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Separation of zirconium and hafnium from early actinides and rare earth elements with eichrom’s pb resin in HCl

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Abstract

The separation of zirconium and hafnium isotopes from the early actinides and rare earth elements (REE) with Eichrom’s Pb resin has been studied. Batch studies were performed to characterize the behavior of actinium, thorium, zirconium, hafnium, lutetium, and yttrium on Pb resin from HCl solutions (0.001 M to 11 M). The early actinides and REE had no affinity for the resin at any concentration of HCl, but zirconium and hafnium showed a moderate uptake at high concentrations of HCl with a maximum extraction at 11 M HCl. Several column separations were tested, including with only tracer isotopes and with mass. Rapid, simple separations of zirconium from actinium, thorium, protactinium, and the REE with high yields and low elution volumes are presented with applications for tracer isotope production and fission product separations. The resin is less suitable for hafnium separations as hafnium tends to bleed off the resin even at high concentrations of HCl.

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Acknowledgements

This study was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

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  1. Lawrence Livermore National Laboratory, Nuclear and Chemical Sciences Division, Livermore, CA, USA

    Kelly N. Kmak, John D. Despotopulos & Nicholas D. Scielzo

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  1. Kelly N. Kmak
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Correspondence to Kelly N. Kmak.

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Kmak, K.N., Despotopulos, J.D. & Scielzo, N.D. Separation of zirconium and hafnium from early actinides and rare earth elements with eichrom’s pb resin in HCl. J Radioanal Nucl Chem 330, 1027–1036 (2021). https://doi.org/10.1007/s10967-021-07990-8

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