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The relationship between properties of fluorinated graphite intercalates and matrix composition 7

Intercalates with ethyl acetate

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Abstract

Inclusion compounds (intercalates) of fluorinated graphite matrix with ethyl acetate (C2FxBrz·yCH3COOC2H5, x = 0.49, 0.69, 0.87, 0.92, z = 0.01) were prepared by guest substitution from acetonitrile to ethyl acetate. The kinetics of the thermal decomposition (the first stage of filling → the second stage of filling) was studied under isothermal conditions at 291–307 K. The relationship of the host matrices’ structure with inclusion compounds’ thermal properties and kinetic parameters is discussed.

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Acknowledgements

Special thanks to Yu. V. Shubin, N. I. Alferova, and V. P. Fadeeva for collaboration.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Ac. Lavrentyev Ave. 3, Novosibirsk-90, 630090, Russia

    D. V. Pinakov, V. A. Logvinenko & G. N. Chekhova

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  1. D. V. Pinakov
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  2. V. A. Logvinenko
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  3. G. N. Chekhova
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Correspondence to D. V. Pinakov.

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Pinakov, D.V., Logvinenko, V.A. & Chekhova, G.N. The relationship between properties of fluorinated graphite intercalates and matrix composition 7. J Therm Anal Calorim 117, 235–241 (2014). https://doi.org/10.1007/s10973-014-3635-4

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  • DOI: https://doi.org/10.1007/s10973-014-3635-4

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