K−1). Heat capacity of BaCe0.8Y0.1Gd0.1O2.9 in the temperature range of 602–680 K was described by a polynomial: C op,m (T) = − 118.18 + 0.71961 T − 5.5387 × 10−4 T2 + 5.6948 × 10+6/T2 (J mol−1 K−1). The heat capacity in the temperature range of 680–790 K was well described by the equation: C op,m (T) = 1987.1 − 6.9263 T + 8.3407 × 10−3 T2 − 3.1992 × 10−6 T3 (J mol−1 K−1).

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Acknowledgements

This work is supported by Karlsruhe Institute of Technology (2016, Germany), Russian Fund of Basic Research (Project 16-08-00226), Federal Agency for Scientific Organizations and Novosibirsk State University. We express our gratitude to the Novosibirsk State University for giving us an access to the library.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk, Russia, 630090

    N. I. Matskevich, D. P. Pischur, S. G. Kozlova, N. V. Gelfond & I. V. Vyazovkin

  2. Institute of Solid State Physics, Karlsruhe Institute of Technology, 76334, Karlsruhe, Germany

    N. I. Matskevich & Th. Wolf

  3. Novosibirsk State University, Novosibirsk, Russia, 630090

    N. I. Matskevich & A. A. Chernov

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  1. N. I. Matskevich
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Matskevich, N.I., Wolf, T., Pischur, D.P. et al. Heat capacity by differential scanning calorimetry and thermodynamic functions of BaCe0.8Gd0.1Y0.1O2.9 in the temperature range of 166–790 K. J Therm Anal Calorim 134, 1123–1128 (2018). https://doi.org/10.1007/s10973-018-7248-1

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