Skip to main content
Log in

Ferroelectric BiFeO3 nanodots formed in non-crystallized BiFeO3 thin-films via a local heating process using a heated atomic force microscope tip

  • Original Paper: Sol-gel and hybrid materials for dielectric, electronic, magnetic and ferroelectric applications
  • Published:
Journal of Sol-Gel Science and Technology Aims and scope Submit manuscript

Abstract

A BiFeO3 thin-film was prepared from a solution by deposition on a Pt/TiO2/SiO2/Si substrate via a spin coating process and was subsequently annealed at 300 °C for 1 h to afford a non-crystallized BiFeO3 thin-film. Locally crystallized BiFeO3 nanodots were formed in the non-crystallized BiFeO3 thin-film via a local crystallization process using an atomic force microscope tip heated to 550 °C. By controlling the local heating time, ferroelectric BiFeO3 nanodots with different diameters ranging from 65 to 120 nm were obtained. The ferroelectric properties of the BiFeO3 nanodots were further investigated by studying the local ferroelectric switching behaviors and local piezoelectric d33 hysteresis loops using a piezoresponse force microscope.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Ghoneim MT, Hussain MM (2015) Study of harsh environment operation of flexible ferroelectric memory integrated with PZT and silicon fabric. Appl Phys Lett 107:052904

    Article  Google Scholar 

  2. Kim W-H, Son JY, Shin Y-H, Jang HM (2014) Imprint control of nonvolatile shape memory with asymmetric ferroelectric multilayers. Chem Mat 26:6911–6914

    Article  Google Scholar 

  3. Lipatov A, Sharma P, Gruverman A, Sinitskii A (2015) Optoelectrical molybdenum disulfide (MoS2) ferroelectric memories. ACS Nano 9:8089–8098

    Article  Google Scholar 

  4. Scott JF (2007) Applications of modern ferroelectrics. Science 315:954–959

    Article  Google Scholar 

  5. Son JY, Ryu S, Park Y-C, Lim Y-T, Shin Y-S, Shin Y-H, Jang HM (2010) A nonvolatile memory device made of a ferroelectric polymer gate nanodot and a single-walled carbon nanotube. ACS Nano 4:7315–7320

    Article  Google Scholar 

  6. Dussan S, Kumar A, Scott JF, Priya S, Katiyar RS (2010) Room temperature multiferroic effects in superlattice nanocapacitors. Appl Phys Lett 97:252902

    Article  Google Scholar 

  7. Lee W, Han H, Lotnyk A, Schubert MA, Senz S, Alexe M, Hesse D, Baik S, Gosele U (2008) Individually addressable epitaxial ferroelectric nanocapacitor arrays with near Tb inch-2 density. Nat Nano 3:402–407

    Article  Google Scholar 

  8. Son JY, Lee J-H, Song S, Shin Y-H, Jang HM (2013) Four-states multiferroic memory embodied using Mn-doped BaTiO3 nanorods. ACS Nano 7:5522–5529

    Article  Google Scholar 

  9. Chu M-W, Szafraniak I, Scholz R, Harnagea C, Hesse D, Alexe M, Gosele U (2004) Impact of misfit dislocations on the polarization instability of epitaxial nanostructured ferroelectric perovskites. Nat Mater 3:87–90

    Article  Google Scholar 

  10. Jung I, Son JY (2012) A nonvolatile memory device made of a graphene nanoribbon and a multiferroic BiFeO3 gate dielectric layer. Carbon N Y 50:3854–3858

    Article  Google Scholar 

  11. Jia C-L, Nagarajan V, He J-Q, Houben L, Zhao T, Ramesh R, Urban K, Waser R (2007) Unit-cell scale mapping of ferroelectricity and tetragonality in epitaxial ultrathin ferroelectric films. Nat Mater 6:64–69

    Article  Google Scholar 

  12. Seyidov MY, Coskun E, Sahin Y, Khamoev R, Suleymanov RA (2006) The effect of thermal annealing on impurity states in ferroelectric- semiconductor TlGaSe2 within the incommensurate phase. Semicond Sci Technol 21:171–174

    Article  Google Scholar 

  13. Hyuk Park M, Joon Kim H, Jin Kim Y, Lee W, Moon T, Seong Hwang C (2013) Evolution of phases and ferroelectric properties of thin Hf 0.5Zr0.5O2 films according to the thickness and annealing temperature. Appl Phys Lett 102:242905

  14. Hironori F, Yuko M, Masaru S (2006) Fabrication of self-assembled Au nanodots and their applications to ferroelectric nanocapacitors. Jpn J Appl Phys 45:7262–7264

    Article  Google Scholar 

  15. Yoo H, Bae C, Kim M, Hong S, No K, Kim Y, Shin H (2013) Visualization of three dimensional domain structures in ferroelectric PbTiO3 nanotubes. Appl Phys Lett 103:022902

    Article  Google Scholar 

  16. Piner RD, Zhu J, Xu F, Hong S, Mirkin CA (1999) ‘Dip-pen’ nanolithography. Science 283:661–663

    Article  Google Scholar 

  17. Hyun J, Ahn SJ, Lee WK, Chilkoti A, Zauscher S (2002) Molecular recognition-mediated fabrication of protein nanostructures by dip-pen lithography. Nano Lett 2:1203–1207

    Article  Google Scholar 

  18. Wang Y, Jiang QH, He HC, Nan CW (2006) Multiferroic BiFeO3 thin films prepared via a simple sol-gel method. Appl Phys Lett 88:142503–142501

    Article  Google Scholar 

  19. Seo J, Ahn Y, Kim W-H, Son JY (2016) Local ferroelectric responses of epitaxial PbTiO3 thin films to heated atomic force microscopy. Mater Lett 168:134–137

    Article  Google Scholar 

  20. Yang J-K, Kim WS, Park H-H (2001) Effect of grain size of Pb(Zr0.4Ti0.6)O3 sol-gel derived thin films on the ferroelectric properties. Appl Surf Sci 169(70):544–548

    Article  Google Scholar 

  21. Qiao L, Bi X (2009) Microstructure and grain size dependence of ferroelectric properties of BaTiO3 thin films on LaNiO3 buffered Si. J Eur Ceram Soc 29:1995–2001

    Article  Google Scholar 

  22. Kim W-H, Son JY (2013) The effects of La substitution on ferroelectric domain structure and multiferroic properties of epitaxially grown BiFeO3 thin films. Appl Phys Lett 103:132907

    Article  Google Scholar 

  23. Bark CW, Ryu S, Koo YM, Jang HM, Youn HS (2007) Electric-field-induced structural modulation of epitaxial BiFeO3 multiferroic thin films as studied using x-ray microdiffraction. Appl Phys Lett 90:022902

    Article  Google Scholar 

Download references

Acknowledgements

This work was supported by the Korea Research Foundation Grant under contract no. 2015R1A2A2A05027951.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jong Yeog Son.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Additional information

Highlights

  • Locally crystallized BiFeO3 nanodots were formed in a non-crystallized BiFeO3 thin-film via a local crystallization process using an atomic force microscope tip heated to 550 °C.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shin, H.W., Son, J.Y. Ferroelectric BiFeO3 nanodots formed in non-crystallized BiFeO3 thin-films via a local heating process using a heated atomic force microscope tip. J Sol-Gel Sci Technol 86, 170–174 (2018). https://doi.org/10.1007/s10971-018-4627-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10971-018-4627-9

Keywords

Navigation