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Porous nanofiber membrane from phase separation electronspun for selectively recovering uranium from seawater

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Abstract

Polymer fibers with amidoxime group are promising candidates to extract uranium from seawater. However, their application is limited majorly by small specific surface area. Here, we show a facial method by just using water as a second phase in electrospinning to fabricate non-woven porous polyamidoxime fibers membrane, with a high specific surface area of 31.1 m2 g−1. The membrane can deliver adsorption capacity of 243.9 mg U g−1 in aqueous solution and 6.65 mg U g−1 in spiked seawater. It also exhibits good selectivity and high stability. The results indicate that this phase separation electrospinning method has great potential on developing high performance adsorbents.

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Acknowledgements

This work is supported by National Natural Science Foundation of China (No. 21667002, 21866001); Foundation of State Key Laboratory of Nuclear Resources and Environment, East China University of Technology (No. NRE1923); Doctoral Foundation of East China University of Technology (No. DHBK2017161) and the Opening Project of Jiangxi Province Key Laboratory of Polymer Micro/Nano Manufacturing and Devices.

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  1. State Key Laboratory of Nuclear Resources and Environment, East China University of Technology, Nanchang, 330013, Jiangxi, China

    Hongxia Jiang, Jianqiang Luo, Zeping Liu, Shujuan Liu, Fangqing Li, Lihua Zuo, Jianguo Ma & Mingbiao Luo

  2. Jiangxi Province Key Laboratory of Polymer Micro/Nano Manufacturing and Devices, Nanchang, 330013, Jiangxi, China

    Jianqiang Luo

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  1. Hongxia Jiang
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Jiang, H., Luo, J., Liu, Z. et al. Porous nanofiber membrane from phase separation electronspun for selectively recovering uranium from seawater. J Radioanal Nucl Chem 331, 2523–2532 (2022). https://doi.org/10.1007/s10967-022-08302-4

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