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Kinetic analysis of thermal decomposition in liquid and solid state of 3-nitro and 4-nitro-benzaldehyde-2,4-dinitrophenylhydrazones

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Abstract

A kinetic study on the thermal decomposition of 3-nitro and 4-nitro-benzaldehyde-2,4-dinitrophenylhydrazones was carried out. The isothermal and dynamic differential scanning calorimetric curves were recorded for solids and melts, respectively. The standard isoconversional analysis of the obtained curves from both isothermal and nonisothermal analysis suggests an autocatalytic decomposition mechanism. This mechanism is also supported by the temperature dependence of the observed induction periods. Based on the results of the model-free method from nonisothermal regime, the kinetic model was derived and the kinetic parameters were obtained by means of a multivariate nonlinear regression.

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Authors and Affiliations

  1. Faculty of Chemistry, Department of Physical Chemistry, University of Bucharest, 4-12 Regina Elisabeta Blvd, 030018, Bucharest, Romania

    Jeanina Pandele Cusu & Dumitru Oancea

  2. “Ilie Murgulescu” Institute of Physical Chemistry, Romanian Academy, 202 Spl.Independentei, 060021, Bucharest, Romania

    Adina Magdalena Musuc

Authors
  1. Jeanina Pandele Cusu
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  2. Adina Magdalena Musuc
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  3. Dumitru Oancea
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Correspondence to Jeanina Pandele Cusu.

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Pandele Cusu, J., Musuc, A.M. & Oancea, D. Kinetic analysis of thermal decomposition in liquid and solid state of 3-nitro and 4-nitro-benzaldehyde-2,4-dinitrophenylhydrazones. J Therm Anal Calorim 109, 255–263 (2012). https://doi.org/10.1007/s10973-011-1662-y

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  • DOI: https://doi.org/10.1007/s10973-011-1662-y

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